三氯化镨六水合物

• 分子结构分类: 无机化合物 - 混合金属/非金属化合物 - 镧系盐
• 中文名称: 三氯化镨六水合物
• 中文别名: 氯化镨(III)水合物；六水氯化镨
• 英文名称: Praseodymium(III) chloride hexahydrate
• 英文别名: trichloropraseodymium;hexahydrate
• 化学式: Cl₃H₁₂O₆Pr
• 分子量: 355.358
• InChiKey: HZYWHLVESVMEHZ-UHFFFAOYSA-K

计算性质

• 辛醇/水分配系数(LogP)：
  -13.94
• 重原子数：
  10
• 可旋转键数：
  0
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  6
• 氢给体数：
  6
• 氢受体数：
  9

反应信息

• 作为反应物：
  描述：

  三氯化镨六水合物 、 aluminum ethoxide 以 甲苯 为溶剂， 生成
  参考文献：
  名称：

  Interaction of LnCl3 · 6H2O crystal hydrates with the alkoxy derivatives of aluminum in organic solvents

  摘要：

  The interaction of LnCl(3) (.) 6H(2)O (Ln = Pr, Nd, and Th) with the alkoxy derivatives of aluminum (RO)(n)AlCl3-n (where R = Et or iso-Bu; n = 1-3) in organic solvents was studied. It was found that the reaction of the crystal water of LnCl(3) (.) 6H(2)O with (RO)(n)AlCl3-n resulted in the partial dehydration of the crystal hydrates with the formation of an alcohol (ROH) and the LnCl(3)(.)3H(2)O(.)3(RO)(m)Al(OH)Cl2-m complex (m = 1, 2). The solid colloidal particles of this complex and a solvent form a lanthanide-containing gel. The physicochemical (including luminescence) and catalytic properties of the complex in butadiene polymerization and 1,1-gem-dibromo-2-phenylcyclopropane dehalogenation were studied.

  DOI：

  10.1134/s0023158406050120

文献信息

• Interaction of LnCl3 · 6H2O crystal hydrates with the alkoxy derivatives of aluminum in organic solvents
  作者：R. G. Bulgakov、S. P. Kuleshov、D. S. Karamzina、A. R. Makhmutov、R. R. Vafin、Ya. L. Shestopal、I. R. Mullagaliev、Yu. B. Monakov、U. M. Dzhemilev

  DOI：10.1134/s0023158406050120

  日期：2006.10

  The interaction of LnCl(3) (.) 6H(2)O (Ln = Pr, Nd, and Th) with the alkoxy derivatives of aluminum (RO)(n)AlCl3-n (where R = Et or iso-Bu; n = 1-3) in organic solvents was studied. It was found that the reaction of the crystal water of LnCl(3) (.) 6H(2)O with (RO)(n)AlCl3-n resulted in the partial dehydration of the crystal hydrates with the formation of an alcohol (ROH) and the LnCl(3)(.)3H(2)O(.)3(RO)(m)Al(OH)Cl2-m complex (m = 1, 2). The solid colloidal particles of this complex and a solvent form a lanthanide-containing gel. The physicochemical (including luminescence) and catalytic properties of the complex in butadiene polymerization and 1,1-gem-dibromo-2-phenylcyclopropane dehalogenation were studied.