zinc 2,2-[μ-(N,N'-dimethylethyleneamino)-dimethyl]-bis(4,6-di-tert-butylphenolate) | 1156505-48-4

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: zinc 2,2-[μ-(N,N'-dimethylethyleneamino)-dimethyl]-bis(4,6-di-tert-butylphenolate)
• 英文别名: ZINC;2,4-ditert-butyl-6-[[2-[(3,5-ditert-butyl-2-oxidophenyl)methyl-methylamino]ethyl-methylamino]methyl]phenolate
• CAS: 1156505-48-4
• 化学式: C₃₄H₅₄N₂O₂Zn
• 分子量: 588.205
• InChiKey: BIBGZSHOHFJXQF-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  6.59
• 重原子数：
  39
• 可旋转键数：
  11
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.65
• 拓扑面积：
  52.6
• 氢给体数：
  0
• 氢受体数：
  4

反应信息

• 作为产物：
  描述：

  diethylzinc 、 N,N'-dimethyl-N,N'-bis(3,5-di-tert-butyl-2-hydroxybenzyl)-1,2-diaminoethane 以 乙醚 为溶剂， 以73%的产率得到zinc 2,2-[μ-(N,N'-dimethylethyleneamino)-dimethyl]-bis(4,6-di-tert-butylphenolate)
  参考文献：
  名称：

  Synthesis, characterization of a novel zinc diamine–bisphenolate complex and its application as an initiator for ring-opening polymerization of rac-lactide

  摘要：

  A novel zinc complex diaminebis(phenolate) [zinc 2,2-{mu-(N, N'-dimethylethyleneamino}dimethyl)-bis(4,6-di-tert-butylphenolate)] (LZn) was synthesized, structurally characterized, and its application as an initiator for the ring-opening polymerization of rac-lactide was reported. (C) 2008 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.inoche.2008.02.011