N-苯基-4-(1-苯基乙基)苯胺 | 65036-84-2

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 中文名称: N-苯基-4-(1-苯基乙基)苯胺
• 英文名称: 4-(1-phenylethyl)diphenylamine
• 英文别名: 4-styryldiphenylamine；N-Phenyl-4-(1-phenylethyl)aniline
• CAS: 65036-84-2
• 化学式: C₂₀H₁₉N
• 分子量: 273.378
• InChiKey: NQVOHIADXFXVKE-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  5.7
• 重原子数：
  21
• 可旋转键数：
  4
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.1
• 拓扑面积：
  12
• 氢给体数：
  1
• 氢受体数：
  1

安全信息

• 海关编码：
  2921420090

反应信息

• 作为产物：
  描述：

  1-氯-1-苯乙烷 、 二苯胺 在 zinc(II) chloride 作用下， 反应 1.33h， 生成 N-苯基-4-(1-苯基乙基)苯胺
  参考文献：
  名称：

  Kopecky, Karl R.; Hall, Michael C., Canadian Journal of Chemistry, 1981, vol. 59, p. 3095 - 3104

  摘要：

  DOI：

文献信息

• CONDENSED HETEROCYCLIC COMPOUND AND COMPOSITION
  申请人：Sakamoto Kei

  公开号：US20120302675A1

  公开（公告）日：2012-11-29

  A condensed heterocyclic compound which is shown by the following formula (I) and a composition containing an (a) organic material and (b) at least one type of the condensed heterocyclic compound are provided. (Y indicates a chemical single bond, —S(═O)—, or —SO 2 —. R a and R b indicate substitutable C 1 to C 30 organic groups. Z a and Z b indicate chemical single bonds or —SO 2 —. X 1 and X 2 indicate hydrogen atoms etc. n and m respectively independently indicate integers of 0 to 2, where one of n and m is not 0).

  提供一种由以下公式（I）显示的缩合杂环化合物和含有（a）有机物质和（b）至少一种类型的缩合杂环化合物的组合物。 （Y表示化学单键，—S(═O)—，或—SO2—。Ra和Rb表示可替代的C1到C30有机基团。Za和Zb表示化学单键或—SO2—。X1和X2表示氢原子等。n和m分别独立表示0到2的整数，其中n和m中的一个不为0）。
• [EN] ALKYLATED PANA AND DPA COMPOSITIONS<br/>[FR] COMPOSITIONS PANA ET DPA ALKYLEES
  申请人：CIBA SC HOLDING AG

  公开号：WO2005097728A1

  公开（公告）日：2005-10-20

  The invention relates to a composition comprising a mixture of alkylated N-α-naphthyl-N­phenylamine (PANA) and alkylated diphenylamine (DPA), the product obtainable by alkylat­ing PANA or a mixture of PANA and DPA with alkenes and the process for alkylating PANA or a mixture of PANA and DPA with alkenes. The compositions according to the present in­vention have an outstanding anti-oxidative action, which can be demonstrated by established test methods.

  该发明涉及一种组合物，包括烷基化的N-α-萘基-N-苯胺（PANA）和烷基化的二苯胺（DPA）的混合物，所述产品可通过用烯烃烷基化PANA或PANA和DPA的混合物获得，并且涉及用烯烃烷基化PANA或PANA和DPA的混合物的方法。根据本发明的组合物具有出色的抗氧化作用，可通过已建立的测试方法加以证明。
• NOVEL DIARYLAMINE COMPOUNDS, AGING INHIBITOR, POLYMER COMPOSITION, CROSSLINKED RUBBER PRODUCT AND MOLDED ARTICLE OF THE CROSSLINKED PRODUCT, AND METHOD OF PRODUCING DIARYLAMINE COMPOUND
  申请人：Sakamoto Kei

  公开号：US20120101196A1

  公开（公告）日：2012-04-26

  There are provided a novel diarylamine compound represented by the following formula (I), (II) or (III), which has at least one signal attributable to the hydrogen of the N—H moiety at 8.30 ppm to 9.00 ppm when a deuterated dimethyl sulfoxide solution of the diarylamine compound is analyzed by 1 H-NMR; and an aging inhibitor, a polymer composition, a crosslinked rubber product and a molded article thereof, and a method of producing a diarylamine compound. In the formulas, A 1 to A 6 each represent an aromatic group which may have a substituent; A represents an aromatic group or a cyclic aliphatic group, which may both have a substituent; L represents 1 or 2; and n represents 0 or 1.

