2,3,4,6-Tetrachloro-5-(trichloromethyl)pyridine | 113982-12-0

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 吡啶及其衍生物
• 英文名称: 2,3,4,6-Tetrachloro-5-(trichloromethyl)pyridine
• CAS: 113982-12-0
• 化学式: C₆Cl₇N
• 分子量: 334.2
• InChiKey: QAEXAGIZTNALSL-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  5.7
• 重原子数：
  14
• 可旋转键数：
  0
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.17
• 拓扑面积：
  12.9
• 氢给体数：
  0
• 氢受体数：
  1

文献信息

• [EN] A METHOD FOR PRODUCING 2,3-DICHLORO-5-(TRICHLOROMETHYL)PYRIDINE<br/>[FR] PROCÉDÉ POUR PRODUIRE DE LA 2,3-DICHLORO-5- (TRICHLOROMÉTHYL)PYRIDINE
  申请人：CHEMINOVA AS

  公开号：WO2014198278A1

  公开（公告）日：2014-12-18

  The present invention relates to a novel process for producing of 2,3-dichloro-5-(trichloromethyl)pyridine by using PCl as chlorinating agent at elevated temperature and pressure.

  本发明涉及一种新型工艺，通过在高温高压下使用PCl作为氯化剂生产2,3-二氯-5-(三氯甲基)吡啶。
• METHOD FOR PRODUCING 2,3-DICHLORO-5-(TRICHLOROMETHYL)PYRIDINE
  申请人：CHEMINOVA A/S

  公开号：US20160145211A1

  公开（公告）日：2016-05-26

  The present invention relates to a novel process for producing of 2,3-dichloro-5-(trichloromethyl)pyridine by using PCl as chlorinating agent at elevated temperature and pressure.

  本发明涉及一种新的工艺，通过在高温高压下使用PCl作为氯化剂来生产2,3-二氯-5-(三氯甲基)吡啶。
• Removal of ferric chloride from halopyridines
  申请人：THE DOW CHEMICAL COMPANY

  公开号：EP0228643A2

  公开（公告）日：1987-07-15

  Ferric chloride is removed from mixtures with chlorinated and/or fluorinated pyridines and methyl­pyridines by extraction with diol solvents. For example, the ferric chloride in halopyridine mixtures containing 2,3,5,6-tetrachloropyridine was removed by extraction with ethylene glycol. The purified halopyridines are useful intermediates for the production of insecticides, herbicides, and fungicides.

  用二元醇溶剂萃取可从含氯和/或含氟吡啶和甲基吡啶的混合物中去除氯化铁。 例如，用乙二醇萃取可去除含 2,3,5,6-四氯吡啶的卤代吡啶混合物中的氯化铁。 纯化的卤代吡啶是生产杀虫剂、除草剂和杀真菌剂的有用中间体。
• PROCESS FOR PRODUCING CYANOPYRIDINE
  申请人：IHARA CHEMICAL INDUSTRY CO., LTD.

  公开号：EP0700903A1

  公开（公告）日：1996-03-13

  A process for producing a cyanopyridine represented by general formula (3) (wherein R represents hydrogen or halogen; X¹ and X² represent each hydrogen or halogen, provided at least one of them represents halogen; and n represents an integer of 1 or 2), characterized by reacting an ammonium halide with a trichloromethylpyridine represented by general formula (1) (wherein R, X¹, X² and n are each as defined above) in the presence of a metal compound represented by the general formula (2): MXm wherein M represents copper or zinc; X represents halogen or oxygen; and m represents an integer of 2 or 1.

  一种生产通式(3)代表的氰基吡啶的工艺(其中R代表氢或卤素；X¹和X²各自代表氢或卤素，但至少其中一个代表卤素；n代表1或2的整数)，其特征在于在通式(2)代表的金属化合物存在下，使卤化铵与通式(1)代表的三氯甲基吡啶反应(其中R、X¹、X²和n各自如上定义)：MXm 其中 M 代表铜或锌；X 代表卤素或氧；m 代表 2 或 1 的整数。
• Method for producing 2,3-dichloro-5-(trichloromethyl)pyridine
  申请人：Cheminova A/S

  公开号：US10442765B2

  公开（公告）日：2019-10-15

  The present invention relates to a novel process for producing of 2,3-dichloro-5-(trichloromethyl)pyridine by using PCl5 as chlorinating agent at elevated temperature and pressure.

  本发明涉及一种在高温高压下使用 PCl5 作为氯化剂生产 2,3-二氯-5-(三氯甲基)吡啶的新工 艺。