di(tert-butylsulfenyl)mercury | 3374-16-1

• 分子结构分类: 有机化合物 - 有机硫化合物
• 英文名称: di(tert-butylsulfenyl)mercury
• 英文别名: di(t-butylthio)mercury；2-methyl-propane-2-thiol; mercury bis-(2-methyl-propane-2-thiolate)；2-Methyl-propan-2-thiol; Quecksilber-bis-(2-methyl-propan-2-thiolat)；2-Methyl-propan-2-thiol; Quecksilber(II)-Verbindung；Quecksilber-bis-tert-butylmercaptid；Quecksilber-tert.-butyl-mercaptid
• CAS: 3374-16-1
• 化学式: C₈H₁₈HgS₂
• 分子量: 378.953
• InChiKey: QREOIABEXJFXOQ-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  1.33
• 重原子数：
  6.0
• 可旋转键数：
  0.0
• 环数：
  0.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  0.0
• 氢给体数：
  0.0
• 氢受体数：
  1.0

安全信息

• 海关编码：
  2930909090

反应信息

• 作为反应物：
  描述：

  二(三氟甲基)亚膦酰碘 、 di(tert-butylsulfenyl)mercury 以 neat (no solvent) 为溶剂， 生成 mercury(II) iodide
  参考文献：
  名称：

  摘要：

  Perfluoromethyl phosphorus and -arsenic compounds of the type (F3C)(2)EE'R (E = P, As; E' = S, Se, Te; R = organic group) are prepared either by dismutation (metathesis) of E-2(CF3)(4) with (RE')(2) or by reaction of the iodine compounds (F3C)(2)EI with mercury(II) organosulfanides Hg(SR)(2) and characterized by spectroscopic (H-1, F-19, P-31-NMR; IR; MS) as well as analytical investigations (C, H).

  DOI：

  10.1002/(sici)1521-3749(199912)625:12<2085::aid-zaac2085>3.3.co;2-j
• 作为产物：
  描述：

  氰化汞 、 叔丁基硫醇 在 乙醇 作用下， 生成 di(tert-butylsulfenyl)mercury
  参考文献：
  名称：

  Rheinboldt; Mott; Motzkus, Journal fur praktische Chemie (Leipzig 1954), 1932, vol. <2>134, p. 274

  摘要：

  DOI：
• 作为试剂：
  描述：

  N-benzyl-S-cyanothiohydroxylamine 在 乙醚 、 di(tert-butylsulfenyl)mercury 作用下， 生成 N-benzyl-2-methyl-propane-2-sulfenamide
  参考文献：
  名称：

  Peyron; Laplaine, Comptes Rendus Hebdomadaires des Seances de l'Academie des Sciences, 1948, vol. 227, p. 132

  摘要：

  DOI：

文献信息

• Synthesis of Thiol, Selenol, and Tellurol Esters by the Reaction of Organochalcogeno Mercurials with Acid Chlorides
  作者：Claudio C. Silveira、Antonio L. Braga、Enrique L. Larghi

  DOI：10.1021/om990589e

  日期：1999.11.1

  Thiol, selenol, and tellurol esters were prepared by the reaction of bis(organochalcogeno)mercurials with acid chlorides in chloroform or carbon tetrachloride and in the presence of tetrabutylammonium halides as catalysts.

  通过在氯仿或四氯化碳中，在卤化四丁基铵的存在下，使双（有机碳氢基）汞与酰氯反应，制得硫醇，硒醇和碲的酯。
• Endovascular Treatment of a Lenticulostriate Artery Aneurysm with N-butyl Cyanoacrylate
  作者：Ramiro Larrazabal、David Pelz、J. Max Findlay

  DOI：10.1017/s0317167100001426

  日期：2001.8

  Aneurysms arising from lenticulostriate artery branches in moyamoya-type disease are challenging lesions to treat, due to their fragility and deep location. Surgery is difficult and endovascular options may be limited.

  A 57-year-old woman presented with a right ganglionic parenchymal hemorrhage due to a ruptured lenticulostriate artery aneurysm associated with ipsilateral middle cerebral artery occlusion. The aneurysm and parent feeding artery were occluded using endovascular injection of N-butyl cyanoacrylate.

  The aneurysm was successfully obliterated and although some glue did enter the more distal middle cerebral artery, there was no change in the patient's neurologic status.

  In highly selected cases where lenticulostriate aneurysms cannot be directly accessed for surgery or endovascular coiling, obliteration with liquid acrylic glue may be considered as a therapeutic option.

