三苯基铅苯基硫化物 | 15590-77-9

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 中文名称: 三苯基铅苯基硫化物
• 英文名称: Triphenyl-phenylmercaptoblei
• 英文别名: Thiophenyl triphenyllead；triphenyl(phenylsulfanyl)plumbane
• CAS: 15590-77-9
• 化学式: C₂₄H₂₀PbS
• 分子量: 547.689
• InChiKey: BQBUWUDGISVYKZ-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  4.45
• 重原子数：
  26
• 可旋转键数：
  5
• 环数：
  4.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  25.3
• 氢给体数：
  0
• 氢受体数：
  1

SDS

---

Section 1. IDENTIFICATION OF THE SUBSTANCE/MIXTURE
Product identifiers
Product name : (THIOPHENOXY)TRIPHENYLLEAD
CAS-No. : 15590-77-9
Relevant identified uses of the substance or mixture and uses advised against
Identified uses : Laboratory chemicals, Manufacture of substances

---

Section 2. HAZARDS IDENTIFICATION
Classification of the substance or mixture
Classification according to Regulation (EC) No 1272/2008 [EU-GHS/CLP]
Reproductive toxicity (Category 1A)
Acute toxicity, Inhalation (Category 4)
Acute toxicity, Oral (Category 4)
Specific target organ toxicity - repeated exposure (Category 2)
Acute aquatic toxicity (Category 1)
Chronic aquatic toxicity (Category 1)
Classification according to EU Directives 67/548/EEC or 1999/45/EC
May cause harm to the unborn child. Possible risk of impaired fertility. Harmful by inhalation and if
swallowed. Danger of cumulative effects. Very toxic to aquatic organisms, may cause long-term adverse
effects in the aquatic environment.
Label elements
Labelling according Regulation (EC) No 1272/2008 [CLP]
Pictogram
Signal word Danger
Hazard statement(s)
H302 Harmful if swallowed.
H332 Harmful if inhaled.
H360Df May damage the unborn child. Suspected of damaging fertility.
H373 May cause damage to organs through prolonged or repeated exposure.
H410 Very toxic to aquatic life with long lasting effects.
Precautionary statement(s)
P201 Obtain special instructions before use.
P273 Avoid release to the environment.
P308 + P313 IF exposed or concerned: Get medical advice/ attention.
P501 Dispose of contents/ container to an approved waste disposal plant.
Supplemental Hazard none
Statements
Restricted to professional users.
According to European Directive 67/548/EEC as amended.
Hazard symbol(s)
R-phrase(s)
R61 May cause harm to the unborn child.
R20/22 Also harmful by inhalation and if swallowed.
R33 Danger of cumulative effects.
R50/53 Very toxic to aquatic organisms, may cause long-term adverse effects in
the aquatic environment.
R62 Possible risk of impaired fertility.
S-phrase(s)
S53 Avoid exposure - obtain special instructions before use.
S45 In case of accident or if you feel unwell, seek medical advice immediately
(show the label where possible).
S60 This material and its container must be disposed of as hazardous waste.
S61 Avoid release to the environment. Refer to special instructions/ Safety
data sheets.
Restricted to professional users.
Other hazards - none

---

Section 3. COMPOSITION/INFORMATION ON INGREDIENTS
Substances
Formula : C24H20PbS
Molecular Weight : 547,68 g/mol
Component Concentration
(THIOPHENOXY)TRIPHENYLLEAD
CAS-No. 15590-77-9 -
Index-No. 082-001-00-6

---

Section 4. FIRST AID MEASURES
Description of first aid measures
General advice
Consult a physician. Show this safety data sheet to the doctor in attendance.
If inhaled
If breathed in, move person into fresh air. If not breathing, give artificial respiration. Consult a physician.
In case of skin contact
Wash off with soap and plenty of water. Consult a physician.
In case of eye contact
Flush eyes with water as a precaution.
If swallowed
Never give anything by mouth to an unconscious person. Rinse mouth with water. Consult a physician.
Most important symptoms and effects, both acute and delayed
To the best of our knowledge, the chemical, physical, and toxicological properties have not been
thoroughly investigated.
Indication of any immediate medical attention and special treatment needed
no data available

