(Z)-4-hepten-2-yl salicylate | 873888-84-7

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: (Z)-4-hepten-2-yl salicylate
• 英文别名: Benzoic acid, 2-hydroxy-, (3Z)-1-methyl-3-hexen-1-yl ester；[(Z)-hept-4-en-2-yl] 2-hydroxybenzoate
• CAS: 873888-84-7
• 化学式: C₁₄H₁₈O₃
• 分子量: 234.295
• InChiKey: AWFJMMINHWORIB-PLNGDYQASA-N

计算性质

• 辛醇/水分配系数(LogP)：
  4.5
• 重原子数：
  17
• 可旋转键数：
  6
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.36
• 拓扑面积：
  46.5
• 氢给体数：
  1
• 氢受体数：
  3

反应信息

• 作为产物：
  描述：

  4-heptyn-2-yl salicylate 在 钯 氢气 、 乙醇 、 crude product 作用下， 以 乙醇 为溶剂， 98.0 ℃ 、1.77 kPa 条件下， 反应 3.0h， 以giving 23.5 g (96%) of a slightly yellowish oil at 98° C./0.1 Torr (0.133 mbar)的产率得到(Z)-4-hepten-2-yl salicylate
  参考文献：
  名称：

  4-hepten-2-yl salicylate and its use as fragrance ingredient

  摘要：

  本发明涉及4-庚烯-2-基水杨酸酯及其作为香料成分的用途。

  公开号：

  US07842660B2

文献信息

• [EN] 4-HEPTEN-2-YL SALICYLATE AND ITS USE AS FRAGRANCE INGREDIENT<br/>[FR] 4-HEPTENE-2-YLE SALICYLATE ET SON UTILISATION COMME AGENT PARFUMANT
  申请人：GIVAUDAN SA

  公开号：WO2006007755A1

  公开（公告）日：2006-01-26

  The present invention is related to 4-hepten-2-yl salicylate and its use as fragrance ingredient.

  本发明涉及4-庚烯-2-基水杨酸酯及其作为香料成分的用途。
• 4-Hepten-2-Yl Salicylate and Its Use as Fragrance Ingredient
  申请人：Kaiser Roman

  公开号：US20080261859A1

  公开（公告）日：2008-10-23

  The present invention is related to 4-hepten-2-yl salicylate and its use as fragrance ingredient.

  本发明涉及4-庚烯-2-基水杨酸酯及其作为香料成分的用途。
• Organic compounds
  申请人：GIVAUDAN SA

  公开号：US10238592B2

  公开（公告）日：2019-03-26

  A liquid fragrance composition consisting essentially of: cyclohexylidene phenyl acetonitrile; and one or more ingredients selected from the group consisting of cyclohexyl salicylate, MEFROSOL™ (3-methyl-5-phenyl-pentan-1-ol), HEDIONE™ (methyl 2-(3-oxo-2-pentylcyclopentyl)acetate), diethyl phthalate, isopropyl myristate, amyl salicylate, iso-amyl salicylate, benzyl salicylate, iso-bornyl salicylate, cis-3 hexenyl salicylate, ethyl salicylate, iso-butyl salicylate, methyl salicylate and phenylethyl salicylate; and optionally one or more of 3-methyl-5-phenylpentan-1-ol (MEFROSOL™); an alcohol comprising more than 3 carbon atoms selected from the group consisting of benzyl alcohol, 1-hexanol, 1-heptanol, 1-octanol, cyclohexanol, cyclohexyl propanol, methyl phenyl carbinol, phenyl ethyl alcohol and dimethyl benzyl carbinol; or a glycol ether.

  一种液体香料组合物，主要由以下成分组成 环己基亚苯基乙腈；以及 一种或多种成分，选自以下组别：水杨酸环己酯，MEFROSOL™（3-甲基-5-苯基-1-戊醇），HEDIONE™（2-(3-氧代-2-戊基环戊基)乙酸甲酯），邻苯二甲酸二乙酯，肉豆蔻酸异丙酯，水杨酸戊酯，水杨酸异戊酯、肉豆蔻酸异丙酯、水杨酸戊酯、水杨酸异戊酯、水杨酸苄酯、水杨酸异莰酯、水杨酸顺-3-己烯酯、水杨酸乙酯、水杨酸异丁酯、水杨酸甲酯和水杨酸苯乙基酯；以及 一种或多种 3-甲基-5-苯基-1-戊醇（MEFROSOL™）；一种包含 3 个以上碳原子的醇，选自苯甲醇、1-己醇、1-庚醇、1-辛醇、环己醇、环己基丙醇、甲基苯甲醇、苯乙醇和二甲基苯甲醇；或乙二醇醚。
• Fragrance compositions
  申请人：Givaudan SA

  公开号：US10982173B2

  公开（公告）日：2021-04-20

  A perfume composition providing differentiated odour depending on the assessment conditions is provided. The perfume composition includes a) less than 20% by weight of perfumery ingredients having an equilibrium headspace concentration (HS) between 151 and 900 microgram/l at 25° C., b) at least 35% by weight of perfumery ingredients having a HS higher than 900 microgram/l at 25° C. and b) 25% by weight of perfumery ingredients having a HS lower than or equal to 150 microgram/l at 25° C. The perfume composition reduces consumer perfume habituation to said perfume product.

  本发明提供了一种香水组合物，可根据评估条件提供不同的气味。这种香水组合物包括：a）按重量计，在 25 摄氏度时平衡顶空浓度（HS）介于 151 和 900 微克/升之间的香水成分少于 20%；b）按重量计，在 25 摄氏度时平衡顶空浓度（HS）高于 900 微克/升的香水成分至少 35%；b）按重量计，在 25 摄氏度时平衡顶空浓度（HS）低于或等于 150 微克/升的香水成分 25%。
• Perfume compositions
  申请人：GIVAUDAN SA

  公开号：US11364184B2

  公开（公告）日：2022-06-21

  A compacted perfume composition comprising at least three Performance Markers A1, each of them at a level higher than or equal to their specific Critical Compaction Concentration (CCC), respectively, the total concentration of said Performance Markers being higher than 1% by weight of the compacted perfume composition; at least one Performance Vehicle A2, the total concentration of said Performance Vehicle being higher than 10% by weight of the compacted perfume composition; and at least one Performing Diluent B1, the total concentration of said Performing Diluents being higher than 5% by weight of the compacted perfume composition.

  一种压缩香水组合物，包含至少三种性能标记物 A1，每种性能标记物的浓度分别高于或等于其特定临界压缩浓度（CCC），所述性能标记物的总浓度高于压缩香水组合物重量的 1%；至少一种性能载体 A2，所述性能载体的总浓度高于压缩香水组合物重量的 10%；以及至少一种性能稀释剂 B1，所述性能稀释剂的总浓度高于压缩香水组合物重量的 5%。