vinyl-benzylsulfonic acid | 743400-68-2

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: vinyl-benzylsulfonic acid
• 英文别名: 1-Phenylprop-2-ene-1-sulfonic acid
• CAS: 743400-68-2
• 化学式: C₉H₁₀O₃S
• 分子量: 198.243
• InChiKey: CBQFBEBEBCHTBK-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  1.5
• 重原子数：
  13
• 可旋转键数：
  3
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.11
• 拓扑面积：
  62.8
• 氢给体数：
  1
• 氢受体数：
  3

反应信息

• 作为产物：
  描述：

  (E)-methyl cinnamyl carbonate 在 palladium diacetate 、 1,2-双(二苯基膦)乙烷 、 sodium sulfite 作用下， 以 乙醇 、 水 为溶剂， 以35.2 mg的产率得到(E)-3-phenylprop-2-ene-1-sulfonic acid
  参考文献：
  名称：

  Synthesis of allylic sulfonic acids via regioselective Pd-catalyzed allylic substitutions of Na 2 SO 3

  摘要：

  Palladium-catalyzed allylic sulfonations of the linear allylic carbonates with sodium sulfite (Na2SO3) were accomplished under mild conditions. This method gave allylic sulfonic acids in good to excellent yields with high level of regioselectivities. (C) 2015 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.tetlet.2015.10.077

文献信息

• Process for preparing high molar mass polymers
  申请人：Doherty A. S. Erin

  公开号：US20060127351A1

  公开（公告）日：2006-06-15

  The present invention describes processes for preparing water-compatible anionic polymers of high molar mass via water-in-oil polymerization.

  本发明描述了通过水包油聚合法制备高分子量水相相容的阴离子聚合物的过程。
• ALKOXYLATES OF S-VINYLTHIOALKANOLS
  申请人：BASF SE

  公开号：US20160264691A1

  公开（公告）日：2016-09-15

  Unsaturated compounds of the general formula (I) where R 1 , R 2 , R 3 are the same or different and are each independently H, CH 3 , R 4 is a linear or branched C 1 -C 30 -alkylene, R 5 , R 6 are the same or different and are each independently, H, C 1 -C 20 -alkyl, C 3 -C 15 -cycloalkyl, aryl, —CH 2 —O—C 1 -C 20 -alkyl, —CH 2 —O—C 2 -C 20 -alkenyl, where R 5 and R 6 may together form a C 3 -C 6 -alkylene, R 7 , is the same or different and is independently, H, C 1 -C 4 -alkyl, R 8 is C 1 -C 22 -alkyl, C 2 -C 22 -alkenyl, and n is an integer from 2 to 200. Mixtures and polymers comprising compounds of the general formula (I). A method for preparing polymers wherein a free-radical polymerization of monomers comprising unsaturated compounds of the general formula (I) is carried out. A process for preparing polymers comprising polymer-analogous reactions. The use of polymers comprising compounds (I) as cement additives, grinding aids in the production of cement, additives to hydraulic binders, concrete plasticizers, reactive plasticizers for preparing plastics, rubber or latex, associative thickeners and antioxidants, or for preparing polyether siloxanes. Mixtures comprising such polymers.

  通式（I）中未饱和化合物，其中R1、R2、R3相同或不同，且每个独立地为H、CH3；R4为线性或支链状C1-C30-烷基；R5、R6相同或不同，且每个独立地为H、C1-C20-烷基、C3-C15-环烷基、芳香基，-CH2-O-C1-C20-烷基、-CH2-O-C2-C20-烯基，其中R5和R6可以共同形成C3-C6-烷基；R7相同或不同，且每个独立地为H、C1-C4-烷基；R8为C1-C22-烷基、C2-C22-烯基；n为2到200的整数。混合物和包含通式（I）化合物的聚合物。一种制备聚合物的方法，其中进行了包含通式（I）未饱和化合物的单体的自由基聚合。一种制备聚合物的过程，其中包括聚合类反应。包含化合物（I）的聚合物的用途，作为水泥添加剂、水泥生产中的磨剂、水泥基材料的添加剂、混凝土增塑剂、制备塑料、橡胶或乳胶的反应性增塑剂、联合增稠剂和抗氧化剂或制备聚醚硅氧烷。包含这种聚合物的混合物。
• Non-aqueous absorbent and use thereof
  申请人：Sumiya Takashi

