4-(6-hydroxyhexyloxy)phenylmethyltriphenylphosphonium bromide | 209810-08-2

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: 4-(6-hydroxyhexyloxy)phenylmethyltriphenylphosphonium bromide
• 英文别名: [4-(6-hydroxyhexoxy)phenyl]methyl-triphenylphosphanium;bromide
• CAS: 209810-08-2
• 化学式: Br*C₃₁H₃₄O₂P
• 分子量: 549.488
• InChiKey: QPBZPTGUSBGJCH-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  3.12
• 重原子数：
  35
• 可旋转键数：
  12
• 环数：
  4.0
• sp3杂化的碳原子比例：
  0.23
• 拓扑面积：
  29.5
• 氢给体数：
  1
• 氢受体数：
  3

反应信息

• 作为反应物：
  描述：

  4-(6-hydroxyhexyloxy)phenylmethyltriphenylphosphonium bromide 、 4-(四氢-吡喃-2-基氧基)-苯甲醛 在 lithium 作用下， 以 乙醇 为溶剂， 生成 (E)-4-(6-hydroxyhexyloxy)-4'-(tetrahydropyran-2-yloxy)stilbene
  参考文献：
  名称：

  DICHROIC GUEST-HOST POLARIZER COMPRISING AN ORIENTED POLYMER FILM

  摘要：

  一种二色性客体-宿主偏振器包括定向聚合液晶宿主和与之对齐的二色性客体。偏振器的二色比约为15或更高。该偏振器可以具有较小的厚度，可以使用湿法沉积法制造，可根据所需的图案进行选择，并放置在液晶电池的内部。还公开了具有高度有序介相的可聚合液晶，可用于获得高度定向的聚合物薄膜，如偏振器薄膜。

  公开号：

  US20100267858A1

文献信息

• Dichroic guest-host polarizer comprising an oriented polymer film
  申请人：Sumitomo Chemical Co., Ltd.

  公开号：US07763330B2

  公开（公告）日：2010-07-27

  A dichroic guest-host polarizer comprises an oriented polymerized liquid crystal host and aligned therewith a dichroic guest. The dichroic ratio of the polarizer is about 15 or more. The polarizer may have a small thickness, be manufactured using a wet deposition method, optionally in accordance with a desired pattern, and be provided on the inside of a liquid crystal cell. Polymerizable liquid crystals having a highly ordered mesophase which may be suitable used to obtain highly oriented polymer films such as polarizer films are disclosed.

  一种二色性客体宿主偏振器包括定向的聚合液晶宿主和与之对齐的二色性客体。偏振器的二色性比约为15或更高。该偏振器可以具有较小的厚度，可以使用湿沉积方法制造，可以根据所需图案进行制造，并放置在液晶电池的内部。还公开了具有高度有序中间相的可聚合液晶，可以用于获得高度定向的聚合膜，例如偏振器膜。
• Liquid crystal display laminate and method of manufacturing such
  申请人：——

  公开号：US20030038912A1

  公开（公告）日：2003-02-27

  A liquid crystal display laminate comprises a liquid crystal layer and a single substrate for confining that layer, allowing the liquid crystal layer to be provided using a wet deposition method such as printing or coating. To improve mechanical stability and provide protection and keep the liquid crystal layer in place, a cover layer may be provided on the liquid crystal layer. The cover layer and liquid crystal layer may together form a stratified-phase-separated composite in which case the liquid crystal layer and the cover layer are provided simultaneously. The display laminate is very thin and light weight. The display laminate may include or be combined with further layers such as orientation layers, electrode layers, polarizers and/or retarders layer to form a fully functional, high contrast display device.

  液晶显示器层压板由液晶层和用于限制该层的单一基板组成，允许使用湿沉积方法（如印刷或涂层）提供液晶层。为了提高机械稳定性，提供保护并保持液晶层的位置，可在液晶层上设置一个覆盖层。在这种情况下，液晶层和覆盖层可同时设置。显示屏层压板非常薄且重量轻。显示层压板可包括或与定向层、电极层、偏光片和/或缓释层等其他层结合，以形成功能齐全的高对比度显示装置。
• US7123319B2
  申请人：——

  公开号：US7123319B2

  公开（公告）日：2006-10-17
• DICHROIC GUEST-HOST POLARIZER COMPRISING AN ORIENTED POLYMER FILM
  申请人：LUB Johan

  公开号：US20100267858A1

  公开（公告）日：2010-10-21

  A dichroic guest-host polarizer comprises an oriented polymerized liquid crystal host and aligned therewith a dichroic guest. The dichroic ratio of the polarizer is about 15 or more. The polarizer may have a small thickness, be manufactured using a wet deposition method, optionally in accordance with a desired pattern, and be provided on the inside of a liquid crystal cell. Polymerizable liquid crystals having a highly ordered mesophase which may be suitable used to obtain highly oriented polymer films such as polarizer films are disclosed.

  一种二色性客体-主体偏振器包括定向聚合液晶主体和与之对齐的二色性客体。该偏振器的二色性比约为15或更高。该偏振器可以具有较小的厚度，使用湿法沉积方法制造，可选地按所需模式，并在液晶电池的内部提供。揭示了具有高度有序介相的可聚合液晶，可用于获得高度定向的聚合物薄膜，如偏振器薄膜。