---

Section 5. FIREFIGHTING MEASURES
Extinguishing media
Suitable extinguishing media
Use water spray, alcohol-resistant foam, dry chemical or carbon dioxide.
Special hazards arising from the substance or mixture
Carbon oxides, Sulphur oxides, Lead oxides
Advice for firefighters
Wear self contained breathing apparatus for fire fighting if necessary.
Further information
no data available

---

Section 6. ACCIDENTAL RELEASE MEASURES
Personal precautions, protective equipment and emergency procedures
Use personal protective equipment. Avoid dust formation. Avoid breathing vapors, mist or gas. Ensure
adequate ventilation. Evacuate personnel to safe areas. Avoid breathing dust.
Environmental precautions
Prevent further leakage or spillage if safe to do so. Do not let product enter drains.
Methods and materials for containment and cleaning up
Pick up and arrange disposal without creating dust. Sweep up and shovel. Keep in suitable, closed
containers for disposal.
Reference to other sections
For disposal see section 13.

---

Section 7. HANDLING AND STORAGE
Precautions for safe handling
Avoid contact with skin and eyes. Avoid formation of dust and aerosols.Avoid exposure - obtain special
instructions before use.
Provide appropriate exhaust ventilation at places where dust is formed.
Conditions for safe storage, including any incompatibilities
Store in cool place. Keep container tightly closed in a dry and well-ventilated place.
Specific end uses
no data available

---

Section 8. EXPOSURE CONTROLS/PERSONAL PROTECTION
Control parameters
Components with workplace control parameters
Exposure controls
Appropriate engineering controls
Handle in accordance with good industrial hygiene and safety practice. Wash hands before breaks and
at the end of workday.
Personal protective equipment
Eye/face protection
Safety glasses with side-shields conforming to EN166 Use equipment for eye protection tested
and approved under appropriate government standards such as NIOSH (US) or EN 166(EU).
Skin protection
Handle with gloves. Gloves must be inspected prior to use. Use proper glove removal technique
(without touching glove's outer surface) to avoid skin contact with this product. Dispose of
contaminated gloves after use in accordance with applicable laws and good laboratory practices.
Wash and dry hands.
The selected protective gloves have to satisfy the specifications of EU Directive 89/686/EEC and
the standard EN 374 derived from it.
Body Protection
Complete suit protecting against chemicals, The type of protective equipment must be selected
according to the concentration and amount of the dangerous substance at the specific workplace.
Respiratory protection
Where risk assessment shows air-purifying respirators are appropriate use a full-face particle
respirator type N100 (US) or type P3 (EN 143) respirator cartridges as a backup to engineering
controls. If the respirator is the sole means of protection, use a full-face supplied air respirator. Use
respirators and components tested and approved under appropriate government standards such
as NIOSH (US) or CEN (EU).

---

Section 9. PHYSICAL AND CHEMICAL PROPERTIES
Information on basic physical and chemical properties
a) Appearance Form: solid
b) Odour no data available
c) Odour Threshold no data available
d) pH no data available
e) Melting point/freezing no data available
point
f) Initial boiling point and no data available
boiling range
g) Flash point no data available
h) Evaporation rate no data available
i) Flammability (solid, gas) no data available
j) Upper/lower no data available
flammability or
explosive limits
k) Vapour pressure no data available
l) Vapour density no data available
m) Relative density no data available
n) Water solubility no data available
o) Partition coefficient: n- no data available
octanol/water
p) Autoignition no data available
temperature
q) Decomposition no data available
temperature
r) Viscosity no data available
s) Explosive properties no data available
t) Oxidizing properties no data available
Other safety information
no data available

---

Section 10. STABILITY AND REACTIVITY
Reactivity
no data available
Chemical stability
no data available
Possibility of hazardous reactions
no data available
Conditions to avoid
no data available
Incompatible materials
Strong oxidizing agents
Hazardous decomposition products
Other decomposition products - no data available

