S-(3,5-二-叔-丁基-4-羟基苯甲基)O-乙基二硫酸酯 | 15367-50-7

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 中文名称: S-(3,5-二-叔-丁基-4-羟基苯甲基)O-乙基二硫酸酯
• 英文名称: S-3,5-di(tert-butyl)-4-hydroxybenzyl-O-ethylxanthate
• 英文别名: O-ethyl (3,5-ditert-butyl-4-hydroxyphenyl)methylsulfanylmethanethioate
• CAS: 15367-50-7
• 化学式: C₁₈H₂₈O₂S₂
• mdl: MFCD00778884
• 分子量: 340.551
• InChiKey: OJILBRJTCQPLCP-UHFFFAOYSA-N

物化性质

• 沸点：
  404.4±33.0 °C(Predicted)
• 密度：
  1.090±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  6.5
• 重原子数：
  22
• 可旋转键数：
  7
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.61
• 拓扑面积：
  86.8
• 氢给体数：
  1
• 氢受体数：
  4

反应信息

• 作为产物：
  描述：

  2,6-二叔丁基对(二甲氨甲基)苯酚 以 丙酮 为溶剂， 反应 2.5h， 生成 S-(3,5-二-叔-丁基-4-羟基苯甲基)O-乙基二硫酸酯
  参考文献：
  名称：

  Acetyl chloride-3,5-di(tert-butyl)-4-hydroxy-N,N-dimethylbenzylamme salt in the benzylation of organic and inorganic sulfur-containing compounds

  摘要：

  The reactions of the quaternary acylammonium salt formed on treatment of 3,5-di-tert-butyl-4-hydroxy-N,N-dimethylbenzylamine with acetyl chloride, with various organic and inorganic sulfur-containing compounds were studied. The possibility of using this salt for the introduction of a sterically hindered phenol moiety in various sulfur-containing compounds was shown.

  DOI：

  10.1007/bf00699143

文献信息

• Acetyl chloride-3,5-di(tert-butyl)-4-hydroxy-N,N-dimethylbenzylamme salt in the benzylation of organic and inorganic sulfur-containing compounds
  作者：D. B. Gorbunov、V. N. Voznesenskii、V. V. Ershov、G. A. Nikiforov

  DOI：10.1007/bf00699143

  日期：1994.1

  The reactions of the quaternary acylammonium salt formed on treatment of 3,5-di-tert-butyl-4-hydroxy-N,N-dimethylbenzylamine with acetyl chloride, with various organic and inorganic sulfur-containing compounds were studied. The possibility of using this salt for the introduction of a sterically hindered phenol moiety in various sulfur-containing compounds was shown.