Pigment dispersions containing copolymer pigment dispersants and methods of grinding pigment dispersions
申请人:HÜLS AMERICA INC.
(a Delaware corporation)
公开号:EP0033213A2
公开(公告)日:1981-08-05
Low-molecular weight addition copolymers of (1) (meth) acrylic acid esters of alcohols such as methanol and butanol with (2) (meth) acrylic acid esters of alcohols such as N-(β-hydroxyethyl)oxazolidine, optionally including (3) α,β-ethylenically-unsaturated monomers such as (meth)acrylic acid, (where in each instance "(meth)acrylic" means acrylic or methacrylic or both) are used as dispersants for inorganic and organic pigments and colourants which are insoluble in organic solvents, for lacquers. These pigment dispersants are compatible with practically all types of lacquer resins, such as vinyls, nitrocellulose and alkyds, and also with many other types of lacquer film-forming materials. Usually, when small amounts of unsaturated carboxylic acids, or other polar monomers and combinations thereof, are incorporated in the polymers, they become improved pigment dispersants. Such pigment dispersions, unexpectedly, can be let down with many types of synthetic resins and used by air-drying or baking the coated articles. Lacquers for metals, paints and printing inks are examples of uses for such blends.
(1)甲醇和丁醇等醇的(甲基)丙烯酸酯与(2)N-(β-羟乙基)恶唑烷等醇的(甲基)丙烯酸酯的低分子量加成共聚物,可选择包括(3)α、β-乙烯基不饱和单体,如(甲基)丙烯酸(这里的"(甲基)丙烯酸 "是指丙烯酸或甲基丙烯酸或两者),可用作不溶于有机溶剂的无机和有机颜料和着色剂的分散剂,如漆。这些颜料分散剂几乎与所有类型的漆树脂兼容,如乙烯基、硝化纤维和醇酸树脂,也与许多其他类型的漆成膜材料兼容。通常情况下,当聚合物中加入少量不饱和羧酸或其他极性单体及其组合时,它们就会成为经过改良的颜料分散剂。出乎意料的是,这种颜料分散剂可以与多种类型的合成树脂混合,并通过风干或烘烤涂覆物品来使用。金属漆、油漆和印刷油墨就是此类混合物的应用实例。