(2-hydroxyethyl)triphenylphosphonium iodide | 4336-77-0

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: (2-hydroxyethyl)triphenylphosphonium iodide
• 英文别名: (2-Hydroxyethyl)-triphenylphosphoniumiodid；(2-Hydroxy-aethyl)-triphenyl-phosphonium; Jodid；2-Hydroxyethyl(triphenyl)phosphanium;iodide；2-hydroxyethyl(triphenyl)phosphanium;iodide
• CAS: 4336-77-0
• 化学式: C₂₀H₂₀OP*I
• 分子量: 434.256
• InChiKey: MNRLEYHFTWLDPL-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  -0.02
• 重原子数：
  23
• 可旋转键数：
  5
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.1
• 拓扑面积：
  20.2
• 氢给体数：
  1
• 氢受体数：
  2

反应信息

• 作为产物：
  描述：

  alkaline earth salt of/the/ methylsulfuric acid 在 potassium iodide 作用下， 生成 (2-hydroxyethyl)triphenylphosphonium iodide
  参考文献：
  名称：

  Michaelis; v.Soden, Justus Liebigs Annalen der Chemie, 1885, vol. 229, p. 298

  摘要：

  DOI：

文献信息

• Synthesis of Cyclic Carbonates from Epoxides and Carbon Dioxide by Using Bifunctional One-Component Phosphorus-Based Organocatalysts
  作者：Hendrik Büttner、Johannes Steinbauer、Thomas Werner

  DOI：10.1002/cssc.201500612

  日期：2015.8.24

  Numerous bifunctional organocatalysts were synthesized and tested for the atom‐efficient addition of carbon dioxide and epoxides to produce cyclic carbonates. These catalysts are based on phosphonium salts containing an alcohol moiety in the side chain for substrate activation through hydrogen bonding. In the model reaction, converting 1,2‐butylene oxide with CO2, 19 catalysts were tested to determine

  合成了许多双功能有机催化剂，并测试了碳和环氧化物的原子效率加成反应，以生产环状碳酸酯。这些催化剂基于在侧链中包含醇部分的phospho盐，用于通过氢键活化底物。在模型反应中，测试了用CO 2转化1,2-环氧丁烷，19种催化剂以确定结构与活性之间的关系。总共有28种环氧化合物被CO 2转化得到相应的环状碳酸酯，产率最高可达99％。即使在45°C时，活性最高的催化剂也能够以高收率选择性地生产环状碳酸酯。在硅胶上简单过滤后，通常以分析纯的形式获得碳酸盐。这种单组分催化剂体系可在纯净和温和的反应条件下运行，并能耐受多个有用的部分。
• PROCESS FOR PRODUCING ETHYLENE GLYCOL CATALYZED BY IONIC LIQUID
  申请人：Zhang Suojiang

  公开号：US20130072727A1

  公开（公告）日：2013-03-21

  Disclosed is a process for producing ethylene glycol catalyzed by an ionic liquid, characterized in that the process includes the following three steps: (a) a carbonylation step of ethylene oxide and CO 2 catalyzed by an ionic liquid composite catalyst comprising a hydroxyl functionalized ionic liquid and an alkali metal salt under an aqueous condition to produce ethylene carbonate and ethylene glycol; (b) a hydrolysis step of reacting the reaction solution containing ethylene carbonate and the ionic liquid composite catalyst obtained in step (a) with water to produce ethylene glycol; (c) a purification step of dehydrating and refining ethylene glycol from the aqueous solution containing ethylene glycol and the catalyst produced in step (b). The present process has the following advantages: the catalyst has high activity, high suitability, and good stability, the reaction condition is wild, the conversion of ethylene oxide is high, the selectivity of ethylene glycol is high, and the process is simple.

  揭示了一种由离子液体催化生产乙二醇的过程，其特征在于该过程包括以下三个步骤：(a) 由含有羟基官能化离子液体和碱金属盐的离子液体复合催化剂在水相条件下催化乙烯氧化物和CO2的羰基化步骤，以产生碳酸乙烯酯和乙二醇；(b) 将步骤(a)中获得的含有碳酸乙烯和离子液体复合催化剂的反应溶液与水反应以产生乙二醇的水解步骤；(c) 从含有乙二醇和步骤(b)中产生的催化剂的水溶液中脱水和精制乙二醇的纯化步骤。该过程具有以下优点：催化剂活性高、适用性强、稳定性好，反应条件宽松，乙烯氧化物转化率高，乙二醇选择性高，过程简单。
• Immobilized bifunctional phosphonium salts as recyclable organocatalysts in the cycloaddition of CO₂ and epoxides
  作者：J. Steinbauer、L. Longwitz、M. Frank、J. Epping、U. Kragl、T. Werner

  DOI：10.1039/c7gc01782k

  日期：——

  was verified by solid-state NMR and FT-IR. SEM and EDX measurements revealed a homogeneous distribution of the phosphonium salt on the particle surface. This catalyst facilitated the addition of CO2 to epoxides under mild conditions. The evaluation of the substrate scope and the catalyst recycling were combined in one set of experiments. In 15 consecutive runs, the synthesis of 12 cyclic carbonates in

  制备了几种双官能phospho盐催化剂并将其固定在二氧化硅和聚苯乙烯载体上。将固定的体系与其均相类似物在环状碳酸酯合成中进行了比较。有趣的是，在某些情况下，固定化催化剂的活性更高。活性最高的系统是负载在二氧化硅表面的酚官能化phospho盐。solid单元与二氧化硅的共价键通过固态NMR和FT-IR验证。SEM和EDX测量表明phospho盐在颗粒表面上均匀分布。该催化剂促进了CO 2的添加在温和的条件下会氧化成环氧化物。在一组实验中结合了对底物范围的评估和催化剂的再循环。在连续15次运行中，合成了12种环状碳酸酯，产率高达98％。循环实验后对催化剂的研究表明，原始阴离子（溴化物）的损失以及of单元的数量减少，这解释了在循环实验过程中观察到的催化剂失活。
• US8658842B2
  申请人：——

  公开号：US8658842B2

  公开（公告）日：2014-02-25