三[2-[[2,4,8,10-四-叔-丁基二苯并[d,f][1,3,2]二氧杂磷杂卓-6-基]氧基]乙基]胺 | 80410-33-9

• 分子结构分类: 有机化合物 - 苯类化合物
• 中文名称: 三[2-[[2,4,8,10-四-叔-丁基二苯并[d,f][1,3,2]二氧杂磷杂卓-6-基]氧基]乙基]胺
• 中文别名: 四磺基化二辛基；2-[[2,4,8,10-四(1,1-二甲基乙基)二苯并[D,F][1,3,2]二恶磷环庚烷-6-基]氧]-N,N-双[2-[[2,4,8,10-四-(1,1-
• 英文名称: 2-[[2,4,8,10-tetrakis(1,1-dimethylethyl)dibenzo[d,f][1,3,2]dioxaphosphepin-6-yl]oxy]-N,N-bis[2-[[2,4,8,10-tetrakis(1,1dimethylethyl)dibenzo[d,f][1,3,2]dioxaphosphepin-6-yl]oxy]-ethyl]ethanamine
• 英文别名: 2-(2,4,8,10-tetratert-butylbenzo[d][1,3,2]benzodioxaphosphepin-6-yl)oxy-N,N-bis[2-(2,4,8,10-tetratert-butylbenzo[d][1,3,2]benzodioxaphosphepin-6-yl)oxyethyl]ethanamine；tris[2-[[2,4,8,10-tetrakis(1,1-dimethylethyl)dibenzo[d,f][1,3,2]dioxaphosphaepin-6-yl]oxy]ethyl]amine；tris[2-[[2,4,8,10-tetrakis(1,1-dimethylethyl)dibenzo[d,f][1,3,2]dioxaphosphepin-6-yl]oxy]ethyl]amine；tris(2-[(2,4,8,10-tetrakistertiary butyldibenzo[d,f][1,3,2]dioxaphosphepin-6-yl)oxy]ethyl)amine；tris(2-[(2,4,8,10-tetrakis-tert-butyldibenzo[d,f][1,3,2]dioxaphosphepine-6-yl)oxy]ethyl)amine；tris(2-[(2,4,8,10-tetrakis-tert-butyldibenzo[d,f][1,3,2]dioxaphosphepin-6-yl)oxy]ethyl)amine；Tris[2-[[2,4,8,10-tetra-tert-butyldibenzo[d,f][1,3,2]dioxaphosphepin-6-yl]oxy]ethyl]amine
• CAS: 80410-33-9
• 化学式: C₉₀H₁₃₂NO₉P₃
• 分子量: 1464.96
• InChiKey: YAGPRJYCDKGWJR-UHFFFAOYSA-N

物化性质

• 熔点：
  105-110 °C
• 密度：
  1.07[at 20℃]
• 物理描述：
  OtherSolid

计算性质

• 辛醇/水分配系数(LogP)：
  29.9
• 重原子数：
  103
• 可旋转键数：
  24
• 环数：
  9.0
• sp3杂化的碳原子比例：
  0.6
• 拓扑面积：
  110
• 氢给体数：
  0
• 氢受体数：
  10

反应信息

• 作为反应物：
  描述：

  三[2-[[2,4,8,10-四-叔-丁基二苯并[d,f][1,3,2]二氧杂磷杂卓-6-基]氧基]乙基]胺 在 三乙基铝 作用下， 以 正己烷 、 二氯甲烷 为溶剂， 反应 2.0h， 以26%的产率得到
  参考文献：
  名称：

  Facile Phosphite to Phosphonate Rearrangement of a Trialkanolamine-derived Triphosphite Promoted by Triethylaluminum

  摘要：

  A facile room temperature rearrangement of a trialkanolamine-derived triphosphite, 1, to the monophosphonate 5 promoted by three equivalents of triethylaluminum is described. The diphosphonate 6 was prepared by the addition of three equivalents of triethylaluminum to the monophosphonate 5. A mechanism is suggested involving a transition state or intermediate with coordination of the trialkylaluminum to the migrating oxygen.

  DOI：

  10.1080/10426500701513248
• 作为产物：
  描述：

  三乙醇胺 、 3,3',5,5'-tetra-tert-butyl-1,1'-biphenyl-2,2'-diyl phosphorochloridite 在 三乙胺 作用下， 以 甲苯 为溶剂， 生成 三[2-[[2,4,8,10-四-叔-丁基二苯并[d,f][1,3,2]二氧杂磷杂卓-6-基]氧基]乙基]胺
  参考文献：
  名称：

  Novel sterically congested chiral tripodal phosphite ligands: catalytic asymmetric hydrosilylation of ketones with a Rh(I)–TRISPHOS catalyst

  摘要：

  A new chiral trisphosphite ligand, (S,S,S)-2,2',2 "-tris(2,4,8,10-tetra-tert-butyl-dibenzo[d,f][1,3,2] dioxaphosphepin-6-yl-6-oxy)tri-2-propylamine, (S,S,S)-TRISPHOS, was synthesized and coordination chemistry investigated. The Rh(I)-(S,S,S)-TRISPHOS complexes were found to be effective catalysts for the enantioselective hydrosilylation of ketones. (C) 1998 Elsevier Science Ltd. All rights reserved.

