O-butyl butylthiocarbamate | 19708-87-3

• 分子结构分类: 有机化合物 - 有机硫化合物 - 硫代羰基化合物
• 英文名称: O-butyl butylthiocarbamate
• 英文别名: O-butyl N-butylcarbamothioate
• CAS: 19708-87-3
• 化学式: C₉H₁₉NOS
• 分子量: 189.322
• InChiKey: BODTTXPZURZGJI-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3
• 重原子数：
  12
• 可旋转键数：
  7
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.89
• 拓扑面积：
  53.4
• 氢给体数：
  1
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  O-butyl butylthiocarbamate 、 2-Butenoic acid, 3-[(1E)-[(phenylamino)carbonyl]azo]-, methyl ester,(2E)- 以 甲醇 为溶剂， 以63%的产率得到2-[(Z)-Butylimino]-4-methyl-3-(3-phenyl-ureido)-2,3-dihydro-thiazole-5-carboxylic acid methyl ester
  参考文献：
  名称：

  2-烷基亚氨基噻唑啉的简便高产直接合成

  摘要：

  1,2-二氮杂-1,3-丁二烯很容易通过杂迈克尔加成/环化反应与O-烷基硫代氨基甲酸酯衍生物反应，在温和条件下直接以高产率得到2-烷基亚氨基噻唑啉。

  DOI：

  10.1055/s-2004-825610
• 作为产物：
  描述：

  bis-butoxythiocarbonyl-trisulfane 、 正丁胺 以91%的产率得到
  参考文献：
  名称：

  PESTOVA G. A.; GNATYUK P. P.; IGNATOV V. A.; SMIRNOV R. P., IZV. VUZOV. XIMIYA I XIM. TEXNOL., 1979, 22, HO 7, 805-808

  摘要：

  DOI：

文献信息

• PRESSURE-SENSITIVE ADHESIVE SHEET WITH IMPROVED WEATHERABILITY
  申请人：NITTO BELGIUM N.V

  公开号：EP3786242A1

  公开（公告）日：2021-03-03

  The disclosure relates to a pressure-sensitive adhesive composition comprising: an acrylic polymer with acrylic acid functional groups; an epoxy-based crosslinking agent at a content of 3 parts per weight or more based on 100 parts per weight of the acrylic polymer; and a UV-absorber at a content of 2 parts per weight or more based on 100 parts per weight of the acrylic polymer. In addition, a surface protection sheet comprising a carrier and a pressure-sensitive adhesive layer formed of the aforementioned pressure-sensitive adhesive composition is described, as well as the use of the aforementioned surface protection sheet for outdoor surface protection. The surface protection sheet exhibits excellent weatherability resistance, adhesion properties on different substrate surfaces, oxidation resistance, advantageous anti-residue properties upon peeling and low surface contaminating properties.

  本公开涉及一种压敏胶组合物，该组合物包括：一种具有丙烯酸官能团的丙烯酸聚合物；一种环氧基交联剂，以每 100 重量份的丙烯酸聚合物为基准，其含量为 3 重量份或以上；以及一种紫外线吸收剂，以每 100 重量份的丙烯酸聚合物为基准，其含量为 2 重量份或以上。此外，还介绍了一种由载体和由上述压敏胶组合物形成的压敏胶层组成的表面保护膜，以及将上述表面保护膜用于户外表面保护的方法。该表面保护膜具有优异的耐候性、在不同基材表面的粘附性、抗氧化性、剥离后的抗残留性以及低表面污染性。
• Pressure sensitive adhesive composition, articles made therewith and method of use
  申请人：3M Innovative Properties Company

