N,N'-bis(4-nitrophenyl)-N,N'-diphenyl-1,4-benzenediamine

• 分子结构分类: 有机化合物 - 有机氮化合物
• 英文名称: N,N'-bis(4-nitrophenyl)-N,N'-diphenyl-1,4-benzenediamine
• 英文别名: N,N'-diphenyl-N,N'-bis(4-nitrophenyl)-p-phenylenediamine；1-N,4-N-bis(4-nitrophenyl)-1-N,4-N-diphenylbenzene-1,4-diamine
• 化学式: C₃₀H₂₂N₄O₄
• 分子量: 502.529
• InChiKey: ACIZQONYMJAENG-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  8.1
• 重原子数：
  38
• 可旋转键数：
  6
• 环数：
  5.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  98.1
• 氢给体数：
  0
• 氢受体数：
  6

反应信息

• 作为反应物：
  描述：

  N,N'-bis(4-nitrophenyl)-N,N'-diphenyl-1,4-benzenediamine 在 铁粉 、 氯化铵 作用下， 以 乙醇 、 水 为溶剂， 反应 4.0h， 以89.7%的产率得到N,N′-bis(4-aminophenyl)-N,N′-diphenyl-1,4-benzenediamine
  参考文献：
  名称：

  用于锂离子电池的高平均电压和长循环寿命的聚（芳胺-酰亚胺）正极材料

  摘要：

  两种聚（芳胺-酰亚胺），聚（N,N,N',N'-四苯基-1,4-苯二胺萘二酰亚胺）（PDDP-NI）和聚（N,N,N',N'-四苯基-通过胺单体 N,N,N',N'-四苯基-1,4-苯二胺 (DDP) 与二酐单体 1,4 缩聚成功制备 1,4-苯二胺苝二酰亚胺 (PDDP-PI)， 5,8-萘四甲酸二酐 (NTCDA) 或 3,4,9,10- 苝四甲酸二酐 (PTCDA)。聚合物中的 DDP 单元可以可逆地掺杂/去掺杂 PF 6 -阴离子，而萘二亚胺 (NI) 单元或苝二亚胺 (PI) 单元可以可逆地插入/脱出锂阳离子。组装基于聚合物正极和锂负极的锂离子半电池并测试其电化学性能。由于聚合物骨架中 DDP 单元的高电压，基于 PDDP-NI 和 PDDP-PI 阴极的锂离子半电池提供约 3.2 V 的高平均放电电压。 此外，所制备的聚合物材料表现出在长循环性能方面，PDDP-NI 在 10 C

  DOI：

  10.1149/1945-7111/abf180
• 作为产物：
  描述：

  N,N'-二苯基-1,4-苯二胺 、 对氟硝基苯 在 sodium hydride 作用下， 以 N,N-二甲基甲酰胺 为溶剂， 生成 N,N'-bis(4-nitrophenyl)-N,N'-diphenyl-1,4-benzenediamine
  参考文献：
  名称：

  Multifunctional polyurethanes synthesized from different triarylamine units with electrochromic, photogeneration, memory storage and sensing properties

  摘要：

  在这里，我们报告了三种多功能聚氨酯材料，具有出色的电致变色、光电、记忆和传感特性，同时还具有良好的机械性能。

  DOI：

  10.1039/c8nj05159c

文献信息

• Electrode for an electrochemical element with an organic electrolyte, electrochemical elements comprising the electrode and polymeric material and its use as electrode active material or as electrode binder
  申请人：VARTA Micro Innovation GmbH

  公开号：EP3032621A1

  公开（公告）日：2016-06-15

  Disclosed is an electrode comprising a polymeric material containing or being composed of subunits according to general formulae (I) and (II) wherein in these structures (I) and (II) n is an integer not smaller than 2, Y represents an amide group (-NH-CO- or -CO-NH-), an ester group (-O-CO- or -CO-O-) or a urethane group (-NH-CO-O- or -O-CO-NH-), R1, R2, R3 and R4 each independently represent H, alkyl (preferably-CH3, -C2H5), alkoxy-(preferably -OCH3, -OC2H5), -halogen or -CN, Ar1 and Ar4 independently represent a bridging aryl group, Ar2 and Ar3 independently represent a non-bridging aryl group, and R5 is a bridging alkyl or aryl group. Further, a Lithium-ion battery and a supercapacitor with such an electrode and the use of said polymeric material as electrode active material in the electrode of a battery or in the electrode of a supercapacitor and/or as an electrode binder is disclosed.

  本发明公开了一种电极，它包含一种聚合物材料，该材料含有或由符合通式 (I) 和 (II) 的亚基组成 其中在这些结构（I）和（II）中，n 是不小于 2 的整数，Y 代表酰胺基（-NH-CO- 或 -CO-NH-）、酯基（-O-CO- 或 -CO-O-）或氨基甲酸酯基（-NH-CO-O- 或 -O-CO-NH-），R1、R2、R3 和 R4 各自独立地代表 H、烷基（优选-CH3、-C2H5）、烷氧基（优选-O 、-O ）、-卤素或-CN，Ar1 和 Ar4 各自独立地代表桥接芳基，Ar2 和 Ar3 各自独立地代表非桥接芳基，R5 是桥接烷基或芳基。此外，还公开了具有这种电极的锂离子电池和超级电容器，以及在电池电极或超级电容器电极中使用所述聚合物材料作为电极活性材料和/或作为电极粘合剂。
• Composite material, electrode, method of producing the material and the electrode and electrochemical cell
  申请人：VARTA Microbattery GmbH

