三硫代亚磷酸三(十二烷基)脂 | 1656-63-9

• 物质功能分类: 生物 - 细胞培养 - 添加剂
• 分子结构分类: 有机化合物 - 有机磷化合物 - 有机硫代磷化合物
• 中文名称: 三硫代亚磷酸三(十二烷基)脂
• 中文别名: 三硫代亚磷酸三月硅酸；三硫代亚磷酸三(十二烷基)酯
• 英文名称: Trilauryl trithiophosphite
• 英文别名: tris(dodecylsulfanyl)phosphane
• CAS: 1656-63-9
• 化学式: C₃₆H₇₅PS₃
• mdl: MFCD00015072
• 分子量: 635.2
• InChiKey: JZNDMMGBXUYFNQ-UHFFFAOYSA-N

物化性质

• 熔点：
  23°C
• 沸点：
  667.8±38.0 °C(Predicted)
• 密度：
  0,92 g/cm3
• 闪点：
  209°C
• 溶解度：
  易溶于乙醇、甲苯

计算性质

• 辛醇/水分配系数(LogP)：
  18
• 重原子数：
  40
• 可旋转键数：
  36
• 环数：
  0.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  75.9
• 氢给体数：
  0
• 氢受体数：
  3

安全信息

• 危险等级：
  6.1(b)
• 危险类别码：
  R36/37/38,R20/21/22
• 危险品运输编号：
  2810
• 海关编码：
  2931900090
• 包装等级：
  III
• 危险类别：
  6.1(b)
• 安全说明：
  S26,S36/37/39

反应信息

• 作为反应物：
  描述：

  三硫代亚磷酸三(十二烷基)脂 生成 1-Bis(dodecylsulfanyl)phosphorylsulfanyldodecane
  参考文献：
  名称：

  KONIG, T.;HABICHER, W. D.;SCHWETLICK, K., J. PRAKT. CHEM., 331,(1989) N, C. 913-922

  摘要：

  DOI：

文献信息

• IMAGE FORMING METHOD
  申请人：GOTOU Hiroshi

  公开号：US20130155145A1

  公开（公告）日：2013-06-20

  An image forming method applying a pretreatment liquid on the surface of a recording medium; and applying an inkjet ink including a colorant, a hydrosoluble organic solvent, a surfactant and water on the surface applied with the pretreatment liquid, wherein the hydrosoluble organic solvent includes at least one polyol including an equilibrium water content in an amount not less than 30% by weight at 23° C. and 80% RH; an amide compound having the following formula (I); and at least one of compounds having the following formulae (II) to (IV), and wherein a pure water transfers to the recording medium in an amount of from 1 to 15 mL/m 2 when measured by a dynamic scanning liquid absorptometer at a contact time of 100 ms.

  一种图像形成方法，其在记录介质的表面上应用预处理液，并在应用预处理液的表面上应用包括颜料、水溶性有机溶剂、表面活性剂和水的喷墨墨水，其中水溶性有机溶剂包括至少一种多元醇，其在23℃和80%相对湿度下的平衡含水量不少于30%（重量百分比），具有以下式（I）的酰胺化合物，以及具有以下式（II）至（IV）之一的化合物，其中在100ms接触时间下，通过动态扫描液体吸收计测量，纯水向记录介质转移的量为1至15 mL/m2。
• Polymeric thermo-sensitive compositions
  申请人：MATSUSHITA ELECTRIC INDUSTRIAL CO., LTD.

  公开号：EP0028764A1

  公开（公告）日：1981-05-20

  This invention is directed to a polymeric thermo-sensitive material which comprises a polyamide composition containing compounds of sulphur-contained compounds or phosphorous acid ester, and which is smaller in polarization in the application of direct-current electric field, higher in temperature detection function, does not cause flexibility deterioration due to heating operation and is less in hygroscopicity. A composition containing thiophosphorous acid ester and bis(hydroxyphenyl) sulfide derivative from a group of the phosphorous acid ester is particularly superior in quality.

  本发明涉及一种聚合热敏材料，它由含有含硫化合物或硫代磷酸酯的聚酰胺组合物组成，在直流电场作用下极化较小，温度检测功能较强，不会因加热操作而导致柔韧性变差，吸湿性较低。含有硫代磷酸酯和来自硫代磷酸酯基团的双（羟基苯基）硫醚衍生物的组合物在质量上尤为出色。
• Photocurable composition
  申请人：KABUSHIKI KAISHA TOSHIBA

  公开号：EP0172330A1

  公开（公告）日：1986-02-26

  Disclosed are photocurable compositions which comprise (A) a compound having at least one epoxy group and at least one photocurable unsaturated ethylenic double bond within the same molecule; (B) an organometallic compound and (C) a silicon compound capable of generating silanol group by irradiation of light, or comprise (A) a compound having at least one epoxy group and at least one photocurable unsaturated ethylenic double bond within the same molecule; (E) an epoxy compound; (F) an organic phosphorus compound; and (G) a photosensitizer. The compositions of the present invention have excellent film characteristics such as good adhesion property, light resistance, heat resistance and weathering resistance.

