Di-(2-n-propoxyphenyl)-phenyl-phosphin

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: Di-(2-n-propoxyphenyl)-phenyl-phosphin
• 英文别名: Phenyl-bis(2-propoxyphenyl)phosphane
• 化学式: C₂₄H₂₇O₂P
• 分子量: 378.451
• InChiKey: BEJJEQCMVYZFRR-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  6.3
• 重原子数：
  27
• 可旋转键数：
  9
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.25
• 拓扑面积：
  18.5
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为产物：
  描述：

  丙氧基苯 、 苯基二氯化磷 在 正丁基锂 作用下， 生成 Di-(2-n-propoxyphenyl)-phenyl-phosphin
  参考文献：
  名称：

  Horner, L.; Simons, G., Phosphorus and Sulfur and the Related Elements, 1983, vol. 14, p. 189 - 210

  摘要：

  DOI：

文献信息

• HORNER, L.;SIMONS, G., PHOSPH. AND SULFUR, 1983, 14, N 2, 189-209
  作者：HORNER, L.、SIMONS, G.

  DOI：——

  日期：——
• AN IMPROVED PROCESS FOR TELOMERIZATION OF BUTADIENE
  申请人：Dow Global Technologies LLC

  公开号：EP2321244A2

  公开（公告）日：2011-05-18
• IMPROVED PROCESS FOR TELOMERIZATION OF BUTADIENE
  申请人：Dow Global Technologies LLC

  公开号：EP2321244B1

  公开（公告）日：2016-12-21
• PROCESS FOR TELOMERIZATION OF BUTADIENE
  申请人：Briggs John R.

  公开号：US20110137086A1

  公开（公告）日：2011-06-09

  In an improved process for telomerizing butadiene, contact butadiene and an organic hydroxy compound represented by formula ROH (I), wherein R is a substituted or unsubstituted C 1 -C 20 -hydrocarbyl and the organic hydroxy compound is not glycerol, in a reaction fluid in the presence of a palladium catalyst and a phosphine ligand represented by formula PAr 3 (II), wherein each Ar is independently a substituted or unsubstituted aryl having a hydrogen atom on at least one ortho position, at least two Ar groups are ortho-hydrocarbyloxyl substituted aryls. The phosphine ligand has a total of two (2), three (3), four (4), five (5), or six (6) substituted or unsubstituted C 1 -C 20 -hydrocarbyloxyls, and optionally, any two adjacent substituents on an Ar group can be bonded to form a 5- to 7-membered ring.
• US8558030B2
  申请人：——

  公开号：US8558030B2

  公开（公告）日：2013-10-15