bis(4-hydroxyphenyl)(4-methylphenyl)phosphine oxide | 452310-90-6

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: bis(4-hydroxyphenyl)(4-methylphenyl)phosphine oxide
• 英文别名: Bis(4-hydroxyphenyl)-(4-methylphenyl)phosphine oxide；4-[(4-hydroxyphenyl)-(4-methylphenyl)phosphoryl]phenol
• CAS: 452310-90-6
• 化学式: C₁₉H₁₇O₃P
• 分子量: 324.316
• InChiKey: KAPZZUGRKWRWMW-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3.7
• 重原子数：
  23
• 可旋转键数：
  3
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.05
• 拓扑面积：
  57.5
• 氢给体数：
  2
• 氢受体数：
  3

反应信息

• 作为产物：
  描述：

  bis(4-methoxyphenyl)(4-methylphenyl)phosphine oxide 在 potassium bromide 、 氢溴酸 作用下， 以77%的产率得到bis(4-hydroxyphenyl)(4-methylphenyl)phosphine oxide
  参考文献：
  名称：

  Phosphine oxide hydroxyaryl mixtures with novolac resins for co-curing epoxy resins

  摘要：

  一种包括（a）单（羟基芳基）膦氧化物，（b）双（羟基芳基）膦氧化物，（c）三（羟基芳基）膦氧化物的羟基芳基膦氧化物混合物，以及可选地（d）与酚类共交联组成的三芳基、烷基或芳基磷氧化物，可用作用于交联环氧树脂的聚羟基混合物，同时赋予阻燃性。

  公开号：

  US06887950B2

文献信息

• Novel hydroxyaryl phosphine oxides, glycidyl ethers and epoxy compositions, composites and laminates derived therefrom
  申请人：——

  公开号：US20040121990A1

  公开（公告）日：2004-06-24

  The invention provides new compositions of matter that are capable of forming cross-linked polymeric materials upon reaction with various known epoxy-containing compositions. Thus, the compositions of this invention are useful in the manufacturing of prepregs and laminates for PWB applications among many other uses. Preferred compositions of this invention include substituted hydroxyarylphosphine oxide mixtures, the glycidyl ether derivatives, or the epoxy resin oligomer adducts derived therefrom. The materials provide for laminates that have higher glass transition temperatures, improved thermal stability, and that are free of halogen.

  该发明提供了新的物质组合，能够与各种已知含环氧基物质反应形成交联聚合材料。因此，该发明的组合物在制造预浸料和用于PWB应用的层压板等众多用途中非常有用。该发明的优选组合物包括取代羟基芳基膦氧混合物、环氧乙醚衍生物或由此衍生的环氧树脂寡聚物加合物。这些材料提供了具有更高玻璃化转变温度、改善热稳定性且无卤素的层压板。
• Hydroxyaryl phosphine oxides, glycidyl ethers and epoxy compositions, composites and laminates derived therefrom
  申请人：Hanson Mark V.

  公开号：US06955851B2

  公开（公告）日：2005-10-18

  The invention provides new compositions of matter that are capable of forming cross-linked polymeric materials upon reaction with various known epoxy-containing compositions. Thus, the compositions of this invention are useful in the manufacturing of prepregs and laminates for PWB applications among many other uses. Preferred compositions of this invention include substituted hydroxyarylphosphine oxide mixtures, the glycidyl ether derivatives, or the epoxy resin oligomer adducts derived therefrom. The materials provide for laminates that have higher glass transition temperatures, improved thermal stability, and that are free of halogen.

  本发明提供了新的物质组成，能够与各种已知含环氧基的物质反应形成交联聚合材料。因此，本发明的组成物在制造预浸料和PWB应用的层压板等许多用途中非常有用。本发明的首选组成物包括取代的羟基芳基膦氧混合物、环氧乙烷衍生物或由此衍生的环氧树脂寡聚物加合物。这些材料提供了具有更高玻璃化转变温度、改善热稳定性且不含卤素的层压板。
• Phosphine oxide hydroxyarl mixtures with novolac resins for co-curing epoxy resins
  申请人：Great Lakes Corporation

  公开号：US07202311B2

  公开（公告）日：2007-04-10

  There is disclosed a novel mixture of polyhydroxy phenolic curing agents, such as novolac resins blended with a mixture of mono, bis and tris hydroxyaryl phosphine oxides for co-curing epoxy resins and imparting flame resistance thereto. A preferred composition includes a mixture of monohydroxyaryl, bishydroxyaryl and trishydroxyaryl phosphine oxide and a benzoguanamine/phenol/formaldehyde terpolymer which is used along with an epoxy resin to produce flame-resistant printed wiring boards without the use of halogens.

  本发明公开了一种新型的多羟基酚固化剂混合物，例如Novolac树脂与一种单、双和三羟基芳基膦氧化物混合物，用于共固化环氧树脂并赋予其阻燃性。一种优选的组合物包括一种单羟基芳基、双羟基芳基和三羟基芳基膦氧化物混合物以及一种苯并三嗪/苯酚/甲醛共聚物，该共聚物与环氧树脂一起使用，以生产无卤素阻燃印刷电路板。
• NOVEL HYDROXYARYL PHOSPHINE OXIDES, GLYCIDYL ETHERS AND EPOXY COMPOSITIONS, COMPOSITES AND LAMINATES DERIVED THEREFROM
  申请人：Pabu Services, Inc.

  公开号：EP1363922A2

  公开（公告）日：2003-11-26
• NOVEL HYDROXYARYL PHOSPHINE OXIDES MIXTURE, GLYCIDYL ETHERS AND EPOXY COMPOSITIONS, COMPOSITES AND LAMINATES DERIVED THEREFROM
  申请人：GREAT LAKES CHEMICAL CORPORATION

  公开号：EP1363922B1

  公开（公告）日：2006-07-26