  公开号：US10468715B2

  公开（公告）日：2019-11-05

  A composite material includes an electrochemically active organic material and an electrochemically active inorganic material. The organic material contains subunits according to formulae (I) and/or (II) wherein n is an integer not smaller than 2, Y represents an amide group (—NH—CO— or —CO—NH—), an ester group (—O—CO— or —CO—O—) or a urethane group (—NH—CO—O— or —O—CO—NH—), R1, R2, R3 and R4 each independently represent H, alkyl (preferably —CH3, —C2H5), alkoxy-(preferably —OCH3, —OC2H5), -halogen or —CN, Ar1 and Ar4 independently represent a bridging aryl group, Ar2 and Ar3 independently represent a non-bridging aryl group, and R5 is a bridging alkyl, alkene or aryl group.

  一种复合材料包括电化学活性有机材料和电化学活性无机材料。有机材料含有符合式 (I) 和/或 (II) 的亚基 其中 n 是不小于 2 的整数，Y 代表酰胺基（-NH-CO- 或 -CO-NH-）、酯基（-O-CO- 或 -CO-O-）或聚氨酯基（-NH-CO-O- 或 -O-CO-NH-），R1、R2、R3 和 R4 各自独立地代表 H、烷基（优选-CH3、-C2H5）、烷氧基（优选-O 、-O ）、-卤素或-CN，Ar1 和 Ar4 各自独立地代表桥接芳基，Ar2 和 Ar3 各自独立地代表非桥接芳基，R5 是桥接烷基、烯基或芳基。
• 含苯并噁嗪结构三芳胺基类聚合物及其制备方法和应用
  申请人：黑龙江大学

  公开号：CN109593172B

  公开（公告）日：2023-03-24

  含苯并噁嗪结构三芳胺基类聚合物及其制备方法和应用，本发明涉及含苯并噁嗪结构三芳胺基类聚合物及其制备方法和应用。本发明是为了解决以往三芳胺基类聚合物耐热性能差，电致变色聚合物薄膜附膜能力差的问题。本发明以N，N‑二苯基‑1,4‑苯二胺，N,N'‑二苯基‑联苯二胺为原料然后与对氟硝基苯反应实现硝基化，随后再将硝基还原为氨基，以双酚A，多聚甲醛，制备的三芳胺基类单体为原料，在一定条件下经过缩合反应合成聚合物，本发明聚合物具有优异的电致变色性能和记忆性能，能够应用于电致变色领域，其在爆炸物检测也具有很好的表现；本发明应用电致变色聚合物领域。
• From aerospace to screen: Multifunctional poly(benzoxazine)s based on different triarylamines for electrochromic, explosive detection and resistance memory devices
  作者：Yan Wang、Haiying Niu、Qingyi Lu、Wei Zhang、Xin Qiao、Haijun Niu、Yanhong Zhang、Wen Wang

  DOI：10.1016/j.saa.2019.117524

  日期：2020.1

  Four kinds of main-chain benzoxazine polymers (PBZ) containing triarylamine (TAA) units were synthesized by Mannich reaction and characterized by H-1 nuclear magnetic resonance (NMR), Fourier transform infrared (FT-IR) techniques, etc. Thermal, optical, photophysical and electrochemical properties were studied. The 50% of char residue is left in N-2 at 800 degrees C. The polymers are soluble in common organic solvents and easily spin-coated onto indium-tin oxide (ITO) coated glass substrates. All the polymers have voltage window ranging from 0 to 1.8 V, and the colors change from yellowish to dark red when voltage is applied. Meanwhile, device assembled from polymer exhibit significant color changes. Furthermore, the polymers also have promising potential application in explosive detection and resistance memory devices. (C) 2019 Elsevier B.V. All rights reserved.
• Simple approach to regulate the spectra of novel kinds of polyazomethines containing bulky triphenylamine: Electrochemistry, electrochromism and photophysical responsive to environment
  作者：Haijun Niu、Jiwei Cai、Ping Zhao、Cheng Wang、Xuduo Bai、Wen Wang

  DOI：10.1016/j.dyepig.2012.08.003

  日期：2013.1

  Two series of novel polyazomethines (PAMs) PIa-PIe, PIIa-PIIe were prepared via the direct polycondensation from N,N'-bis(4-aminophenyl)-N,N'-diphenyl-1,4-phenylenediamine, and N.N'-bis(4-aminophenyl)-N,N'-diphenyl-4,4'-biphenyldiamine with various dicarboxaldehyde such as phthaldialdehyde, 1,3-isophthalaldehyde, terephthalaldehyde, 4,4'-diformyltriphenylamine, 5-thiophenedialdehyde. The variation of the backbone structure significantly affected the dihedral angles and changed the electronic properties of PAMs. The obtained PAMs exhibited stable and reversible electrochromic properties and reversible color change. The color of PAMs could be varied from initial yellowish to red, violet or blue via electrooxidation. And multiple reversible colors states were also observed with pH and chemical doping. Considering the sensitive chromic properties of PAMs, they will have potential applications for display device, chemical sensor, et al. (C) 2012 Elsevier Ltd. All rights reserved.