[EN] CONJUGATED POLYELECTROLYTES AND METHODS OF USING THE SAME<br/>[FR] POLYÉLECTROLYTES CONJUGUÉS ET LEURS PROCÉDÉS D'UTILISATION
申请人:WHITTEN DAVID G
公开号:WO2016115362A1
公开(公告)日:2016-07-21
Various embodiments disclosed relate to conjugated polyelectrolytes and methods of using the same. Various embodiments provide a conjugated polyelectrolyte including a subunit having the structure -R1-Y-R2-Z-. At each occurrence, R1 is independently chosen from 1,4-bonded phenylene substituted by -X-R3-R4 j times and 2,5-bonded thiophene substituted by -X-R3-R4 j times. At each occurrence, Y is independently chosen from a bond and -C≡C-. At each occurrence, R2 is independently chosen from a bond, a substituted or unsubstituted phenylene, thiophenylene, azulenylene, heptalenylene, biphenylene, indacenylene, fluorenylene, phenanthrenylene, triphenylenylene, pyrenylene, naphthacenylene, chrysenylene, biphenylenylene, anthracenylene, and naphthylene. At each occurrence, Z is independently chosen from a bond and -C≡C-. The variables j, R3, and R4 are as defined herein.
披露的各种实施方式涉及共轭聚电解质及其使用方法。各种实施方式提供了一种共轭聚电解质,包括具有结构-R1-Y-R2-Z-的亚单位。在每次出现时,R1独立选择自1,4-键合的苯亚甲基,被-X-R3-R4 j次取代,和2,5-键合的噻吩亚甲基,被-X-R3-R4 j次取代。在每次出现时,Y独立选择自一个键合和-C≡C-。在每次出现时,R2独立选择自一个键合,一个取代或未取代的苯亚甲基、噻吩亚甲基、蓝紫菁亚甲基、庚二亚甲基、联苯亚甲基、茚苯亚甲基、芴亚甲基、菲亚甲基、菲啶亚甲基、芘亚甲基、萘茚亚甲基、蒽亚甲基和萘亚甲基。在每次出现时,Z独立选择自一个键合和-C≡C-。变量j、R3和R4如本文所定义。