Dimethyl heptacyclo[15.7.1.15,9.02,16.04,14.021,25.013,26]hexacosa-1(24),2,4(14),5,7,9(26),10,12,15,17,19,21(25),22-tridecaene-3,15-dicarboxylate | 175289-24-4

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: Dimethyl heptacyclo[15.7.1.15,9.02,16.04,14.021,25.013,26]hexacosa-1(24),2,4(14),5,7,9(26),10,12,15,17,19,21(25),22-tridecaene-3,15-dicarboxylate
• CAS: 175289-24-4
• 化学式: C₃₀H₁₈O₄
• 分子量: 442.471
• InChiKey: GHSMWUINZKMGMW-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  6.8
• 重原子数：
  34
• 可旋转键数：
  4
• 环数：
  7.0
• sp3杂化的碳原子比例：
  0.07
• 拓扑面积：
  52.6
• 氢给体数：
  0
• 氢受体数：
  4

反应信息

• 作为反应物：
  描述：

  Dimethyl heptacyclo[15.7.1.15,9.02,16.04,14.021,25.013,26]hexacosa-1(24),2,4(14),5,7,9(26),10,12,15,17,19,21(25),22-tridecaene-3,15-dicarboxylate 在 lithium aluminium tetrahydride 作用下， 以 四氢呋喃 为溶剂， 以76%的产率得到
  参考文献：
  名称：

  Synthesis and Characterization of Hepta[5][5]circulene as a Subunit of C₇₀Fullerene

  摘要：

  通过对双(1-氯乙烯基)苊荧蒽 9 进行 FVP 反应，制备了七苯环呈 S 形环状排列的多环芳烃化合物--庚[5][5]环烯 11。该化合物的结构和电化学特性也得到了报道。

  DOI：

  10.1246/cl.1996.157
• 作为产物：
  描述：

  2,5-bis(methoxycarbonyl)acecyclone 、 苊烯 以52%的产率得到Dimethyl heptacyclo[15.7.1.15,9.02,16.04,14.021,25.013,26]hexacosa-1(24),2,4(14),5,7,9(26),10,12,15,17,19,21(25),22-tridecaene-3,15-dicarboxylate
  参考文献：
  名称：

  Synthesis and Characterization of Hepta[5][5]circulene as a Subunit of C₇₀Fullerene

  摘要：

  通过对双(1-氯乙烯基)苊荧蒽 9 进行 FVP 反应，制备了七苯环呈 S 形环状排列的多环芳烃化合物--庚[5][5]环烯 11。该化合物的结构和电化学特性也得到了报道。

  DOI：

  10.1246/cl.1996.157

文献信息

• Organic electroluminescence device
  申请人：Tagami Sanae

  公开号：US20070003788A1

  公开（公告）日：2007-01-04

  An organic electroluminescence device which exhibits an excellent purity of color and a high efficiency of light emission, has a long life and emits reddish light and a novel compound having these characteristics are provided. The organic electroluminescence device comprises an organic layer disposed between at least one pair of electrodes, wherein the organic layer comprises a compound having a fluoranthene skeleton structure substituted at least with an amine group or an alkenyl group.
• ORGANIC ELECTROLUMINESCENCE DEVICE
  申请人：Tagami Sanae

  公开号：US20080074045A1

  公开（公告）日：2008-03-27

  An organic electroluminescence device which exhibits an excellent purity of color and a high efficiency of light emission, has a long life and emits reddish light and a novel compound having these characteristics are provided. The organic electroluminescence device comprises an organic layer disposed between at least one pair of electrodes, wherein the organic layer comprises a compound having a fluoranthene skeleton structure substituted at least with an amine group or an alkenyl group.
• Synthesis and Characterization of Hepta[5][5]circulene as a Subunit of C₇₀Fullerene
  作者：Masanori Matsuda、Hiroshi Matsubara、Masaaki Sato、Susumu Okamoto、Koji Yamamoto

  DOI：10.1246/cl.1996.157

  日期：1996.2

  The polycyclic aromatic compound with a S-shaped circular arrangement of seven benzene rings, hepta[5][5]circulene 11, was prepared by FVP of bis(1-chlorovinyl)acenaphthofluoranthene 9. The structure and electrochemical properties were also reported.

  通过对双(1-氯乙烯基)苊荧蒽 9 进行 FVP 反应，制备了七苯环呈 S 形环状排列的多环芳烃化合物--庚[5][5]环烯 11。该化合物的结构和电化学特性也得到了报道。