---

Section 11. TOXICOLOGICAL INFORMATION
Information on toxicological effects
Acute toxicity
no data available
Skin corrosion/irritation
no data available
Serious eye damage/eye irritation
no data available
Respiratory or skin sensitization
no data available
Germ cell mutagenicity
Carcinogenicity
IARC: No component of this product present at levels greater than or equal to 0.1% is identified as
probable, possible or confirmed human carcinogen by IARC.
Reproductive toxicity
Presumed human reproductive toxicant
Specific target organ toxicity - single exposure
no data available
Specific target organ toxicity - repeated exposure
May cause damage to organs through prolonged or repeated exposure.
Aspiration hazard
no data available
Potential health effects
Inhalation Harmful if inhaled. May cause respiratory tract irritation.
Ingestion
Harmful if swallowed.
Skin Harmful if absorbed through skin. May cause skin irritation.
Eyes May cause eye irritation.
Signs and Symptoms of Exposure
To the best of our knowledge, the chemical, physical, and toxicological properties have not been
thoroughly investigated.
Additional Information
RTECS: TP4516000

---

Section 12. ECOLOGICAL INFORMATION
Toxicity
no data available
Persistence and degradability
Biodegradability Result: - According to the results of tests of biodegradability this product is not
readily biodegradable.
Remarks: no data available
Bioaccumulative potential
no data available
Mobility in soil
no data available
Results of PBT and vPvB assessment
no data available
Other adverse effects
no data available

---

Section 13. DISPOSAL CONSIDERATIONS
Waste treatment methods
Product
Offer surplus and non-recyclable solutions to a licensed disposal company. Dissolve or mix the material
with a combustible solvent and burn in a chemical incinerator equipped with an afterburner and scrubber.
Contaminated packaging
Dispose of as unused product.

---

Section 14. TRANSPORT INFORMATION
UN number
ADR/RID: 2811 IMDG: 2811 IATA: 2811
UN proper shipping name
ADR/RID: TOXIC SOLID, ORGANIC, N.O.S. ((THIOPHENOXY)TRIPHENYLLEAD)
IMDG: TOXIC SOLID, ORGANIC, N.O.S. ((THIOPHENOXY)TRIPHENYLLEAD)
IATA: Toxic solid, organic, n.o.s. ((THIOPHENOXY)TRIPHENYLLEAD)
Transport hazard class(es)
ADR/RID: 6.1 IMDG: 6.1 IATA: 6.1
Packaging group
ADR/RID: III IMDG: III IATA: III
Environmental hazards
ADR/RID: no IMDG Marine pollutant: no IATA: no
Special precautions for user
no data available

---

---

SECTION 15 - REGULATORY INFORMATION
N/A

---

SECTION 16 - ADDITIONAL INFORMATION
N/A

反应信息

• 作为反应物：
  描述：

  三苯基铅苯基硫化物 、 cyclohexyl-[2-(4-fluorophenyl)ethynyl]mercury 以 甲苯 为溶剂， 生成 [(4-Fluorophenyl)ethynyl](triphenyl)plumbane 、 cyclohexylmercury thiophenolate
  参考文献：
  名称：

  C,N and C,S transfers in exchange equilibria involving 4-fluorophenylacetylene, benzenesulfonanilide, and thiophenol and their organometallic derivatives

  摘要：

  DOI：

  10.1007/bf00955355
• 作为产物：
  描述：

  氯化三苯基铅 以 乙醚 、 苯 为溶剂， 生成 三苯基铅苯基硫化物
  参考文献：
  名称：

  （环戊二烯基）苯基铅（IV）化合物的化学

  摘要：

  黄色空气稳定的（环戊二烯基）苯基-铅（IV）化合物，PbPh 4- Ñ（CP）ñ [ Ñ = 1或2，CP = C 5 H ^ 5 ]，已经通过相应的苯基的反应合成氯化铅（IV）和环戊二烯化锂在乙醚中的溶液。PbPh 3（cp）的晶体是单斜晶体，空间群P 2 1 / c，其中a = 9.5426，b = 12.3843，c = 16.1714Å，β= 102.3358°和Z＝ 4，并且包括具有扭曲的四面体几何形状的离散的非相互作用分子。Pb–C（cp）键的距离[2.30（2）Å]明显长于Pb–C（Ph）的距离[平均2.22（2）Å]，表明该键的强度明显减弱。环戊二烯基环（平面）的环内CC键与远离铅的碳原子上的π电子密度浓度一致。PbPh 3（cp）与乙酸，苯硫酚和咪唑的反应继续进行Pb–C（cp）键裂解，得到PbPh 3（O 2 CMe），PbPh 3（SPh）和PbPh 3（N 2 C 3