  公开号：US20050136247A1

  公开（公告）日：2005-06-23

  A non-aqueous absorbent comprising a crosslinked polymer which contains a structural unit having a carboxyl group and/or a sulfonate group in an amount of 20 to 100% weight in its molecule and in which from 30 to 100% by mol of the protons in the carboxyl group and/or the sulfonate group have been substituted by onium cations; a non-aqueous gel made of this non-aqueous absorbent and an organic solvent; and a non-aqueous absorbent sheet and a non-aqueous absorbent agent containing the non-aqueous absorbent. Because of having excellent capabilities of absorbing and holding various organic solvents such as alcohols and gelating, these materials are usable for various purposes, for example, lithium batteries, alcohol-based bactericidal materials or alcohol-based bactericides, cold insulating materials or cold insulators, gel sheets for cooling, fuel compositions for solid fuels or solid fuels using the same, fragrance materials or fragrances, patch materials or patches, insecticidal compositions or insecticides, fuel stores for fuel batteries or fuel batteries using the same.

  一种非水吸收剂，包含交联聚合物，其分子中含有具有羧基和/或磺酸基的结构单元，其含量为20至100％重量，并且其中羧基和/或磺酸基中的30至100％摩尔的质子已被离子上离子替代物取代；由此制成的非水凝胶和有机溶剂；以及含有非水吸收剂的非水吸收剂片和非水吸收剂剂。由于具有吸收和保持各种有机溶剂（如醇类）的能力，以及凝胶化，这些材料可用于各种用途，例如锂电池，醇基杀菌材料或醇基杀菌剂，冷绝缘材料或冷绝缘材料，用于冷却的凝胶片，用于固体燃料的燃料组合物或使用相同的固体燃料，香料材料或香料，贴片材料或贴片，杀虫组合物或杀虫剂，燃料电池的燃料存储器或使用相同的燃料电池。
• Anionic polymers as toxin binders and antibacterial agents
  申请人：Kurtz Isabelle Bacon Caroline

  公开号：US20060029568A1

  公开（公告）日：2006-02-09

  The present invention relates to a method of inhibiting a toxin in an animal, such as a human, by administering to the animal a therapeutically effective amount of a polymer having a plurality of pendant acid functional groups which are directly attached to the polymer backbone or attached to the polymer backbone by a spacer group. The spacer group can have a length in the range from 0 to about 20 atoms. The toxin is, typically, an exotoxin secreted by a pathogenic microorganism, such as a bacterium.

  本发明涉及一种抑制动物中毒素的方法，例如人类，通过向动物施用具有多个悬垂酸性功能基团的聚合物的治疗有效量，这些基团直接连接到聚合物骨架或通过一个间隔基团连接到聚合物骨架。间隔基团的长度可以在0到大约20个原子的范围内。毒素通常是由致病微生物（例如细菌）分泌的外毒素。
• Polyelectrolyte membrane and production method therefor
  申请人：Kinouchi Masayuki

  公开号：US20050221193A1

  公开（公告）日：2005-10-06

  A polymer electrolyte membrane comprising a microporous polymer membrane having pores penetrating through the opposite sides thereof. The microporous polymer membrane holds a mixture of a polymer and a molten salt at a weight ratio of 1/99 to 99/1 and/or a molten salt. The polymer electrolyte membrane is inexpensive, durable, excellent in mechanical strength, excellent in structural retention in high temperatures, and capable of stably holding a molten salt in its porous polymer membrane structure, shows high heat resistance, and secures high ionic conductivity in the absence of water or a solvent and is therefore useful in fuel cells, secondary batteries, electric double layer capacitors, electrolytic capacitors, and the like.

  一种聚合物电解质膜，包括具有贯穿其相对两侧的孔隙的微孔聚合物膜。微孔聚合物膜保持聚合物和熔盐的混合物，重量比为1/99至99/1和/或熔盐。聚合物电解质膜廉价、耐用、机械强度优异、在高温下具有良好的结构保持性，能够稳定地保持熔盐在其多孔聚合物膜结构中，具有高耐热性，且在无水或溶剂的情况下保持高离子导电性，因此在燃料电池、二次电池、电双层电容器、电解电容器等方面非常有用。