  提供了一种新型的二芳基胺化合物，其由以下公式（I）、（II）或（III）表示，当通过1H-NMR分析二芳基胺化合物的氘代二甲基亚磺酸溶液时，具有至少一种可归因于N-H基团的氢的信号在8.30 ppm至9.00 ppm之间；以及一种抗老化剂、一种聚合物组合物、一种交联橡胶产品及其模压制品，以及一种生产二芳基胺化合物的方法。在公式中，A1到A6分别表示可能具有取代基的芳香族基；A表示芳香族基或环状脂肪族基，两者都可能具有取代基；L表示1或2；n表示0或1。
• Expanding the scope of bis(catecholato)germane catalysis: hydrosilylation, hydroboration, Friedel–Crafts alkylation and oligomerization
  作者：Andrew T. Henry、Dana A. R. Nanan、Kim M. Baines

  DOI：10.1039/d3dt01945d

  日期：——

  catalysis were examined. The hydrosilylation of benzaldehydes, hydroboration of phenylacetylene derivatives, and Friedel–Crafts alkylation using arylalkenes and either diphenylamine or anisole was achieved. Furthermore, the recently reported oligomerization of α-methylstyrene catalyzed by bis(catecholato)germanes with weak donor ligands was examined further. The formation of a trimer species was observed

  研究了双（儿茶酚）锗烷在催化中的各种应用。苯甲醛的氢化硅烷化、苯乙炔衍生物的硼氢化以及使用芳基烯烃和二苯胺或苯甲醚的弗里德尔-克来福特烷基化均已实现。此外，还进一步研究了最近报道的具有弱供体配体的双（儿茶酚）锗烷催化的α-甲基苯乙烯齐聚反应。在 DCM 中观察到三聚体的形成。对低聚反应进行了 VTNA 和 Hammett 分析，并提出了双（儿茶酚）锗烷催化的更新机制。
• ACRYLIC RUBBER COMPOSITION, CROSSLINKABLE ACRYLIC RUBBER COMPOSITION, AND CROSSLINKED OBJECT OBTAINED THEREFROM
  申请人：Zeon Corporation

  公开号：EP1270666A1

  公开（公告）日：2003-01-02

  An acrylic rubber composition comprising 100 parts by weight of (a) an acrylic rubber having carboxyl groups, 0.3 to 8 parts by weight of (b) an aromatic secondary amine compound, and 0.3 to 8 parts by weight of (c) nickel dialkyldithiocarbamate. A crosslinkable acrylic rubber composition further comprising 0.1 to 10 parts by weight of a crosslinking agent in addition to the ingredients (a), (b) and (c). By crosslinking the crosslinkable acrylic rubber composition, a crosslinked article having high heat resistance and exhibiting especially a reduced variation in elongation by heat load can be obtained.

  一种丙烯酸橡胶组合物，按重量计包含 100 份(a)具有羧基的丙烯酸橡胶、0.3 至 8 份(b)芳香族仲胺化合物和 0.3 至 8 份(c)二烷基二硫代氨基甲酸镍。一种可交联丙烯酸橡胶组合物，除成分(a)、(b)和(c)外，还包括 0.1 至 10 份（重量）交联剂。通过对可交联丙烯酸橡胶组合物进行交联，可获得具有高耐热性的交联制品，特别是在热负荷下伸长率的变化较小。