2,7-dibromo-9,10-di(p-tolyl)-9,10-dihydro-phenanthrene-9,10-diol | 1010812-08-4

• 分子结构分类: 有机化合物 - 苯类化合物 - 萘
• 英文名称: 2,7-dibromo-9,10-di(p-tolyl)-9,10-dihydro-phenanthrene-9,10-diol
• 英文别名: 2,7-Dibromo-9,10-bis(4-methylphenyl)phenanthrene-9,10-diol
• CAS: 1010812-08-4
• 化学式: C₂₈H₂₂Br₂O₂
• 分子量: 550.289
• InChiKey: ZYRPLAPYFDGDGY-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  6.7
• 重原子数：
  32
• 可旋转键数：
  2
• 环数：
  5.0
• sp3杂化的碳原子比例：
  0.14
• 拓扑面积：
  40.5
• 氢给体数：
  2
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  2,7-dibromo-9,10-di(p-tolyl)-9,10-dihydro-phenanthrene-9,10-diol 在 盐酸 、 溶剂黄146 、 锌 作用下， 以 水 为溶剂， 以75.7%的产率得到2,7-dibromo-9,10-di(p-tolyl)-phenanthrene
  参考文献：
  名称：

  Facile Synthesis of 9,10-Diarylphenanthrenes and Poly(9,10-diarylphenanthrene)s

  摘要：

  One-pot reduction of 9,10-diaryl-9,10-dihydrophenanthrene-9,10-diols to 9,10-diarylphenanthrenes was achieved with Zn/H+ in acetic acid. Accordingly, various novel phenanthrenes and polyphenanthrenes with efficient blue emission were easily synthesized.

  DOI：

  10.1021/ol702873z
• 作为产物：
  描述：

  对溴甲苯 、 2,7-二溴菲醌 在 正丁基锂 、 水 作用下， 以 四氢呋喃 、 正己烷 为溶剂， 以63.2%的产率得到2,7-dibromo-9,10-di(p-tolyl)-9,10-dihydro-phenanthrene-9,10-diol
  参考文献：
  名称：

  Facile Synthesis of 9,10-Diarylphenanthrenes and Poly(9,10-diarylphenanthrene)s

  摘要：

  One-pot reduction of 9,10-diaryl-9,10-dihydrophenanthrene-9,10-diols to 9,10-diarylphenanthrenes was achieved with Zn/H+ in acetic acid. Accordingly, various novel phenanthrenes and polyphenanthrenes with efficient blue emission were easily synthesized.

  DOI：

  10.1021/ol702873z

文献信息

• Facile Synthesis of 9,10-Diarylphenanthrenes and Poly(9,10-diarylphenanthrene)s
  作者：Bo He、Hongkun Tian、Yanhou Geng、Fosong Wang、Klaus Müllen

  DOI：10.1021/ol702873z

  日期：2008.3.1

  One-pot reduction of 9,10-diaryl-9,10-dihydrophenanthrene-9,10-diols to 9,10-diarylphenanthrenes was achieved with Zn/H+ in acetic acid. Accordingly, various novel phenanthrenes and polyphenanthrenes with efficient blue emission were easily synthesized.