N-allyl-N-t-butylbenzylamine | 10601-84-0

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: N-allyl-N-t-butylbenzylamine
• 英文别名: N-Allyl-N-benzyl-tert.-butylamin；N-benzyl-2-methyl-N-prop-2-enylpropan-2-amine
• CAS: 10601-84-0
• 化学式: C₁₄H₂₁N
• 分子量: 203.327
• InChiKey: IIFWILZNWIYWHR-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3.4
• 重原子数：
  15
• 可旋转键数：
  5
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.43
• 拓扑面积：
  3.2
• 氢给体数：
  0
• 氢受体数：
  1

反应信息

• 作为产物：
  描述：

  N-叔丁基苄胺 在 氨 、 sodium 作用下， 生成 N-allyl-N-t-butylbenzylamine
  参考文献：
  名称：

  The Sodium—Ammonia Reduction of Bispropargyl- and Propargylallylamines. Steric and Conformational Effects¹

  摘要：

  DOI：

  10.1021/jo01344a510

文献信息

• Phenyl Chloro(thionoformate): a New Dealkylating Agent of Tertiary Amines
  作者：David S. Millan、David S. Millan、Rolf H. Prager、Rolf H. Prager

  DOI：10.1071/ch98147

  日期：——

  Phenyl chloro(thionoformate) reacts rapidly with unhindered tertiary aliphatic amines at 20° to give a thiocarbamate and an alkyl chloride. Dialkylcyclohexylamines react surprisingly rapidly to form predominantly cyclohexene. The thiocarbamates are converted into the secondary amine salt by treatment with dimethyl sulfate, followed by hydrolysis with water. Rates of reaction and alkyl group cleavage selectivity in amines were found to be superior or comparable to those previously reported with chloroformates.

  苯基氯代(硫代甲酸酯)在20°下与无障碍的三级脂肪胺迅速反应，生成硫代氨酸酯和烷基氯化物。二烷基环己胺出奇地迅速反应，主要生成环己烯。硫代氨酸酯经过甲基硫酸二甲酯处理后，再用水水解转化为二级胺盐。在氨基中，反应速率和烷基团裂解选择性被发现优于或与以前报道的氯代甲酸酯相媲美。
• Improved cleaning composition
  申请人：The Clorox Company

  公开号：EP2256182A2

  公开（公告）日：2010-12-01

  An improved cleaning composition adapted to clean a variety of hard surfaces. The improved cleaning composition includes a cationic biocide that includes biguanide compounds and/or quats.

  一种适用于清洁各种硬表面的改良清洁组合物。改进后的清洁组合物包括一种阳离子杀菌剂，其中包括双胍化合物和/或季铵盐。
• Disinfection and cleaning confirmation system
  申请人：Metrex Research LLC

  公开号：EP2851094A1

  公开（公告）日：2015-03-25

  An indicator kit for detecting the presence of a quaternary ammonium compound disinfectant is provided. The kit includes an indicator composition that includes an azo dye material and water; an extraction composition that includes water, and at least one of a C1-C7 alcohol or a glycol ether; and an acidic compound present in at least one of the indicator composition, the extraction composition, or an acidic developer solution packaged separately from the indicator composition and the extraction composition. A method of detecting a quaternary ammonium compound disinfectant on a surface is also provided.

  提供了一种用于检测季铵化合物消毒剂存在的指示剂试剂盒。该试剂盒包括一种指示剂组合物，其中包括偶氮染料材料和水；一种萃取组合物，其中包括水、C1-C7 醇或乙二醇醚中的至少一种；以及一种酸性化合物，存在于指示剂组合物、萃取组合物或与指示剂组合物和萃取组合物分开包装的酸性显影液中的至少一种中。此外，还提供了一种检测表面上季铵盐化合物消毒剂的方法。
• Low-VOC cleaning substrates and compositions
  申请人：The Clorox Company

  公开号：US10358624B1

  公开（公告）日：2019-07-23

  A cleaning composition for sanitizing and/or disinfecting hard surfaces, comprising: a cationic biocide, surfactant and low levels of VOC solvents. The cleaning composition is adapted to clean a variety of hard surfaces without leaving behind a visible residue and creates low levels of streaking and filming on the treated surface. The cleaning composition contains less than 5% by weight of VOCs. The cleaning composition may be used alone as a liquid or spray formulation or in combination with a substrate, for example, a pre-loaded cleaning wipe.

  一种用于硬表面消毒和/或杀菌的清洁组合物，包括：阳离子杀菌剂、表面活性剂和低挥发性有机化合物溶剂。该清洁组合物适用于清洁各种硬表面，不会留下明显的残留物，并能在处理过的表面形成低水平的条纹和薄膜。按重量计，清洁组合物中的挥发性有机化合物含量低于 5%。该清洁组合物可单独作为液体或喷雾制剂使用，也可与基质结合使用，例如预装清洁抹布。
• Low-VOC cleaning substrates comprising a quat and ethoxylated/propdxylated fatty alcohol
  申请人：THE CLOROX COMPANY

  公开号：US10421929B2

  公开（公告）日：2019-09-24

  A cleaning composition for sanitizing and/or disinfecting hard surfaces, comprising: a cationic biocide, surfactant and low levels of VOC solvents. The cleaning composition is adapted to clean a variety of hard surfaces without leaving behind a visible residue and creates low levels of streaking and filming on the treated surface. The cleaning composition contains less than 5% by weight of VOCs. The cleaning composition may be used alone as a liquid or spray formulation or in combination with a substrate, for example, a pre-loaded cleaning wipe.

  一种用于硬表面消毒和/或杀菌的清洁组合物，包括：阳离子杀菌剂、表面活性剂和低挥发性有机化合物溶剂。该清洁组合物适用于清洁各种硬表面，不会留下明显的残留物，并能在处理过的表面形成低水平的条纹和薄膜。按重量计，清洁组合物中的挥发性有机化合物含量低于 5%。该清洁组合物可单独作为液体或喷雾制剂使用，也可与基质结合使用，例如预装清洁抹布。