N,N-diphenylnaphtho[1,2-b][1]benzothiol-5-amine

• 分子结构分类: 有机化合物 - 有机氮化合物
• 英文名称: N,N-diphenylnaphtho[1,2-b][1]benzothiol-5-amine
• 化学式: C₂₈H₁₉NS
• 分子量: 401.5
• InChiKey: PTDHURQGZWPZIJ-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  8.8
• 重原子数：
  30
• 可旋转键数：
  3
• 环数：
  6.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  31.5
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为产物：
  描述：

  2-(benzo[b]thiophen-2-yl)aniline 在 1,10-菲罗啉 、 bis(η3-allyl-μ-chloropalladium(II)) 、 potassium tert-butylate 、 对甲苯磺酸一水合物 、 potassium hydrogencarbonate 、 三(邻甲基苯基)磷 作用下， 以 1,4-二氧六环 、 N,N-二甲基甲酰胺 、 乙腈 为溶剂， 反应 38.17h， 生成 N,N-diphenylnaphtho[1,2-b][1]benzothiol-5-amine 、 18-Phenyl-9-thia-18-azahexacyclo[15.7.0.02,10.03,8.011,16.019,24]tetracosa-1(17),2(10),3,5,7,11,13,15,19,21,23-undecaene
  参考文献：
  名称：

  通过热/光化学过程控制的氨基（氧膦基）芳烃的脱氧膦官能化化学发散合成多环芳香族二芳胺和咔唑

  摘要：

  使用 KO t Bu/1,10-菲咯啉采用热或光化学控制工艺建立了多环芳香二芳基胺和咔唑的化学发散合成方法。合成过程涉及9-氨基-10-(氧膦基)菲的脱氧膦基化，这是通过区域选择性钯催化的氧膦基胺与2-碘联苯的直接[4 + 2]苯环化反应获得的。当在加热条件（～100℃）下进行脱氧膦化时，会产生9-氨基菲。然而，当反应在紫光（LED，λ max = 约 390 nm）照射下进行时，KO t Bu/1,10-菲咯啉促进单电子转移触发的脱氧膦化，然后环化，产生相应的π-膨胀咔唑。我们通过双脱氧膦环化成功合成了高度π扩容的二咔唑。此外，我们还介绍了通过脱膦酰化过程产生的一系列氨基化合物的光学性质。

  DOI：

  10.1021/acs.joc.4c00432

文献信息

• Oxygen-containing fused ring amine compound, sulfur-containing fused ring amine compound and organic electroluminescence device
  申请人：IDEMITSU KOSAN CO., LTD.

  公开号：US10270040B2

  公开（公告）日：2019-04-23

  A fused amine compound including a furan ring or a thiophene ring and an organic electroluminescence device employing the amine compound. The organic electroluminescence device includes a cathode, an anode, and one or more organic thin film layers which are disposed between the cathode and the anode. The organic thin film layers include a light emitting layer and at least one layer of the organic thin film layers includes at least one amine compound.

  一种包括呋喃环或噻吩环的熔融胺化合物和一种采用该胺化合物的有机电致发光器件。有机电致发光器件包括一个阴极、一个阳极和一个或多个有机薄膜层，有机薄膜层被放置在阴极和阳极之间。有机薄膜层包括发光层，有机薄膜层中至少有一层包括至少一种胺化合物。
• ORGANIC ELECTROLUMINESCENCE
  申请人：IDEMITSU KOSAN CO., LTD.

  公开号：US20140183500A1

  公开（公告）日：2014-07-03

  A fused amine compound including a furan ring or a thiophene ring and an organic electroluminescence device employing the amine compound. The organic electroluminescence device includes a cathode, an anode, and one or more organic thin film layers which are disposed between the cathode and the anode. The organic thin film layers include a light emitting layer and at least one layer of the organic thin film layers includes at least one amine compound.
• OXYGEN-CONTAINING FUSED RING AMINE COMPOUND, SULFUR-CONTAINING FUSED RING AMINE COMPOUND AND ORGANIC ELECTROLUMINESCENCE DEVICE
  申请人：IDEMITSU KOSAN CO., LTD.

  公开号：US20170324043A1

  公开（公告）日：2017-11-09

  A fused amine compound including a furan ring or a thiophene ring and an organic electroluminescence device employing the amine compound. The organic electroluminescence device includes a cathode, an anode, and one or more organic thin film layers which are disposed between the cathode and the anode. The organic thin film layers include a light emitting layer and at least one layer of the organic thin film layers includes at least one amine compound.
• ORGANIC ELECTROLUMINESCENCE DEVICE AND POLYCYCLIC COMPOUND FOR ORGANIC ELECTROLUMINESCENCE DEVICE
  申请人：Samsung Display Co., Ltd.

  公开号：US20220416174A1

  公开（公告）日：2022-12-29

  An organic electroluminescence device includes a first electrode, a hole transport region disposed on the first electrode, an emission layer disposed on the hole transport region, an electron transport region disposed on the emission layer, and a second electrode disposed on the electron transport region, wherein the hole transport region includes a polycyclic compound represented by Formula 1, and the device shows high emission efficiency:
• US9755156B2
  申请人：——

  公开号：US9755156B2

  公开（公告）日：2017-09-05