N-Methyl-9-amino-anthracen | 423125-85-3

• 分子结构分类: 有机化合物 - 苯类化合物 - 蒽
• 英文名称: N-Methyl-9-amino-anthracen
• 英文别名: [9]anthryl-methyl-amine；N-Methyl-mesoanthramin；9-Methylamino-anthracen；N-methylanthracen-9-amine
• CAS: 423125-85-3
• 化学式: C₁₅H₁₃N
• 分子量: 207.275
• InChiKey: XQMQIMWCQMZJMX-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  4.5
• 重原子数：
  16
• 可旋转键数：
  1
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.07
• 拓扑面积：
  12
• 氢给体数：
  1
• 氢受体数：
  1

反应信息

• 作为反应物：
  描述：

  N-Methyl-9-amino-anthracen 、 碘甲烷 在 偶氮二甲酸二异丙酯 、 polymer-bound triphenylphosphine 作用下， 以 四氢呋喃 为溶剂， 反应 12.0h， 以98%的产率得到N,N-dimethylanthracen-9-amine
  参考文献：
  名称：

  从仲胺高效合成叔胺

  摘要：

  已经开发出可靠的仲胺的N-烷基化。通过使用DIAD和TPP（或PS-TPP），可以使用多种烷基卤将多种仲胺以高至极好的收率转化为相应的叔胺。没有观察到季胺盐的形成。这些方案适用于组合化学文库，也可用于通过可裂解的叔氨基树脂的酸裂解来合成仲胺。

  DOI：

  10.1016/j.tetlet.2006.05.038

文献信息

• [EN] NEW ORGANIC COMPOUNDS FOR ELECTROLUMINESCENCE AND ORGANIC ELECTROLUMINESCENT DEVICES USING THE SAME<br/>[FR] NOUVEAUX COMPOSES ORGANIQUES POUR L'ELECTROLUMINESCENCE ET DISPOSITIFS ELECTROLUMINESCENTS ORGANIQUES DANS LESQUELS ILS SONT UTILISES
  申请人：LG CHEMICAL LTD

  公开号：WO2003095445A1

  公开（公告）日：2003-11-20

  Disclosed is a novel group of compounds having a general structure of anthracene body substituted with at least one thiophenyl group, which can be further substituted with various substituent groups. These new compounds are generally compatible with organic electroluminescence. Also disclosed are organic electroluminescent devices and method of making the same. The organic electroluminescent devices include at least one of the compounds in various layers thereof. Organic electroluminescent devices employing the new compounds in their light-emitting layers show outstanding stability.

  揭示了一类新的化合物群，其具有一个蒽骨架的一般结构，并且至少被一种噻吩基团取代，该基团可以进一步被各种取代基团取代。这些新化合物通常与有机电致发光兼容。还揭示了有机电致发光器件以及其制备方法。有机电致发光器件包括其中的至少一种化合物在各种层中。在其发光层中使用新化合物的有机电致发光器件表现出出色的稳定性。
• Methods for preparing arene-BIS (dicarboximide)-based semiconducting materials and related intermediates for preparing same
  申请人：Facchetti Antonio

  公开号：US20080177073A1

  公开（公告）日：2008-07-24

  The present teachings provide compounds of formulae I and II: where Q, R a , R 1 , W, and n are as defined herein. The present teachings also provide methods of preparing compounds of formulae I and II, including methods of preparing compounds of formula II from compounds of formula I. The compounds disclosed herein can be used to prepare semiconductor materials and related composites and electronic devices.

  本教学提供了符合以下公式I和II的化合物：其中Q、Ra、R1、W和n的定义如本文所述。本教学还提供了制备符合公式I和II的化合物的方法，包括从符合公式I的化合物制备符合公式II的方法。本文披露的化合物可用于制备半导体材料、相关复合材料和电子器件。
• Organic semiconductor materials and precursors thereof
  申请人：Facchetti Antonio

  公开号：US20080249309A1

  公开（公告）日：2008-10-09

  The present teachings provide novel organic semiconductor compounds and their soluble precursors, methods for preparing these compounds and precursors, as well as compositions, materials, articles, structures, and devices that incorporate such compounds.

