p,p-ditolylmagnesium

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: p,p-ditolylmagnesium
• 英文别名: ditolylmagnesium
• 化学式: C₁₄H₁₄Mg
• 分子量: 206.57
• InChiKey: ANELLYFTBMQWHK-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3.34
• 重原子数：
  15
• 可旋转键数：
  0
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.14
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  0

反应信息

• 作为反应物：
  描述：

  dichloro(1,3-diisopropyl-4,5-dimethylimidazolin-2-ylidene)germanium(II) 、 p,p-ditolylmagnesium 以 四氢呋喃 、 1,4-二氧六环 为溶剂， 生成 1,1,2,2,3,3,4,4-octa-p-tolyltetragermetane
  参考文献：
  名称：

  Synthesis and Structure of N-Heterocyclic Carbene Complexes of Germanium(II)

  摘要：

  The synthesis and structural characterization of a series of N-heterocyclic carbene (NHC) complexes of GeR1R2 are reported, where R-1 = R-2 = Mes (Mes = 2,4,6-trimethylphenyl) (1), R-1 = R-2 = F (5), R-1 = R-2 = Br (6), R-1 = Cl, R-2 = OTf (OTf = O3SCF3) (7), R-1 = R-2 = (OBu)-Bu-t (10), and R-1 = R-2 = NCS (11). The bond length between the carbenic carbon and the germanium is observed to vary in accordance with the pi-donating ability of the substituent on Ge. Efforts to synthesize stable complexes with small alkyl or aryl substituents were not successful; evidence for oligomerization of the GeR2 fragment is presented. The reaction between 1 and 3 (R-1 = R-2 = Cl) resulted in the formation of an NHC-coordinated germylgermylene (13). The H-1 NMR spectra of 3-7, 10, and 11 display broad signals at room temperature. To rationalize the H-1 NMR spectra, mechanisms for conformational interchange, as well as intermolecular exchanges, are discussed.

  DOI：

  10.1021/om800368d
• 作为产物：
  描述：

  甲基苯锂 在 magnesium chloride 作用下， 以 乙醚 为溶剂， 生成 p,p-ditolylmagnesium
  参考文献：
  名称：

  Preparation of solvated and/or unsolvated simple and mixed diarylmagnesiums

  摘要：

  DOI：

  10.1016/0022-328x(85)80218-7

文献信息

• Oxidatively Induced Reductive Elimination from a Chromium(III) Bis(aryl) Complex
  作者：K. Cory MacLeod、Brian O. Patrick、Kevin M. Smith

  DOI：10.1021/om300751z

  日期：2012.9.24

  investigated as precursors to CpCr(III) complexes. Single-electron oxidation of 1 was used to prepare CpCr(C6H4CH2NMe2)(X) for X = I (3), OTs (4), O2CPh (5), OCMe2Ph (6), SPh (7). Similarly, CpCr[C(Ph)C(Ph)C6H4CH2NMe2](X) for X = I (8), SPh (9) were obtained from 2. Reactions of 4 with PhCH2MgCl or Mg(C6H4Me)2 reagents gave the Cr(III) benzyl (10) and p-tolyl (11) complexes, respectively. The corresponding

  研究了先前报道的高自旋Cr（II）化合物CpCr（C 6 H 4 CH 2 NMe 2）（1）和CpCr [C（Ph）C（Ph）C 6 H 4 CH 2 NMe 2 ]（2）作为CpCr（III）配合物的前体。单电子氧化1用于制备CpCr（C 6 H 4 CH 2 NMe 2）（X），用于X = I（3），OTs（4），O 2 CPh（5），OCMe 2 Ph（6） ，SPh（7）。类似地，从2获得X = I（8），SPh（9）的CpCr [C（Ph）C（Ph）C 6 H 4 CH 2 NMe 2 ]（X）。的反应4与物理信道2的MgCl或Mg（C 6 H ^ 4 Me）的2种试剂，得到的Cr（III）的苄基（10）和p -甲苯基（11）配合，分别。4与Mg（CH 2 CMe 3）2的相应反应导致12的分离，具有桥联新戊叉基的双金属配合物。尽管7或10与AgOTs的反应生成了Cr（III）
• Halo, Alkyl, Aryl, and Bis(imido) Complexes of Niobium Supported by the β-Diketiminato Ligand
  作者：Neil C. Tomson、John Arnold、Robert G. Bergman

