(Undecyl-tridecyl)amine | 927820-85-7

• 分子结构分类: 有机化合物 - 有机氮化合物
• 英文名称: (Undecyl-tridecyl)amine
• 英文别名: tetracosan-12-amine
• CAS: 927820-85-7
• 化学式: C₂₄H₅₁N
• 分子量: 353.676
• InChiKey: WGZKDMKRWKJVLF-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  11.1
• 重原子数：
  25
• 可旋转键数：
  21
• 环数：
  0.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  26
• 氢给体数：
  1
• 氢受体数：
  1

反应信息

• 作为反应物：
  描述：

  BOC-甘氨酸 、 (Undecyl-tridecyl)amine 在 1-羟基苯并三唑 、 N,N'-二环己基碳二亚胺 作用下， 以 二氯甲烷 为溶剂， 反应 0.25h， 生成 12-(N-tert-butyloxycarbonylglycinamido)tetraeicosane
  参考文献：
  名称：

  Vesicles and other supramolecular systems from biocompatible synthetic glycolipids with hydrocarbon and/or fluorocarbon chains

  摘要：

  A series of double-tailed hydrocarbon and/or fluorocarbon glycolipids derived from galactose and glucose have been prepared. These compounds were obtained upon opening a lactono- and maltonolactone moiety by the amino group of either a glycine, glycylglycine or lysine residue. The carboxyl terminus of the glycyl and glycylglycine conjugates was further reacted with the appropriate double-tailed amine. In the case of lysine, the lactonamide conjugate was functionalized with a hydrocarbon and/or fluorocarbon fatty amine and acid, respectively. The ability of such glycolipids to disperse in water, the morphology of self-assemblies formed and the stability of the supramolecular structure obtained were shown to depend on the presence or absence and on the nature of the aminoacid spacer. Most of the compounds described were shown by conventional techniques (TEM, Cryo-TEM, LLS, etc.) to produce stable vesicular systems.

  DOI：

  10.1016/0009-3084(94)90099-x
• 作为产物：
  描述：

  十二醛 在 lithium aluminium tetrahydride 、 叠氮磷酸二苯酯 、 三苯基膦 、 偶氮二甲酸二乙酯 作用下， 以 四氢呋喃 、 乙醚 为溶剂， 反应 2.0h， 生成 (Undecyl-tridecyl)amine
  参考文献：
  名称：

  Vesicles and other supramolecular systems from biocompatible synthetic glycolipids with hydrocarbon and/or fluorocarbon chains

  摘要：

  A series of double-tailed hydrocarbon and/or fluorocarbon glycolipids derived from galactose and glucose have been prepared. These compounds were obtained upon opening a lactono- and maltonolactone moiety by the amino group of either a glycine, glycylglycine or lysine residue. The carboxyl terminus of the glycyl and glycylglycine conjugates was further reacted with the appropriate double-tailed amine. In the case of lysine, the lactonamide conjugate was functionalized with a hydrocarbon and/or fluorocarbon fatty amine and acid, respectively. The ability of such glycolipids to disperse in water, the morphology of self-assemblies formed and the stability of the supramolecular structure obtained were shown to depend on the presence or absence and on the nature of the aminoacid spacer. Most of the compounds described were shown by conventional techniques (TEM, Cryo-TEM, LLS, etc.) to produce stable vesicular systems.

  DOI：

  10.1016/0009-3084(94)90099-x

文献信息

• Golf ball
  申请人：Dunlop Sports Co., Ltd.

  公开号：EP2610291A2

  公开（公告）日：2013-07-03

  An object of the present invention is to provide a golf ball having a low spin rate on driver shots. The present invention provides a golf ball comprising a spherical core and at least one cover layer covering the spherical core, wherein the spherical core is formed from a rubber composition containing (a) base rubber, (b) an α,β-unsaturated carboxylic acid having 3 to 8 carbon atoms and/or a metal salt thereof as a co-crosslinking agent, (c) a crosslinking initiator and (d) a carboxylic acid having a benzene ring and/or a salt thereof, provided that the rubber composition further contains (e) a metal compound in case of containing only (b) the α,β-unsaturated carboxylic acid having 3 to 8 carbon atoms as the co-crosslinking agent.

  本发明的目的是提供一种在发球木杆击球时后旋率较低的高尔夫球。本发明提供了一种高尔夫球，包括一个球形芯和至少一个覆盖在球形芯上的覆盖层，其中球形芯由橡胶组合物形成，该橡胶组合物含有(a)基础橡胶，(b)具有 3 至 8 个碳原子的α，β-不饱和羧酸和/或作为共交联剂的金属盐，(c)交联引发剂和(d)具有苯环的羧酸和/或其盐、(c) 交联引发剂和 (d) 具有苯环的羧酸和/或其盐，条件是在仅含有 (b) 具有 3 至 8 个碳原子的 α，β-不饱和羧酸作为共交联剂的情况下，橡胶组合物还含有 (e) 金属化合物。
• GOLF BALL
  申请人：Dunlop Sports Co., Ltd.

  公开号：EP2610291B1

  公开（公告）日：2017-12-20
• GOLF BALL MATERIAL AND GOLF BALL
  申请人：Shiga Kazuyoshi

  公开号：US20110159990A1

  公开（公告）日：2011-06-30

  An object of the present invention is to provide a golf ball material producing a high spin rate on approach shots and a low spin rate on driver shots and a golf ball using the same. The present invention provides a golf ball material having a ratio [Shore D/log(bending stiffness)] of Shore D hardness to a logarithm of bending stiffness (kgf/cm 2 ) of 19.0 or more.
• RUBBER COMPOSITION AND GOLF BALL
  申请人：DUNLOP SPORTS CO. LTD.

  公开号：US20130324311A1

  公开（公告）日：2013-12-05

  The invention provides a rubber composition having high rebound resilience measured by a rebound resilience evaluation method which is excellent in measurement accuracy and can sufficiently evaluate the difference in performance between samples. The invention also provides a golf ball formed from the rubber composition. The invention further provides a golf ball having excellent flight performance owing to good hardness distribution measured by a hardness evaluation method which is excellent in measurement accuracy and can sufficiently evaluate the difference in performance between samples. The invention relates to a rubber composition having a specific radius of gyration R g obtained by a predetermined curve fitting method. The invention also relates to a golf ball including a spherical core having at least one layer, and a cover having at least one layer disposed to cover the spherical core, wherein the golf ball satisfies a predetermined relation obtained by a predetermined curve fitting method.
• GOLF BALL AND METHOD FOR MANUFACTURING THE SAME
  申请人：Dunlop Sports Co., Ltd.

  公开号：US20130324312A1

  公开（公告）日：2013-12-05

  An object of the present invention is to provide a golf ball comprising a core formed from a rubber composition containing (d) a carboxylic acid and/or a salt thereof and traveling a great flight distance on driver shots. The present invention provides a golf ball comprising a spherical core and at least one cover layer covering the spherical core, wherein the spherical core is formed from a rubber composition containing (a) a base rubber, (b) an α,β-unsaturated carboxylic acid having 3 to 8 carbon atoms and/or a metal salt thereof as a co-crosslinking agent, (c) a crosslinking initiator, (d) a carboxylic acid and/or a salt thereof and two or more kinds of (e) organic sulfur compounds, provided that the rubber composition further contains (f) a metal compound in case of containing only (b) the α,β-unsaturated carboxylic acid having 3 to 8 carbon atoms as the co-crosslinking agent.