tetrafluoroborate ion

• 分子结构分类: 无机化合物 - 混合金属/非金属化合物 - 类金属盐
• 英文名称: tetrafluoroborate ion
• 英文别名: tetrafluoroborate(1-)；tetrafluoroborate
• 化学式: BF₄
• 分子量: 86.8046
• InChiKey: OADPYROAGNTBKO-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  tetrafluoroborate ion 以 not given 为溶剂， 生成 氢氟酸
  参考文献：
  名称：

  Gmelin Handbuch der Anorganischen Chemie, Gmelin Handbook: F: SVol.1, 26, page 143 - 146

  摘要：

  DOI：
• 作为产物：
  描述：

  1-butyl-3-methylimidazolium Tetrafluoroborate 反应 5.0h， 生成 tetrafluoroborate ion
  参考文献：
  名称：

  电化学氟化（Simons工艺）–一种强大的工具，可用于制备新的导电盐，离子液体和强布朗斯台德酸

  摘要：

  电化学氟化（Simons工艺）为一系列三（全氟烷基）二氟磷烷提供了廉价的商业途径。这些物质是制备各种含氟化合物的方便原料。描述了用全氟烷基氟磷酸盐（FAP）和全氟烷基次膦酸酯阴离子合成新的导电盐和离子液体的方法。FAP离子液体具有出色的水解稳定性，低粘度以及高电化学和热稳定性。具有FAP阴离子的有机盐和无机盐具有很高的电化学稳定性和电导率，这使其在多种电化学设备（锂离子电池，超级电容器等）中具有吸引力。H [（R F）3 PF 3的可能应用讨论了作为质子传导膜的成分的（HFAP），（R F）2 P（O）（OH）和（R F）P（O）（OH）2。

  DOI：

  10.1016/j.jfluchem.2009.09.016
• 作为试剂：
  描述：

  糠醛 、 5-氨基水杨酸 在 tetrafluoroborate ion 、 sodium nitrite 、 copper dichloride 作用下， 以 水 、 丙酮 为溶剂， 生成 5-(5-formylfuran-2-yl)-2-hydroxybenzoic acid
  参考文献：
  名称：

  Exploration of novel thiobarbituric acid-, rhodanine- and thiohydantoin-based HIV-1 integrase inhibitors

  摘要：

  A novel compound inhibiting HIV-1 integrase has been identified by means of virtual screening techniques. A small family of structurally related molecules has been synthesized and biologically evaluated with some of the compounds possessing micromolar activity both in enzymatic and cellular assays. (C) 2009 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.bmcl.2009.04.132

文献信息

• Structural and Electronic Properties of Iron(II) Complexes of 2-(1,2,4-Triazol-3-yl)pyridine and Substituted Derivatives
  作者：KH Sugiyarto、DC Craig、AD Rae、HA Goodwin

  DOI：10.1071/ch9950035

  日期：——

  Iron(II) and nickel(II) tris(ligand) complexes of 2-(triazol-3-yl)pyridine and the substituted derivatives 2-(1(N)-methyltriazol-3-yl)pyridine and -(1,5-dimethyltriazol-3-yl)pyridine have been prepared. Coordination of the dimethyl -substituted ligand via N(4) of the triazolyl moieties is confirmed by structure determination of [FeL3] [BF4]2, which has the mer configuration. Tris (2-(1,5-dimethyltriazol-3-yl)pyridine)iron(II) bis ( tetrafluoroborate ): orthorhombic, space group Pbca, a 11.568(3), b 19.442(4), c 30.551(8) Ǻ, Z 8. The methyl substituents appear to have only a minor influence on the donor properties of the ligands, all three of which have field strengths in the iron(II) quintet ↔ singlet crossover region. Temperature-induced singlet ↔ quintet transitions occur in salts of the [FeN6]2+ derivatives in both the solid and solution states. Mossbauer effect studies reveal the complexity of the solid state properties of salts of the iron complex of 2-(1(N)-methyltriazol-3-yl)pyridine and suggest that there is a fundamental change with time in the geometry of the complex cation. The metastable form of the complex hexafluorophosphate salt shows virtually no quadrupole splitting in the spectrum for the quintet state species, which implies high symmetry for the metal ion environment. Mossbauer studies further reveal the presence of multiple iron(II) sites in the lattice for salts containing either the N-methyl or the unsubstituted ligand.