  DOI：10.1021/om1001827

  日期：2010.7.12

  by treatment with B(C6F5)3, affording the Lewis base-free complexes (BDI)Nb(NtBu)X2 (X = Cl, F). Additionally, the Lewis base-free dichlorides of the tBu-imido and Ar-imido (Ar = 2,6-iPr2-C6H3) complexes were obtained following treatment of Nb(NR)Cl3(dme) (R = tBu, Ar) with Li(BDI)(OEt2). The pyridine-coordinated dichloride was alkylated and arylated to form the dimethyl complex (BDI)Nb(NtBu)Me2 (described

  复合物 (BDI)Nb(N t Bu)Cl 2 py (BDI = HC[C(Me)N( 2,6 - i Pr 2 -C 6 H 3 )] 2 ) 以高产率合成用Li(BDI)(OEt 2 )处理Nb(N t Bu)Cl 3 py 2。通过在甲苯中引入 2.0 当量的 Me 3 SnF 来实现氯化物对氟化物的取代，以中等产率提供吡啶配位的二氟化物络合物 (BDI)Nb(N t Bu)F 2 py。通过用 B(C 6 F5 ) 3，提供路易斯无碱配合物(BDI)Nb(N t Bu)X 2 (X = Cl，F)。此外，在处理 Nb(NR)Cl 3 (dme) 后，获得了t Bu-imido 和 Ar-imido (Ar = 2,6 - i Pr 2 -C 6 H 3 ) 配合物的无路易斯碱二氯化物( R = t Bu, Ar) 和 Li(BDI)(OEt 2 )。吡啶配位的二氯化物被烷基化和芳基化以形成二甲基络合物
• Binuclear alkynylplatinum(II) complexes
  作者：Richard J. Puddephatt、Mary A. Thomson

  DOI：10.1016/s0022-328x(00)84806-8

  日期：1982.10
• Synthesis and Structure of N-Heterocyclic Carbene Complexes of Germanium(II)
  作者：Paul A. Rupar、Michael C. Jennings、Kim M. Baines

  DOI：10.1021/om800368d

  日期：2008.10.13

  The synthesis and structural characterization of a series of N-heterocyclic carbene (NHC) complexes of GeR1R2 are reported, where R-1 = R-2 = Mes (Mes = 2,4,6-trimethylphenyl) (1), R-1 = R-2 = F (5), R-1 = R-2 = Br (6), R-1 = Cl, R-2 = OTf (OTf = O3SCF3) (7), R-1 = R-2 = (OBu)-Bu-t (10), and R-1 = R-2 = NCS (11). The bond length between the carbenic carbon and the germanium is observed to vary in accordance with the pi-donating ability of the substituent on Ge. Efforts to synthesize stable complexes with small alkyl or aryl substituents were not successful; evidence for oligomerization of the GeR2 fragment is presented. The reaction between 1 and 3 (R-1 = R-2 = Cl) resulted in the formation of an NHC-coordinated germylgermylene (13). The H-1 NMR spectra of 3-7, 10, and 11 display broad signals at room temperature. To rationalize the H-1 NMR spectra, mechanisms for conformational interchange, as well as intermolecular exchanges, are discussed.
• Preparation of solvated and/or unsolvated simple and mixed diarylmagnesiums
  作者：Constantinos G. Screttas、Maria Micha-Screttas

  DOI：10.1016/0022-328x(85)80218-7

  日期：1985.9