  DOI：

  10.1039/dt9820001055

文献信息

• Reactivity of allylic and vinylic silanes, germanes, stannanes and plumbanes toward SH2′ or SH2 substitution by carbon- or heteroatom-centered free radicals
  作者：James P. Light、Michael Ridenour、Lois Beard、James W. Hershberger

  DOI：10.1016/0022-328x(87)80119-5

  日期：1987.5

  E-PhCHCHMR3 (M  Si, Ge, Sn, Pb) were allowed to react with a series of heteroatom-centered radicals (PhY ·, Y = S, Se, Te, derived from PhYYPh) and carbon-centered radicals ((CH3)2CH · derived from (CH3)2CHHgCl). We report that alkenylplumbanes and, under forcing conditions, alkenylgermanes undergo SH2 or SH2′ substitution of the metal by chain mechanism analogous to those previously reported for alkenylstannanes

  类型CH的化合物2 CHCH 2 MR 3和ë -PhCHCHMR 3（M硅，锗，锡，铅）被允许与一系列杂原子中心自由基（PHY·，Y = S，硒的反应，Te（源自PhYYPh）和碳中心自由基（（CH 3）2 CH·源自（CH 3）2 CHHgCl）。我们报告说，烯基铅烷和在强迫条件下，烯基锗烷通过类似于先前针对烯基锡烷所报道的链机理经历了金属的S H 2或S H 2'取代。烯基硅烷是不反应的。
• Novel room light-induced disproportionation reaction of organo-ditin and -dilead compounds with organic dichalcogenides: an efficient salt-free route to organo-tin and -lead chalcogenides
  作者：Farzad Mirzaei、Li-Biao Han、Masato Tanaka

  DOI：10.1039/b000309n

  日期：——

  Disproportionation of organo-ditin and -dilead compounds (R3M)2 (M = Sn, Pb) with organic dichalcogenides (R′Z)2 (Z = S, Se, Te) is efficiently promoted by room light to produce the corresponding organo-tin and -lead chalcogenides R3MZR′ quantitatively.

  有机二锡和二铅化合物 (R3M)2 (M = Sn, Pb) 与有机二硫代元素 (R′Z)2 (Z = S, Se, Te) 的不成比例反应在室光下高效促进，定量生成相应的有机锡和铅硫化物 R3MZR′。
• The chemistry of (cyclopentadienyl)phenyl-lead(IV) compounds
  作者：Christine Gaffney、Philip G. Harrison

  DOI：10.1039/dt9820001055

  日期：——

  Pb–C(cp) bond cleavage affording PbPh3(O2CMe), PbPh3(SPh), and PbPh3(N2C3H3), respectively. Only PbPh4 was isolated from the reaction with 4-chlorophenol. The compound PbPh2(cp)2 decomposes on attempted sublimation at 60–70 °C and 0.01 mmHg giving Pb(cp)2, whilst reaction with hydrogen chloride, carboxylic acids, and imidazole yields the corresponding diphenyl-lead(IV) derivative. Cleavage of all four

  黄色空气稳定的（环戊二烯基）苯基-铅（IV）化合物，PbPh 4- Ñ（CP）ñ [ Ñ = 1或2，CP = C 5 H ^ 5 ]，已经通过相应的苯基的反应合成氯化铅（IV）和环戊二烯化锂在乙醚中的溶液。PbPh 3（cp）的晶体是单斜晶体，空间群P 2 1 / c，其中a = 9.5426，b = 12.3843，c = 16.1714Å，β= 102.3358°和Z＝ 4，并且包括具有扭曲的四面体几何形状的离散的非相互作用分子。Pb–C（cp）键的距离[2.30（2）Å]明显长于Pb–C（Ph）的距离[平均2.22（2）Å]，表明该键的强度明显减弱。环戊二烯基环（平面）的环内CC键与远离铅的碳原子上的π电子密度浓度一致。PbPh 3（cp）与乙酸，苯硫酚和咪唑的反应继续进行Pb–C（cp）键裂解，得到PbPh 3（O 2 CMe），PbPh 3（SPh）和PbPh 3（N 2 C 3
• C,N and C,S transfers in exchange equilibria involving 4-fluorophenylacetylene, benzenesulfonanilide, and thiophenol and their organometallic derivatives
  作者：A. S. Peregudov、V. F. Ivanov、D. N. Kravtsov

  DOI：10.1007/bf00955355

  日期：1986.5