N,N′-bis(ethyl)-1,4,5,8-naphthalenetetracarboxylicdiimide | 64005-88-5

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 吡啶及其衍生物
• 英文名称: N,N′-bis(ethyl)-1,4,5,8-naphthalenetetracarboxylicdiimide
• 英文别名: 1,4,5,8-Naphthalin-tetracarbonsaeure-diethyl-diimid；Naphthalin-N,N'-diethyl-1,4,5,8-tetracarbonsaeure-diimid；2,7-diethyl-benzo[lmn][3,8]phenanthroline-1,3,6,8-tetraone；2,7-Diethylbenzo[lmn][3,8]phenanthroline-1,3,6,8(2H,7H)-tetraone；6,13-diethyl-6,13-diazatetracyclo[6.6.2.04,16.011,15]hexadeca-1(15),2,4(16),8,10-pentaene-5,7,12,14-tetrone
• CAS: 64005-88-5
• 化学式: C₁₈H₁₄N₂O₄
• 分子量: 322.32
• InChiKey: DNRRBVDAAYJLBG-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  1.9
• 重原子数：
  24
• 可旋转键数：
  2
• 环数：
  4.0
• sp3杂化的碳原子比例：
  0.22
• 拓扑面积：
  74.8
• 氢给体数：
  0
• 氢受体数：
  4

反应信息

• 作为反应物：
  描述：

  N,N′-bis(ethyl)-1,4,5,8-naphthalenetetracarboxylicdiimide 在 aluminum (III) chloride 、 lithium aluminium tetrahydride 作用下， 以 四氢呋喃 为溶剂， 以80%的产率得到1,3,6,8-tetrahydro-2,7-bis(ethyl)-2,7-diazapyrene
  参考文献：
  名称：

  A Molecular Cage That Selectively Complexes Three Different Guests in Solution

  摘要：

  A system based on a molecular cage, in which bisdiazonium, bispyridinium, and anthraquinone guests can be complexed to the host sequentially through the application of suitable stimuli, is reported.

  DOI：

  10.1021/ol901873m
• 作为产物：
  描述：

  1,4,5,8-萘四甲酸酐 、 乙胺 以 水 为溶剂， 反应 6.0h， 以91%的产率得到N,N′-bis(ethyl)-1,4,5,8-naphthalenetetracarboxylicdiimide
  参考文献：
  名称：

  A Molecular Cage That Selectively Complexes Three Different Guests in Solution

  摘要：

  A system based on a molecular cage, in which bisdiazonium, bispyridinium, and anthraquinone guests can be complexed to the host sequentially through the application of suitable stimuli, is reported.

  DOI：

  10.1021/ol901873m

文献信息

• Conjugated monomers and polymers and preparation and use thereof
  申请人：Marks Tobin J.

  公开号：US20090036643A1

  公开（公告）日：2009-02-05

  Disclosed are new conjugated compounds (e.g., monomers and polymers) that include ladder-type moieties which can be used for preparing semiconducting materials. Such conjugated compounds can exhibit high n-type carrier mobility and/or good current modulation characteristics. Compounds of the present teachings also can exhibit ambipolar semiconducting activity. In addition, the compounds of the present teachings can possess certain processing advantages such as solution-processability and/or good stability in ambient conditions.

  披露了包括阶梯型结构单元的新的共轭化合物（例如，单体和聚合物），可用于制备半导体材料。这种共轭化合物可以表现出高n型载流子迁移率和/或良好的电流调制特性。本教导的化合物还可以表现出双极半导体活性。此外，本教导的化合物可以具有某些加工优势，如可溶性加工性和/或在环境条件下良好的稳定性。
• Zinc-porphyrins functionalized with redox-active metal peripherals: enhancement of dπ–pπ interaction leading to unique assembly and redox-triggered remote switching of fluorescence
  作者：Masahito Murai、Manabu Sugimoto、Munetaka Akita

  DOI：10.1039/c3dt51675j

  日期：——

  intramolecular photoinduced electron transfer from the MCp*(dppe) moieties to the porphyrin chromophores in the excited states. The emission is recovered by subsequent reduction of the MCp*(dppe) fragments. Thus, the fluorescence from the porphyrin moieties is switched off and on upon oxidation and subsequent reduction, respectively. The iron acetylide complex 1 can assemble with nitrogen-donors including pyridine

  小说 卟啉-MCP *（DPPE）偶联物与乙炔连接物，POR-C CMCP *（DPPE）（POR =（5,15-diarylporphinato）锌（II）中，Cp * =η 5 -C 5我5，dppe = 1,2-双（二苯基膦基）乙烷; 合成了M /芳基＝ Fe /苯基（1），Fe / 3，5-二叔丁基苯基（2），Ru /苯基（3））。吸收和荧光光谱研究与电化学研究相结合，揭示了卟啉部分与给电子的MCp *（dppe）片段之间有很强的相互作用。氧化铁共轭物1的卟啉核可生成支配基1 2+，其自发地与其单阳离子对应物1 +结合形成稳定的π自由基三阳离子二聚体[ 1 2 ] 3+，而络合物2和3进行简单的氧化而不会形成这种二聚体。此外，卟啉环与MCp *（dppe）片段之间的分子内电荷转移导致在可见光区域出现电荷转移吸收带。还发现在氧化时，通过分子内光诱导的电子从MCp *（dppe）部分向
• Single-layer organic el device
  申请人：Isobe Shinichiro

  公开号：US20070116981A1

  公开（公告）日：2007-05-24

  Disclosed is an organic EL dye enabling to provide an organic EL device which is capable of emitting a light at a low voltage even when it has a single layer structure. Also disclosed is an organic EL device using such an organic EL dye. The organic EL dye is represented by the general formula (1): (Y—L)nXm wherein x is an n-valent charge-transporting group, Y is a light-emitting group, L is a linking group bonding the charge-transporting group and the light-emitting group, and m and n are respectively an integer not less than 1.

  本发明公开了一种有机EL染料，能够提供一种能够在低电压下发光的有机EL器件，即使该器件具有单层结构。还公开了使用这种有机EL染料的有机EL器件。该有机EL染料由通式（1）表示：（Y-L）nXm，其中X是n价输运基团，Y是发光基团，L是连接基团，连接输运基团和发光基团，m和n分别是不小于1的整数。
• CAPPED STRUCTURE ORGANIC FILM COMPOSITIONS
  申请人：Cöté Adrien P.

  公开号：US20120029236A1

  公开（公告）日：2012-02-02

  A capped structured organic film comprising a plurality of segments and a plurality of linkers arranged as a covalent organic framework, wherein the structured organic film may be a multi-segment thick structured organic film.

  一种带有盖子的结构有机薄膜，包括多个片段和多个链接剂，排列成共价有机框架。其中，这种结构有机薄膜可以是多片段厚度的结构有机薄膜。
• COMPOSITE STRUCTURED ORGANIC FILMS
  申请人：HEUFT Matthew A.

  公开号：US20100227157A1

  公开（公告）日：2010-09-09

  A structured organic film with an added functionality comprising a plurality of segments and a plurality of linkers arranged as a covalent organic framework, wherein the structured organic film may be a multi-segment thick structured organic film.

  一种具有附加功能的有序有机薄膜，包括多个片段和多个连接剂，排列成共价有机框架，其中有序有机薄膜可以是多片段厚有序有机薄膜。