phenyl-acetaldehyde-(N-phenyl oxime ) | 145397-08-6

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: phenyl-acetaldehyde-(N-phenyl oxime )
• 英文别名: Phenyl-acetaldehyd-(N-phenyl-oxim)；N-Phenyl-C-benzyl-nitron；Phenaethylidenanilin-N-oxid；N,2-diphenylethanimine oxide
• CAS: 145397-08-6
• 化学式: C₁₄H₁₃NO
• 分子量: 211.263
• InChiKey: KSCFDLHNSAFJDZ-QINSGFPZSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  2.6
• 重原子数：
  16
• 可旋转键数：
  3
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.07
• 拓扑面积：
  28.8
• 氢给体数：
  0
• 氢受体数：
  1

反应信息

• 作为反应物：
  描述：

  甲基苯基亚砜 、 phenyl-acetaldehyde-(N-phenyl oxime ) 在 lithium diisopropyl amide 作用下， 生成 (R_S^*,1R^*)N-phenyl-N-(1-benzyl-2-(phenylsulfinyl))ethylhydroxylamine 、 (R_S^*,1S^*)N-phenyl-N-(1-benzyl-2-(phenylsulfinyl))ethylhydroxylamine
  参考文献：
  名称：

  将锂化的甲基苯基亚砜添加到硝酮中的立体化学

  摘要：

  报道了锂化的甲基苯基亚砜与硝酮反应的立体化学结果和非对映选择性。主要的非对映异构体产物的相对立体化学是通过与锂化外消旋甲基苯基亚砜与亚胺反应的主要的非对映异构体产物的化学相关性来确定的。

  DOI：

  10.1016/s0040-4020(01)85627-1
• 作为产物：
  描述：

  苯乙醛 、 苯基羟胺 在 乙醇 作用下， 生成 phenyl-acetaldehyde-(N-phenyl oxime )
  参考文献：
  名称：

  Minor- and trace-element zoning in plagioclase: implications for magma chamber processes at Parinacota volcano, northern Chile

  摘要：

  Textural and compositional zoning in plagioclase phenocrysts in a sample from Parinacota volcano (Chile) was investigated using backscattered electron images and electron microprobe analysis of major and trace elements. Large (2 mm) oscillatory zoned crystals (type 1) with resorption surfaces of moderate An discontinuities (less than or equal to 10% An) and decreasing trace-element contents (Sr. Mg, Ti) towards the rim reflect melt differentiation and turbulent convection in the main magma body. Early recharge with a low-Sr mafic magma is seen in the core. Small-scale Sr variations in the core indicate limited diffusion and thus residence and differentiation times of the magma shorter than a few thousand years. Smaller crystals (type II) with low trace-element An ratio reflect the influence of an HO-rich melt probably from a differentiated boundary layer. Closed-system in-situ crystallisation. mafic magma recharge and the role of a water-rich differentiated boundary layer can be distinguished from the An-trace element relationships. Crystals apparently move relatively freely between different parts and regimes in the magma chamber. evidence for "convective crystal dispersion". High-Sr type 11 crystals indicate an earlier input of Sr-rich mafic magma. Recharge of two distinct mafic magma types is thus identified (high-Sr and low-Sr), which must have been present - at increasing recharge rates with time - in the plumbing system throughout the volcano's history.

  DOI：

  10.1007/s00410-002-0351-z