  制备了 2-(三唑-3-基)吡啶和取代衍生物 2-(1(N)-甲基三唑-3-基)吡啶和-(1,5-二甲基三唑-3-基)吡啶的三(配体)铁(II)和镍(II)配合物。通过测定[FeL3] [BF4]2的结构，证实了二甲基取代配体通过三唑基的 N(4)配位，而[FeL3] [BF4]2具有合并构型。三（2-(1,5-二甲基三唑-3-基)吡啶）双（四氟硼酸盐）铁（II）：正方体，空间群 Pbca，a 11.568(3)，b 19.442(4)，c 30.551(8)Ǻ，Z 8。甲基取代基似乎对配体的供体性质影响不大，这三种配体的场强都在铁（II）五元组↔单线交叉区域。在[FeN6]2+衍生物盐的固态和溶液态中，都会出现温度诱导的单子↔五次跃迁。 莫斯鲍尔效应研究揭示了 2-(1(N)-甲基三唑-3-基)吡啶铁络合物盐固态性质的复杂性，并表明络合物阳离子的几何形状随着时间的推移发生了根本变化。络合物六氟磷酸盐的蜕变形式在光谱中几乎没有五元态物种的四极分裂，这意味着金属离子环境的高度对称性。 莫斯鲍尔研究进一步揭示了含有 N-甲基或未取代配体的盐的晶格中存在多个铁（II）位点。
• Pd/C as a Catalyst for Completely Regioselective CH Functionalization of Thiophenes under Mild Conditions
  作者：Dan-Tam D. Tang、Karl D. Collins、Johannes B. Ernst、Frank Glorius

  DOI：10.1002/anie.201309305

  日期：2014.2.10

  The completely C3‐selective arylation of thiophenes and benzo[b]thiophenes was achieved by using Pd/C as a heterogeneous catalyst without ligands or additives under mild reaction conditions. The practicability of this transformation is demonstrated by notable functional group tolerance and the insensitivity of the reaction to H2O and air. This method is also applicable to nitrogen‐ and oxygen‐containing

  通过在温和的反应条件下使用Pd / C作为不带配体或添加剂的非均相催化剂，可以实现噻吩和苯并[ b ]噻吩的完全C3选择性芳基化。该转化的实用性通过显着的官能团耐受性和反应对H 2 O和空气的不敏感性得到证明。该方法也适用于含氮和氧的杂环，产生相应的C2芳基化产物。三相试验以及汞中毒和热过滤试验表明，催化活性物质在性质上是异质的。
• Liquid hydrogen sulphide as an ionising solvent. Part II. Reactions of Lewis acids of boron with base analogues
  作者：J. D. Cotton、T. C. Waddington

  DOI：10.1039/j19660000789

  日期：——

  Neutralisations of base analogues by volatile boron Lewis acids have been examined in liquid hydrogen sulphide. Salts containing the new anions BF3SH–, BCl3SH–, BBr3SH–, and BEt3SH– have been prepared. The reaction of diborane is more complicated but seems to proceed, at least initially, through the formation of the ion BH3,SH·BH3–, which subsequently loses hydrogen. The ions BF3SH– and BCl3SH– react with excess

  已在液态硫化氢中研究了挥发性硼路易斯酸对碱类似物的中和作用。包含新的阴离子BF盐3 SH - ，的BCl 3 SH - ，的BBr 3 SH - ，和BET 3 SH -已经制备。乙硼烷的反应是比较复杂的，但似乎继续进行，至少在最初，通过形成离子BH的3，SH·BH 3 - ，其随后失去氢。离子BF 3 SH –和BCl 3 SH – 与过量的三卤化硼反应，分别得到四氟硼酸根离子和四氯硼酸根离子。
• Chelated fluoroboron cations. III. Spectroscopic evidence for ring size and steric limitations to chelate formation by amine chelating donors
  作者：J Stephen Hartman、James AW Shoemaker

  DOI：10.1139/v01-030

  日期：2001.4.1

  Factors affecting the ability of potentially chelating amine ligands to form chelated fluoroboron cations are explored by ¹⁹F and ¹¹B NMR spectroscopy and fast atom bombardment mass spectrometry (FAB-MS). Five-membered chelate rings form much more readily than six-membered. Some potentially chelating ligands give rise to additional fluoroboron species by various redistribution and decomposition reactions.Key words: chelated fluoroboron cations, ¹⁹F NMR, ¹¹B NMR; FAB-MS, N,N,N',N'-tetraethylethylenediamine.

  通过¹⁹F和¹¹B核磁共振光谱和快速原子轰击质谱（FAB-MS），探讨影响潜在螯合胺配体形成螯合氟硼阳离子能力的因素。五元螯合环比六元螯合环更容易形成。一些潜在螯合配体通过各种再分配和分解反应产生额外的氟硼物种。关键词：螯合氟硼阳离子，¹⁹F核磁共振，¹¹B核磁共振；FAB-MS，N,N,N',N'-四乙基乙二胺。
• New derivatives of tetrahydroborate(1–), BH₃SiF₃^–and BH₂(SiF₃)₂^–
  作者：Sydney Brownstein

  DOI：10.1039/c39800000149

  日期：——

  Silicon tetrafluoride and tetrabutylammonium (TBA) tetrahydroborate react in methylene chloride solution to produce [TBA][BH3SiF3] and [TBA][BH2(SiF3)2].

  四氟化硅和四氢硼酸四丁基铵（TBA）在二氯甲烷溶液中反应，生成[TBA] [BH 3 SiF 3 ]和[TBA] [BH 2（SiF 3）2 ]。