  DOI：

  10.1016/s0957-4166(98)00018-4

文献信息

• Stabilization of iodine biocides
  申请人：Uhr Hermann

  公开号：US20090036555A1

  公开（公告）日：2009-02-05

  2-(2-Hydroxyphenyl)benzotriazoles are outstandingly suitable for stabilizing iodine-containing biocides in industrial materials, more particularly in paints based on alkyd resin.

  2-(2-羟基苯基)苯并三唑在工业材料中稳定含碘生物杀菌剂方面特别适用，尤其是在基于醇酸树脂的油性漆中。
• COMPOSITION, FILM, NEAR INFRARED CUT FILTER, LAMINATE, PATTERN FORMING METHOD, SOLID IMAGE PICKUP ELEMENT, IMAGE DISPLAY DEVICE, INFRARED SENSOR, AND COLOR FILTER
  申请人：FUJIFILM Corporation

  公开号：US20180305552A1

  公开（公告）日：2018-10-25

  The composition includes two or more near infrared absorbing compounds having an absorption maximum in a wavelength range of 650 to 1000 nm and having a solubility of 0.1 mass % or lower in water at 23° C., in which the two or more near infrared absorbing compounds include a first near infrared absorbing compound having an absorption maximum in a wavelength range of 650 to 1000 nm, and a second near infrared absorbing compound having an absorption maximum in a wavelength range of 650 to 1000 nm which is shorter than the absorption maximum of the first near infrared absorbing compound, and a difference between the absorption maximum of the first near infrared absorbing compound and the absorption maximum of the second near infrared absorbing compound is 1 to 150 nm.

  该组合物包括两种或更多在波长范围为650到1000纳米具有吸收峰值的近红外吸收化合物，并且在23°C下其在水中的溶解度为0.1质量%或更低。其中，这两种或更多的近红外吸收化合物包括第一种在波长范围为650到1000纳米具有吸收峰值的近红外吸收化合物，以及第二种在波长范围为650到1000纳米具有比第一种近红外吸收化合物吸收峰值更短的吸收峰值的近红外吸收化合物，第一种近红外吸收化合物的吸收峰值与第二种近红外吸收化合物的吸收峰值之间的差值为1到150纳米。
• STABLE COMPOSITIONS OF THIABENDAZOLE AND IODINE-CONTAINING FUNGICIDES
  申请人：LANXESS Deutschland GmbH

  公开号：US20150051279A1

  公开（公告）日：2015-02-19

  The present invention relates to stable compositions for the fungicidal equipment of thermoplastic polymers, in particular PVC, comprising thiabendazole, at least one iodine-containing fungicide and at least one epoxide and optionally further fungicidally active compounds, and also to methods for preparing these formulations and to uses thereof for the protection of thermoplastic polymers against attack and destruction by microorganisms. Moreover, the invention relates to mold-resistant PVC materials equipped with the compositions according to the invention.

  本发明涉及用于热塑性聚合物的抗真菌设备的稳定组合物，特别是PVC，包括噻苯唑、至少一种含碘真菌剂和至少一种环氧化物，以及可选的其他具有抗真菌活性的化合物，以及制备这些配方的方法和用途，用于保护热塑性聚合物免受微生物的侵害和破坏。此外，该发明涉及配备了根据本发明的组合物的耐霉PVC材料。
• COMPOSITION AND FIRE-RETARDANT RESIN COMPOSITION
  申请人：ADEKA CORPORATION

  公开号：US20210171833A1

  公开（公告）日：2021-06-10

  A heat-resistant composition useful as a flame retardant, a flame retardant composition containing the same, and a flame-retardant resin composition are provided. The composition contains 20 to 50 parts by mass of a specific melamine salt as component (A), 50 to 80 parts by mass of a specific piperazine salt as component (B), and 1 to 50 parts by mass of a phosphoric ester compound having a specific structure as component (C), wherein the sum of the components (A) and (B) is 100 parts by mass.

  提供一种作为阻燃剂有用的耐热组合物，包含该组合物的阻燃剂组合物以及阻燃树脂组合物。该组合物包含20至50质量份的特定三聚氰胺盐作为组分（A），50至80质量份的特定哌嗪盐作为组分（B），以及1至50质量份具有特定结构的磷酸酯化合物作为组分（C），其中组分（A）和（B）的总和为100质量份。
• NOVEL TRIAZINE COMPOUND AND SYNTHETIC RESIN COMPOSITION USING SAME
  申请人：ADEKA CORPORATION

  公开号：US20170327475A1

  公开（公告）日：2017-11-16

  A novel compound excellent in heat resistance, resistance to volatilization, and compatibility with a resin component and useful as a UV absorber and a synthetic resin composition containing the compound are provided. Specifically provided are a triazine compound of general formula (1), preferably general formula (2) and a synthetic resin composition containing 0.001 to 20 parts by mass of the compound per 100 parts by mass of a synthetic resin. The details of formulae (1) and (2) are as defined in the description.

  提供了一种在耐热性、抗挥发性和与树脂成分的相容性方面表现出色的新型化合物，可用作紫外线吸收剂和含有该化合物的合成树脂组合物。具体提供的是一般式（1）的三嗪化合物，优选一般式（2）的化合物和含有该化合物每100份合成树脂中0.001至20质量份的合成树脂组合物。一般式（1）和（2）的细节如描述中定义。