  本教学提供了新型有机半导体化合物及其可溶性前体，制备这些化合物和前体的方法，以及包含这些化合物的组合物、材料、文章、结构和设备。
• Process for production of vinyl chloride polymer
  申请人：Shin-Etsu Chemical Co., Ltd.

  公开号：EP0172427A2

  公开（公告）日：1986-02-26

  This process is a process for production of a vinyl chloride polymer by suspension polymerization or emulsion polymerization of vinyl chloride monomer or a mixture of vinyl chloride monomer with a vinyl monomer copolymerizable with said vinyl chloride monomer in an aqueous medium, characterized in that the polymerization is carried out in a polymerizer, the inner wall surface and portions of the auxiliary equipment thereof which may come into contact with the monomer during polymerization being previously coated with a scaling preventive comprising at least one selected from dyes, pigments and aromatic or heterocyclic compounds having at least 5 conjugated π bonds, while controlling the chloride ion concentration in the reaction mixture to not higher than 100 ppm. According to said process, scaling onto the inner wall surface of a polymerizer, etc. during polymerization can be prevented effectively and surely.

  该工艺是通过氯乙烯单体或氯乙烯单体与可与所述氯乙烯单体共聚的乙烯基单体混合物在水介质中进行悬浮聚合或乳液聚合来生产氯乙烯聚合物的工艺，其特征在于聚合是在聚合器中进行的、内壁表面及其辅助设备中可能在聚合过程中与单体接触的部分事先涂上一层防垢剂，该防垢剂至少包括一种选自染料、颜料和至少有 5 个共轭 π 键的芳香族或杂环化合物的防垢剂，同时控制反应混合物中的氯离子浓度不高于 100 ppm。根据上述工艺，可有效、可靠地防止聚合过程中聚合器等内壁表面结垢。
• Method for the photochemical conversion of tachysterol compounds into previtamin D compounds and of trans-vitamin D compounds into cis-vitamin D compounds
  申请人：DUPHAR INTERNATIONAL RESEARCH B.V

  公开号：EP0373687A1

  公开（公告）日：1990-06-20

  The invention relates to a method for the photochemical conversion of tachysterol compounds into previtamin D compounds and of trans-vitamin D compounds into cis-vitamin D compounds under the influence of radiation, by exposing the tachysterol compound and trans-vitamin D compound, respecti­vely, dissolved in a suitable solvent system, in the presence of a polymeric photosensitizer consisting of a polymer chain ("backbone") comprising covalently bound sensitizers suitable for the photochemical conversion, to light with a wavelength of preferably between approx. 300 and approx. 1,000 nm, and by then isolating the resulting previtamin D compound and cis-vitamin D compound, respectively, in which a polymeric photosensitizer is used, the polymer chain of which has been selected from the group consisting of a polyether chain, an amino groups-containing polymer chain and a block copolymer chain comprising polyether segments and/or amino groups-­containing polymer segments, in such a manner that the polymeric photosensitizer dissolves in the solvent system during the exposure to radiation but either upon cooling precipitates from the solution and can be separated, or, in case said polymer chain comprises amino groups, can be protonated with a suitable acid substance and be removed in an after-treatment. The invention also relates to a polymeric photosensitizer to be used for the said method.

  本发明涉及一种在辐射影响下将速效甾醇化合物光化学转化为前维生素 D 化合物和将反式维生素 D 化合物光化学转化为顺式维生素 D 化合物的方法，该方法是将分别溶解在合适溶剂体系中的速效甾醇化合物和反式维生素 D 化合物，在由聚合物链（"骨架"）组成的聚合物光敏剂（其中包含适合光化学转化的共价结合敏化剂）的存在下，暴露于波长最好在约 300 到约 300 之间的光下。300 至约然后分别分离得到的前维生素 D 化合物和顺式维生素 D 化合物，其中使用的聚合物光敏剂的聚合物链选自聚醚链、含氨基聚合物链和由聚醚段和/或含氨基聚合物段组成的嵌段共聚物链组成的组、使聚合物光敏剂在辐照期间溶解在溶剂体系中，但冷却后从溶液中析出并可分离，或者，在所述聚合物链包含氨基的情况下，可与适当的酸性物质质子化，并在后处理中去除。本发明还涉及一种可用于上述方法的聚合物光敏剂。