[1-(3-Butylselanyl-propylselanyl)-ethyl]-benzene

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: [1-(3-Butylselanyl-propylselanyl)-ethyl]-benzene
• 英文别名: 1-(3-Butylselanylpropylselanyl)ethylbenzene；1-(3-butylselanylpropylselanyl)ethylbenzene
• 化学式: C₁₅H₂₄Se₂
• 分子量: 362.276
• InChiKey: AUWHYRWQTFCBBJ-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  4.6
• 重原子数：
  17
• 可旋转键数：
  9
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.6
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  0

反应信息

• 作为产物：
  描述：

  正丁基锂 、 2-Methyl-2-phenyl-[1,3]diselenane 以 四氢呋喃 为溶剂， 反应 0.5h， 以77%的产率得到[1-(3-Butylselanyl-propylselanyl)-ethyl]-benzene
  参考文献：
  名称：

  Cleavage of the CSe bond of cyclic selenoacetals derived from 4-t-butyl cyclohexanone with butyllithiums and tin and silyl hydrides

  摘要：

  Selenoacetals derived from 1,3-propanediselenol and 1,2-ethanediselenol are much less Hone to be cleaved by butyllithiums than their open chain analogues. The stereochemistry of the products resulting from these reactions as well as from the cleavage of the C-Se bond under radical conditions is disclosed.

  DOI：

  10.1016/s0040-4039(00)61373-4

文献信息

• Cleavage of the CSe bond of cyclic selenoacetals derived from 4-t-butyl cyclohexanone with butyllithiums and tin and silyl hydrides
  作者：Alain Krief、Elie Badaoui、Willy Dumont

  DOI：10.1016/s0040-4039(00)61373-4

  日期：1993.1

  Selenoacetals derived from 1,3-propanediselenol and 1,2-ethanediselenol are much less Hone to be cleaved by butyllithiums than their open chain analogues. The stereochemistry of the products resulting from these reactions as well as from the cleavage of the C-Se bond under radical conditions is disclosed.