N,N’-bis(9-anhtracenylmethyl)-1,2-cyclohexanediamine | 1003557-93-4

• 分子结构分类: 有机化合物 - 苯类化合物 - 蒽
• 英文名称: N,N’-bis(9-anhtracenylmethyl)-1,2-cyclohexanediamine
• 英文别名: N,N'-bis(anthracen-9-yl-methyl)cyclohexane-1,2-diamine；1-N,2-N-bis(anthracen-9-ylmethyl)cyclohexane-1,2-diamine
• CAS: 1003557-93-4
• 化学式: C₃₆H₃₄N₂
• 分子量: 494.679
• InChiKey: ZKZMLJPVYBGYPL-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  8.7
• 重原子数：
  38
• 可旋转键数：
  6
• 环数：
  7.0
• sp3杂化的碳原子比例：
  0.22
• 拓扑面积：
  24.1
• 氢给体数：
  2
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  N,N’-bis(9-anhtracenylmethyl)-1,2-cyclohexanediamine 、 原甲酸三乙酯 在 氯化铵 作用下， 以84%的产率得到1,3-bis(9-anthracenylmethyl)perhydrobenzimidazolinium chloride
  参考文献：
  名称：

  Synthesis of 1,3-Dialkylperhydrobenzimidazolinium Salts and Their Catalytic Properties in Heck Reactions

  摘要：

  Novel eight 1,3-dialkylperhydrobenzimidazolinium chloride salts 3a-h were prepared as precursors of N-heterocyclic carbenes by reacting N,N'-dialkylcyclohexanediamine, triethyl orthoformate and ammonium chloride. The salts were characterized spectroscopically and the complexes formed in situ from Pd(OAc)(2) and 3 have been tested as catalysts in homogenous Heck coupling reactions.

  DOI：

  10.3987/com-13-12678
• 作为产物：
  描述：

  1,2-二氨基环己烷 在 sodium tetrahydroborate 作用下， 以 甲醇 、 乙醇 为溶剂， 反应 16.5h， 生成 N,N’-bis(9-anhtracenylmethyl)-1,2-cyclohexanediamine
  参考文献：
  名称：

  Synthesis of 1,3-Dialkylperhydrobenzimidazolinium Salts and Their Catalytic Properties in Heck Reactions

  摘要：

  Novel eight 1,3-dialkylperhydrobenzimidazolinium chloride salts 3a-h were prepared as precursors of N-heterocyclic carbenes by reacting N,N'-dialkylcyclohexanediamine, triethyl orthoformate and ammonium chloride. The salts were characterized spectroscopically and the complexes formed in situ from Pd(OAc)(2) and 3 have been tested as catalysts in homogenous Heck coupling reactions.

  DOI：

  10.3987/com-13-12678

文献信息

• US7326510B2
  申请人：——

  公开号：US7326510B2

  公开（公告）日：2008-02-05
• Synthesis of 1,3-Dialkylperhydrobenzimidazolinium Salts and Their Catalytic Properties in Heck Reactions
  作者：Murat Yiğit、Gülin Bayam、Beyhan Yiğit、İsmail Özdemir

  DOI：10.3987/com-13-12678

  日期：——

  Novel eight 1,3-dialkylperhydrobenzimidazolinium chloride salts 3a-h were prepared as precursors of N-heterocyclic carbenes by reacting N,N'-dialkylcyclohexanediamine, triethyl orthoformate and ammonium chloride. The salts were characterized spectroscopically and the complexes formed in situ from Pd(OAc)(2) and 3 have been tested as catalysts in homogenous Heck coupling reactions.