  公开号：US20030215630A1

  公开（公告）日：2003-11-20

  A pressure sensitive adhesive composition is described, comprising the reaction product of a copolymer and a bisamide crosslinking agent, (A) the copolymer comprising the reaction product of (i) a (meth)acrylate ester of a non-tertiary alcohol in which the alkyl group contains between 1 and 4 carbon atoms, inclusive, and (ii) a carboxylic acid-functional, ethylenically unsaturated co-monomer, and (B) a bisamide crosslinking agent having the formula: 1 where, R 1 and R 3 independently, are selected from the group consisting of H and C n H 2n+1 , n is an integer ranging from 1 to 5, R 2 is a divalent radical selected from the group consisting of benzeno (—C 6 H 4 —), substituted benzeno, triazine, C m H 2m , and combinations thereof, m is an integer ranging from 1 to 10, and the relative amounts of the carboxylic acid-functional, ethylenically unsaturated co-monomer and the bisamide crosslinking agent providing a ratio of the number of equivalents of amide groups to the number of equivalents of carboxylic acid groups of less than about 0.1. Articles made with the pressure sensitive adhesive composition and methods for its use are also described.

  描述了一种压敏型粘合剂组合物，包括共聚物和双酰胺交联剂的反应产物，(A)共聚物包括(i)非叔醇的(甲基)丙烯酸酯（其中烷基含有 1 至 4 个碳原子（含 4 个））和(ii)具有羧酸官能团的乙烯基不饱和共聚单体，以及(B)具有以下式子的双酰胺交联剂的反应产物： 1 其中 R 1 和 R 3 分别选自 H 和 C 组成的组 n H 2n+1 , n 是 1 至 5 的整数、 R 2 是二价基，选自由苯并[-C 6 H 4 -）、取代的苯并芘、三嗪、C m H 2m 及其组合、 m 是 1-10 之间的整数，以及 羧酸官能团、乙烯基不饱和共聚单体和双酰胺交联剂的相对量，使酰胺基团的当量数与羧酸基团的当量数之比小于约 0.1。此外，还描述了用压敏胶组合物制成的物品及其使用方法。
• US6893718B2
  申请人：——

  公开号：US6893718B2

  公开（公告）日：2005-05-17
• [EN] PRESSURE SENSITIVE ADHESIVE COMPOSITION, ARTICLES MADE THEREWITH AND METHOD OF USE<br/>[FR] COMPOSITION D'ADHESIF AUTOCOLLANT, ARTICLES REALISES AVEC CETTE COMPOSITION ET PROCEDE D'UTILISATION
  申请人：3M INNOVATIVE PROPERTIES CO

  公开号：WO2003099954A2

  公开（公告）日：2003-12-04

  A pressure sensitive adhesive composition is described, comprising the reaction product of a copolymer and a bisamide crosslinking agent, (A) the copolymer comprising the reaction product of (i) a (meth)acrylate ester of a non-tertiary alcohol in which the alkyl group contains between 1 and 4 carbon atoms, inclusive, and (ii) a carboxylic acid-functional, ethylenically unsaturated co-monomer, and (B) a bisamide crosslinking agent having the Formula: (I) where, R1 and R3 independently, are selected from the group consisting of H and CnH2n+1, n is an integer ranging from 1 to 5, R2 is a divalent radical selected from the group consisting of benzeno (-C6H4-), substituted benzeno, triazine, CmH2m, and combinations thereof, m is an integer ranging from 1 to 10, and the relative amounts of the carboxylic acid-functional, ethylenically unsaturated co-monomer and the bisamide crosslinking agent providing a ratio of the number of equivalents of amide groups to the number of equivalents of carboxylic acid groups of less than about 0.1. Articles made with the pressure sensitive adhesive composition and methods for its use are also described.
• PESTOVA G. A.; GNATYUK P. P.; IGNATOV V. A.; SMIRNOV R. P., IZV. VUZOV. XIMIYA I XIM. TEXNOL., 1979, 22, HO 7, 805-808
  作者：PESTOVA G. A.、 GNATYUK P. P.、 IGNATOV V. A.、 SMIRNOV R. P.

  DOI：——

  日期：——