trans-ClCF=CFBF3(1-)

• 分子结构分类: 有机化合物 - 有机酸及其衍生物 - 硼酸衍生物
• 英文名称: trans-ClCF=CFBF3(1-)
• 英文别名: [(E)-2-chloro-1,2-difluoroethenyl]-trifluoroboranuide
• 化学式: C₂BClF₅
• 分子量: 165.278
• InChiKey: AIJLRNAZXQRJBZ-UPHRSURJSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  2.72
• 重原子数：
  9
• 可旋转键数：
  0
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  6

反应信息

• 作为产物：
  描述：

  水 、 trans-chloro-1,2-difluoroeth-1-enyldifluoroborane 以 乙醚 、 丙酮 为溶剂， 生成 c-F1122 、 tetrafluoroborate ion 、 trans-ClCF=CFBF3(1-) 、 cis-ClCF=CFBF3(1-)
  参考文献：
  名称：

  (Fluoroorgano)fluoroboranes and -fluoroborates

  摘要：

  Polyfluoroalken-1-yldifluoroboranes RCF=CFBF2 (R = F, cis-, trans-Cl, trans-C4F9, cis-C2F5, cis-C6F13, trans-C4H9, trans-C6H5) were prepared by defluoridation of the corresponding fluoroborate salts K[RCF=CFBF3] using boron trifluoride in dichloromethane or fluorotrichloromethane. The alkenylboranes were characterised by H-1-, B-11- and F-19-NMR spectroscopy. Their reactivity towards ether, water and anhydrous HF was investigated. (C) 2001 Elsevier Science V.B. All rights reserved.

  DOI：

  10.1016/s0022-328x(01)00858-0

文献信息

• (Fluoroorgano)fluoroboranes and -fluoroborates
  作者：H.-J. Frohn、V.V. Bardin

  DOI：10.1016/s0022-328x(01)00858-0

  日期：2001.8

  Polyfluoroalken-1-yldifluoroboranes RCF=CFBF2 (R = F, cis-, trans-Cl, trans-C4F9, cis-C2F5, cis-C6F13, trans-C4H9, trans-C6H5) were prepared by defluoridation of the corresponding fluoroborate salts K[RCF=CFBF3] using boron trifluoride in dichloromethane or fluorotrichloromethane. The alkenylboranes were characterised by H-1-, B-11- and F-19-NMR spectroscopy. Their reactivity towards ether, water and anhydrous HF was investigated. (C) 2001 Elsevier Science V.B. All rights reserved.