  背景：在莫亚莫亚型疾病中，由皮孔状动脉分支产生的动脉瘤因其脆性和深部位置，治疗起来具有挑战性。方法：一名 57 岁的女性因枕叶动脉动脉瘤破裂导致右侧神经节实质出血，并伴有同侧大脑中动脉闭塞。结果：动脉瘤被成功堵塞，虽然一些胶水进入了较远端大脑中动脉，但患者的神经状况没有发生变化。结论：在无法直接进入皮孔状动脉瘤进行手术或血管内卷曲的高选择性病例中，可以考虑使用液态丙烯酸胶水堵塞动脉瘤作为一种治疗选择。
• Syntheses and vibrational spectra of some tris(alkanethiolato)mercurate(II) complexes, and crystal structure of the Hexakis(methanethiolato)dimercurate(II) dianion
  作者：GA Bowmaker、IG Dance、BC Dobson、DA Rogers

  DOI：10.1071/ch9841607

  日期：——

  The complexes [cation] [Hg(SR)3](R = Me, cation = Et4N+; R = But, cation = Et4N+, Bu4N+, [N(Ph3P)2]+) have been prepared. The crystal structure of the methanethiolate complex shows that it contains centrosymmetric dinuclear anions [(MeS)2Hg(�-SMe)2Hg(SMe)2]2- with distorted tetrahedral geometry about the mercury atoms. Vibrational spectroscopic evidence suggests that this complex dissociates on dissolution in ethanol to give mononuclear [Hg(SMe)3]- species. The ButS- complexes appear to exist as mononuclear [Hg(SBut)3]- species both in the solid state and in solution. The metal-sulfur stretching frequencies are assigned for all of the complexes studied, and the vibrational spectra are discussed in terms of the structures of the complex anions involved. Crystal data for [(C2H5)4N]2Hg2(SCH3)6 : a 8.656(5), b gS130(6), c 12.368(8) �; α 102.16(4), β 105.51(4), γ 105.29(4)�; space group P1, Z 1, R 0.034, Rw 0.042.

  阳离子] 复合物 [Hg(SR)3]（R = Me，阳离子 = Et4N+；R = But、 阳离子 = Et4N+、Bu4N+、[N(Ph3P)2]+) 的晶体结构。甲硫醇复合物的晶体结构显示，它含有中心对称的 复合物的晶体结构显示，它含有中心对称的双核 阴离子[(MeS)2Hg(�-SMe)2Hg(SMe)2]2-，以汞原子为中心呈扭曲的四面体几何形状。 几何形状。振动 光谱证据表明，该复合物在乙醇中溶解后会解离出单核 乙醇中溶解，生成单核 [Hg(SMe)3]-。 物种。ButS- 复合物似乎 单核[Hg(SBut)3]-物种。 在固态和溶液中都以单核 [Hg(SBut)3]- 物种的形式存在。所有配合物的金属硫伸展 频率，并根据所涉及的络阴离子的结构对振动光谱进行了讨论。 的结构进行了讨论。(C2H5)4N]2Hg2(SCH3)6的晶体数据 ：a 8.656(5)，b gS130(6)，c 12.368(8)； α 102.16(4)，β 105.51(4)，γ 105.29(4)。 0.034，Rw 0.042。
• Reaction of arsenic, antimony, bismuth and sulfur fluorides with (t-butylthio) trimethylsilane
  作者：A.F. Janzen、O.C. Vaidya、C.J. Willis

  DOI：10.1016/0022-1902(81)80318-1

  日期：1981.1

  Tris(t-butylthio) derivatives of arsenic, antimony and bismuth have been prepared in high yield by the reaction of metal fluoride with (t-butylthio)trimethylsilane. The products have been characterized by elemental analysis, IR, Raman, proton NMR and mass spectrometry. Attempts to prepare As(V), Sb(V) or S(IV) derivatives were unsuccessful, although the reaction of SF4 or Et2NSF3 suggests the formation

  通过金属氟化物与（叔丁基硫基）三甲基硅烷的反应，高产率地制备了砷，锑和铋的三（叔丁基硫基）衍生物。产品已通过元素分析，IR，拉曼，质子NMR和质谱进行了表征。尽管SF 4或Et 2 NSF 3的反应表明形成了S（IV）中间体，但未能成功制备As（V），Sb（V）或S（IV）衍生物。
• Rheinboldt; Dewald; Diepenbruck, Journal fur praktische Chemie (Leipzig 1954), 1931, vol. <2>130, p. 138
  作者：Rheinboldt、Dewald、Diepenbruck

  DOI：——

  日期：——