  所公开的光固化组合物包括 (A) 在同一分子内具有至少一个环氧基团和至少一个光固化不饱和乙烯双键的化合物； (B) 有机金属化合物和 (C) 能在光照射下生成硅醇基的硅化合物，或包括 (A) 在同一分子内具有至少一个环氧基团和至少一个光固化不饱和乙烯双键的 化合物； (B) 在同一分子内具有至少一个环氧基团和至少一个光固化不饱和乙烯双键的 化合物 (E) 一种环氧化合物 (F) 有机磷化合物；以及 (G) 一种光敏剂。 本发明的组合物具有优异的薄膜特性，如良好的附着性、耐光性、耐热性和耐候性。
• Flame retardant polyolefin resin composition
  申请人：Chisso Corporation

  公开号：EP0209679A2

  公开（公告）日：1987-01-28

  A flame retardant polyolefin resin composition which, when molded, affords a molded product having highly flame retardant properties, no dripping properties, a smooth surface and an excellent appearance and superior resistances to heavy metal deterioration, heat deterioration and weather is provided, which composition consists of (A) 5 - 60% by weight of a halogen-containing flame retardant, (B) 100 - 10% by weight of antimony trioxide based on the weight of the halogen-containing flame retardant, (C) 0.5 - 15% by weight of a crosslinking agent, (D) 0.05 - 5% by weight of a specified thiophosphite, and (E) the balance % by weight of a polyolefin raein, the total of the quantities of (A), (B), (C), (D) and (E) being 100% by weight. If necessary, a processing aid may be further added to the above flame retardant polyolefin resin composition.

  本发明提供了一种阻燃聚烯烃树脂组合物，该组合物在模塑时可获得具有高度阻燃性能、无滴落性能、光滑表面和优异外观以及优异的抗重金属劣化、抗热劣化和抗风化性能的模塑产品，该组合物由以下成分组成：(A) 5 - 60% （按重量计）的含卤阻燃剂，(B) 100 - 10% （按重量计）的三氧化二锑（基于含卤阻燃剂的重量），(C) 0.5-15%（按重量计）的交联剂，（D）0.05-5%（按重量计）的特定亚硫代磷酸酯，以及（E）余下的 %（按重量计）的聚烯烃树脂，(A)、(B)、(C)、(D)和(E)的总量为 100%（按重量计）。如有必要，可在上述阻燃聚烯烃树脂组合物中进一步添加加工助剂。
• Can carrier composition
  申请人：UNION CARBIDE CORPORATION

  公开号：EP0310092A2

  公开（公告）日：1989-04-05

  A can carrier composition comprising at least one of each of the following components wherein all parts are by weight based on 100 parts by weight of component (i): (i) a high pressure polyethylene having a density in the range of about 0.918 to about 0.930 gram per cubic centimeter; (ii) a linear polyethylene having a density of less than about 0.925 gram per cubic centimeter in an amount of about 2 to about 35 parts; (iii) polyethylene wax in an amount of about 0.5 to about 5 parts; (iv) a mineral filler coated with a metal salt of a fatty acid in an amount of about 0.05 to about 0.50 parts; (v) a secondary amide in an amount of about 0.02 to about 0.15 part; (vi) an antioxidant in an amount of about 0.02 to about 0.10 part; and (vii) an organic phosphorus compound in an amount of about 0.005 to about 0.05 part.

  一种易拉罐载体组合物，包含以下每种成分中的至少一种，其中所有成分的重量均以 100 份成分(i)的重量为基准： (i) 密度在每立方厘米约 0.918 至约 0.930 克范围内的高压聚乙烯； (ii) 密度小于每立方厘米约 0.925 克的线性聚乙烯，其用量为约 2 至约 35 份； (iii) 聚乙烯蜡，用量约为 0.5 至约 5 份； (iv) 塗有脂肪酸的金屬鹽的礦物填料，份量約為 0.05 至約 0.50 份； (v) 一种仲酰胺，用量约为 0.02 至约 0.15 份 (vi) 抗氧化剂，用量约为 0.02 至约 0.10 份；以及 (vii) 有机磷化合物，用量约为 0.005 至约 0.05 份。

表征谱图