1-(Dichloromethyl)-4-ethylbenzene | 54789-29-6

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: 1-(Dichloromethyl)-4-ethylbenzene
• CAS: 54789-29-6
• 化学式: C₉H₁₀Cl₂
• 分子量: 189.08
• InChiKey: PWKUMFYUILTTMD-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3.8
• 重原子数：
  11
• 可旋转键数：
  2
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.33
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  0

反应信息

• 作为反应物：
  描述：

  1-(Dichloromethyl)-4-ethylbenzene 、 六氯乙烷 、 sodium hydroxide 、 十二烷基三甲基氯化铵 以89%的产率得到
  参考文献：
  名称：

  CHUPP, J. P.;GRABIAK, R. C.;LESCHINSKY, K. L.;NEUMANN, T. L., SYNTHESIS, BRD, 1986, N 3, 224-226

  摘要：

  DOI：

文献信息

• Process for preparing substituted benzotrichloride compounds
  申请人：Monsanto Company

  公开号：US04593144A1

  公开（公告）日：1986-06-03

  This invention pertains to a process for preparing substituted and unsubstituted benzotrichlorides. The process generally involves reacting the starting compound with a perchloroalkane with presence of base and a phase transfer catalyst.

  本发明涉及一种制备取代和未取代苯并三氯化物的过程。该过程通常涉及在碱和相转移催化剂的存在下，将起始化合物与高氯酸盐烷基反应。
• A process for preparing substituted benzotrichloride compounds
  申请人：Monsanto Company

  公开号：EP0150169A2

  公开（公告）日：1985-07-31

  This invention pertains to a process for preparing substituted and unsubstituted benzotrichlorides. The process generally involves reacting the starting compound with a perchloroalkane with presence of base and a phase transfer catalyst.

  本发明涉及一种制备取代和未取代的苯并三氯化物的工艺。 该工艺一般包括在碱和相转移催化剂存在的情况下，使起始化合物与全氯代烃反应。
• A method of producing an aromatic ketone and an aromatic ketone composition containing it
  申请人：TORAY INDUSTRIES, INC.

  公开号：EP1053990A2

  公开（公告）日：2000-11-22

  In a method of producing an aromatic ketone an aromatic compound having an R-CH2 group ( R denotes an alkyl group, aryl group, allyl group or aralkyl group) is oxidised in liquid phase by an oxygen-containing gas in the presence of a catalyst comprising a heavy metal compound and at least one compound selected from (1) ammonia, (2) organic basic compounds and (3) onium halides while the water produced in the reaction is removed from the reaction solution. An aromatic ketone composition produced by the process comprises the aromatic ketone and 10 ppm to 3 wt% of at least one compound selected from: a benzene derivative of the formula (II) a vinylbenzene of the formula (III) a benzaldehyde of the formula (IV) where X is a substituent; n is zero or 1 to 5; R is alkyl, aryl, allyl or aralkyl and R1 is hydrogen, alkyl, aryl, allyl or aralkyl.

  在一种生产芳香酮的方法中，具有 R-CH2 基团（R 表示烷基、芳基、烯丙基或芳烷基）的芳香化合物在液相中被含氧气体氧化，催化剂包括重金属化合物和至少一种选自(1)氨、(2)有机碱性化合物和(3)卤化铌的化合物，同时从反应溶液中除去反应中产生的水。 由该工艺制得的芳香酮组合物包括芳香酮和 10ppm 至 3 wt%的至少一种选自以下的化合物： 式 (II) 的苯衍生物 式 (III) 的乙烯基苯 式 (IV) 的苯甲醛 其中 X 为取代基；n 为零或 1 至 5；R 为烷基、芳基、烯丙基或芳烷基，R1 为氢、烷基、芳基、烯丙基或芳烷基。
• Process for producing benzoyl chlorides
  申请人：MITSUBISHI GAS CHEMICAL COMPANY, INC.

  公开号：EP0849253B1

  公开（公告）日：2001-05-16
• MONODISPERSE CHLOROMETHYLSTYRENE POLYMER AND PRODUCING METHOD THEREOF
  申请人：Kambara Riina

  公开号：US20120059137A1

  公开（公告）日：2012-03-08

  Provided is a monodisperse polymer of chloromethylstyrene as a bifunctional compound. Chloromethylstyrene is purified to a purity of at least 99% and polymerized preferably using a RAFT reagent.