benzo[b]naphtho[1,2,3,4-pqr]perylene | 53156-62-0

• 分子结构分类: 有机化合物 - 苯类化合物 - 芘
• 英文名称: benzo[b]naphtho[1,2,3,4-pqr]perylene
• 英文别名: Benzonaphtho<1,2,3,4-ghi>perylen；Octacyclo[16.12.0.02,11.03,8.04,29.012,17.019,24.025,30]triaconta-1(18),2(11),3(8),4,6,9,12,14,16,19,21,23,25(30),26,28-pentadecaene
• CAS: 53156-62-0
• 化学式: C₃₀H₁₆
• 分子量: 376.457
• InChiKey: BLVGGEGKRGWNNL-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  8.6
• 重原子数：
  30
• 可旋转键数：
  0
• 环数：
  8.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  0

反应信息

• 作为产物：
  描述：

  4,5-Diphenyltriphenylen 在 碘 作用下， 以 苯 为溶剂， 生成 benzo[b]naphtho[1,2,3,4-pqr]perylene
  参考文献：
  名称：

  Photodehydrocyclizations in stilbene-like compounds. X. Rearrangements in the photocyclization of 4,5-diphenyltriphenylene and 4,5-diphenylphenanthrene

  摘要：

  DOI：

  10.1021/ja00821a043

文献信息

• Unsymmetrically Extended Polyfused Aromatics Embedding Coronene and Perylene Frameworks: Syntheses and Properties
  作者：Sushil Kumar、Man-Tzu Ho、Yu-Tai Tao

  DOI：10.1021/acs.orglett.5b03291

  日期：2016.1.15

  A series of polyfused aromatics containing coronene and perylene in their frameworks was successfully constructed by a modified Ramirez-Corey-Fuchs reaction as the key reaction. Typical six-membered annulation and atypical five-membered annulation through controlled reaction conditions led to a range of extensively conjugate aromatics as possible candidates for organic semiconductors. A significant p-type field-effect mobility of 0.42-0.64 cm(2)/V center dot s was obtained from one of the derivatives, dibenzo[a,d]coronene.
• Photodehydrocyclizations in stilbene-like compounds. X. Rearrangements in the photocyclization of 4,5-diphenyltriphenylene and 4,5-diphenylphenanthrene
  作者：A. H. A. Tinnemans、W. H. Laarhoven

  DOI：10.1021/ja00821a043

  日期：1974.7