[4-(Ethenyloxy)phenyl](phenyl)methanone | 437614-72-7

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: [4-(Ethenyloxy)phenyl](phenyl)methanone
• 英文别名: (4-ethenoxyphenyl)-phenylmethanone
• CAS: 437614-72-7
• 化学式: C₁₅H₁₂O₂
• 分子量: 224.25
• InChiKey: BUCYOCHOLDPJFS-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3.9
• 重原子数：
  17
• 可旋转键数：
  4
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  26.3
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为产物：
  描述：

  4-羟基-二苯甲酮 、 N-甲基吡咯烷酮 在 Zinc naphthenate 氮气 、 乙炔 、 polyethylene glycol 作用下， 20.0~190.0 ℃ 、16.0 kPa 条件下， 反应 12.0h， 以This gave a total of 522 g of 4-vinyloxybenzophenone having a purity of from 96 to 99% by weight的产率得到[4-(Ethenyloxy)phenyl](phenyl)methanone
  参考文献：
  名称：

  Uv-crosslinkable copolymers

  摘要：

  本发明涉及使用公式I中的苯乙酮或苯基苯酮衍生物，其中R为未取代或取代的C1到C3烷基，C6到C10芳基或含有6到10个碳原子的芳基烷基，以及含有1到6个碳原子的烷基，作为共聚光引发剂。本发明还涉及含有公式I中的苯乙酮或苯基苯酮衍生物的共聚物，用于紫外线交联的组合物的制备过程以及使用该共聚物在紫外线交联组合物中的应用。

  公开号：

  US20050080213A1

文献信息

• Uv-crosslinkable copolymers
  申请人：Meyer Harald

  公开号：US20050080213A1

  公开（公告）日：2005-04-14

  The present invention relates to the use of acetophenone or benzophenone derivatives of the formula I where R is unsubstituted or substituted C 1 to C 3 alkyl, C 6 to C 10 aryl or aralkyl having from 6 to 10 carbon atoms in the aryl moiety and from 1 to 6 carbon atoms in the alkyl moiety as copolymerizable photoinitiators. The invention further relates to copolymers containing acetophenone or benzophenone derivatives of the formula I in copolymerized form, to processes for preparing said copolymers, and to the use of said copolymers in UV crosslinkable compositions.

  本发明涉及使用公式I中的苯乙酮或苯基苯酮衍生物，其中R为未取代或取代的C1到C3烷基，C6到C10芳基或含有6到10个碳原子的芳基烷基，以及含有1到6个碳原子的烷基，作为共聚光引发剂。本发明还涉及含有公式I中的苯乙酮或苯基苯酮衍生物的共聚物，用于紫外线交联的组合物的制备过程以及使用该共聚物在紫外线交联组合物中的应用。
• Aromatic vinyl ether compounds
  申请人：Emory University

  公开号：US20040181098A1

  公开（公告）日：2004-09-16

  Aromatic vinyl ether compounds represented by Formula (1) or by Formula (2) 1 wherein each R and R′ is a hydrogen atom or a group represented by Formula (3) 2 and wherein the remaining variables are as defined in the specification, provided that at least one pR in Formula (1) and at least one uR in Formula (2) is a Formula (3) group. These aromatic vinyl ether compounds are useful as, e.g., curing agents for cationic polymerization.

  公式（1）或公式（2）所代表的芳香基乙醚化合物，其中每个R和R'是氢原子或由公式（3）表示的基团，其余变量如规范中所定义，前提是公式（1）中至少有一个pR和公式（2）中至少有一个uR是公式（3）基团。这些芳香基乙醚化合物可用作阳离子聚合的固化剂。
• Polymers Comprising Photoinitiator Moieties and Dye Moieties
  申请人：Lambson Limited

  公开号：US20140316060A1

  公开（公告）日：2014-10-23

  The invention relates to a polymer (P) comprising at least one photoinitiator moiety (PI) and at least one dye moiety (DYE), wherein said at least one photoinitiator moiety (PI) and at least one dye moiety (DYE) are covalently linked to said polymer (P). Additionally, the invention relates to said polymer (P) being end-functionalized with optionally substituted acryloyi groups. The fact that both of these moieties are tightly bonded within the polymer, and the cross-linked polymer, means that the opportunities for leaching/migration of these components is reduced or even eliminated. Inks comprising at least one of said polymers are also provided. Methods for the manufacture of the polymers, and for printing are provided.

  本发明涉及一种聚合物（P），其包括至少一个光引发剂基团（PI）和至少一个染料基团（DYE），其中所述至少一个光引发剂基团（PI）和至少一个染料基团（DYE）与所述聚合物（P）共价连接。此外，本发明涉及所述聚合物（P）末端官能化，其具有可选的取代丙烯酰基团。这些基团都被紧密结合在聚合物中，交联的聚合物意味着这些组分的渗出/迁移机会减少甚至消除。本发明还提供了包含至少一种所述聚合物的油墨。提供了制造聚合物和印刷的方法。
• Organopolysiloxane photosensitizers and methods for their preparation
  申请人：Toray Silicone Company Limited

  公开号：EP0088842A1

  公开（公告）日：1983-09-21

  Novel photosensitizers are disclosed which are particularly useful in photopolymerizable organopolysiloxane and silicone resins. The photosensitizers are themselves organopolysiloxanes which contain at least one silicon-bonded benzophenone-containing radical. Synthesis methods are disclosed for preparing these photosensitizers which employ, as starting materials, an alkenyloxy-substituted benzophenone and a silicon compound containing at least one silicon-bonded hydrogen atom.

  本发明公开了新型光敏剂，这些光敏剂在可光聚合的有机聚硅氧烷和硅树脂中特别有用。 这些光敏剂本身是有机聚硅氧烷，含有至少一个硅键合的二苯甲酮基。 本发明公开了制备这些光敏剂的合成方法，这些方法采用烯氧基取代的二苯甲酮和含有至少一个硅键合氢原子的硅化合物作为起始原料。
• Hydrophilic gels derived from grafted photoinitiators
  申请人：Coloplast

  公开号：US10011688B2

  公开（公告）日：2018-07-03

  The invention provides a method for the manufacture of a gel, said method comprising the steps of: providing a matrix composition comprising a polymeric photoinitiator of the general formula (I): Polymer-[CR2—CHR-Spacer(PI)n]m (I) curing the matrix composition by exposing it to UV radiation and exposing the matrix composition to a swelling medium. The invention also relates to gels obtainable via the above method. The invention provides a hydrophilic gel precursor manufactured from the polymeric photoinitiator of Formula (I). Medical devices comprising the gels and hydrophilic gel precursors of the invention are provided. The invention also provides the use of a polymeric photoinitiator in the manufacture of a gel.

  本发明提供了一种凝胶的制造方法，所述方法包括以下步骤：提供一种基质组合物，其中包含通式（I）的聚合物光引发剂：聚合物-[CR2-CHR-Spacer(PI)n]m (I) 将基质组合物置于紫外线辐射下固化，并将基质组合物置于溶胀介质中。本发明还涉及可通过上述方法获得的凝胶。本发明提供了一种由式（I）的聚合物光引发剂制成的亲水性凝胶前体。本发明提供了包含本发明凝胶和亲水凝胶前体的医疗设备。本发明还提供了聚合物光引发剂在凝胶制造中的用途。