nickel(II) dithizonate

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: nickel(II) dithizonate
• 英文别名: Ni(Dz)2；N'-anilino-N-phenyliminocarbamimidothioate;nickel(2+)
• 化学式: C₂₆H₂₂N₈NiS₂
• 分子量: 569.336
• InChiKey: GSLVLFHBAYQFLZ-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  7.4
• 重原子数：
  37
• 可旋转键数：
  8
• 环数：
  4.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  100
• 氢给体数：
  2
• 氢受体数：
  8

反应信息

• 作为反应物：
  描述：

  tripyridyl triazine 、 nickel(II) dithizonate 以 二甲基亚砜 为溶剂， 生成 nickel(II) tetra-tert-butylphthalocyanine
  参考文献：
  名称：

  Reactions of Chelate Complexes with Macrocyclic Ligands. Tetra-tert-butylphthalocyanine

  摘要：

  Complexation reactions of tetra-tert-butylphthalocyanine (I) with Cu(II) acetate, acetylacetonate, 8-hydroxyquinolate, glycinate, valinate or dithizonate, as well as with Zn(II), Co(II), and Ni(II) 8-hydroxyquinolates, valinates, and dithizonates were studied. Unlike porphyrins themselves and porphyrins with planar distortions, compound I was found to form metal phthalocyanines with all indicated chelate salts in common solvents. It was established that compound I exhibits more equalized dependences of the coordination rate on the nature of the salt anion and cation as compared to the majority of the other porphyrins.

  DOI：

  10.1023/b:ruco.0000026003.90733.86