[4-(dibenzo[b,d]thiophen-2-yl)phenyl]diphenylamine

• 分子结构分类: 有机化合物 - 有机氮化合物
• 英文名称: [4-(dibenzo[b,d]thiophen-2-yl)phenyl]diphenylamine
• 英文别名: 4-(dibenzothiophene-2-yl)triphenylamine；4-dibenzothiophen-2-yl-N,N-diphenylaniline
• 化学式: C₃₀H₂₁NS
• 分子量: 427.569
• InChiKey: BGUBMQDGHYXYFJ-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  9.1
• 重原子数：
  32
• 可旋转键数：
  4
• 环数：
  6.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  31.5
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  [4-(dibenzo[b,d]thiophen-2-yl)phenyl]diphenylamine 在 N-溴代丁二酰亚胺(NBS) 作用下， 以 氯仿 为溶剂， 以93%的产率得到
  参考文献：
  名称：

  아민계 화합물 및 이를 포함하는 유기 발광 소자

  摘要：

  本规范提供了胺类化合物及包含其的有机发光器件。

  公开号：

  KR20150024804A
• 作为产物：
  描述：

  二苯并噻吩-2-硼酸 、 4-溴三苯胺 在 二(三叔丁基膦)钯 、 sodium t-butanolate 作用下， 以 甲苯 为溶剂， 以83.43%的产率得到[4-(dibenzo[b,d]thiophen-2-yl)phenyl]diphenylamine
  参考文献：
  名称：

  아민계 화합물 및 이를 포함하는 유기 발광 소자

  摘要：

  本规范提供了胺类化合物及包含其的有机发光器件。

  公开号：

  KR20150024804A

文献信息

• Organic electroluminescent derivatives containing dibenzothiophene and diarylamine segments
  作者：Tai-Hsiang Huang、Wha-Tzong Whang、Jiun Yi Shen、Jiann T. Lin、Hegen Zheng

  DOI：10.1039/b507210g

  日期：——

  A new series of 2,8-disubstituted dibenzothiophenes have been successfully synthesized via palladium-catalyzed C–N or C–C bond formation using 2,8-dibromodibenzothiophene and diarylamines as starting materials. These new dibenzothiophene derivatives are amorphous with a glass transition temperature ranging from 86 to 190 °C. Furthermore, they are fluorescent in the blue to bluish green region. Two types of light-emitting diodes (LED) were constructed from these compounds, (I) ITO/Cpd/TPBI/LiF/Al and (II) ITO/Cpd/Alq3/LiF/Al, where TPBI and Alq3 are 1,3,5-tris(N-phenylbenzimidazol-2-yl)benzene and tris(8-hydroxyquinolinato)aluminium, respectively. In type I devices, the compounds function as the hole-transporting and emitting material. In type II devices, emission from Alq3 is observed. Several type I devices emit pure blue light, and most of the devices II have very promising performance. The relation between the energy levels of the materials and the performance of the light-emitting diodes is discussed.

  以 2,8-二溴二苯并噻吩和二芳基胺为起始原料，通过钯催化 C-N 或 C-C 键的形成，成功合成了一系列新的 2,8-二取代二苯并噻吩。这些新的二苯并噻吩衍生物是无定形的，玻璃化转变温度为 86 至 190 ℃。此外，它们还具有蓝色至蓝绿色荧光。利用这些化合物构建了两种类型的发光二极管（LED）：（I）ITO/Cpd/TPBI/LiF/Al 和（II）ITO/Cpd/Alq3/LiF/Al，其中 TPBI 和 Alq3 分别是 1,3,5-三（N-苯基苯并咪唑-2-基）苯和三（8-羟基喹啉）铝。在 I 型器件中，这些化合物起着空穴传输和发射材料的作用。在 II 型器件中，可观察到 Alq3 的发射。有几个 I 型器件能发出纯蓝光，而大多数 II 型器件的性能都很不错。本文讨论了材料能级与发光二极管性能之间的关系。
• Constructing a novel single-layer white organic light-emitting device through a new sky-blue fluorescent bipolar host
  作者：Jun Ye、Kai Wang、Zhan Chen、Fei-Fei An、Yi Yuan、Chi Zhang、Xiao-Hong Zhang、Chun-Sing Lee

  DOI：10.1016/j.orgel.2014.10.007

  日期：2014.12

  A novel device concept was realized for simple single-layer small-molecule white organic light emitting devices. The single organic active layer here is simply comprised of a newly synthesized sky-blue fluorescent bipolar host (TPASO) and a common orange phosphorescent dopant. Suppressed singlet Foster energy transfer induced by a low-concentration doping and spontaneous high- to low-lying triplet energy transfer, respectively, lead to sky-blue fluorescence from TPASO and orange phosphorescence from the dopant. The resulting two-organic-component device exhibits a low turn-on voltage of 2.4 V, maximum current/power efficiencies up to 11.27 +/- 0.02 cd A(-1) and 14.15 +/- 0.03 lm W-1, and a warm-white CIE coordinate of (0.42, 0.45) at 1000 cd m(2). (C) 2014 Elsevier B.V. All rights reserved.
• MATERIAL FOR ORGANIC LIGHT-EMITTING DEVICE, AND ORGANIC LIGHT-EMITTING DEVICE USING SAME
  申请人：LG Chem, Ltd.

  公开号：EP2755254B1

  公开（公告）日：2018-02-21
• ORGANIC OPTOELECTRONIC DEVICE, AND DISPLAY DEVICE INCLUDING THE SAME
  申请人：SAMSUNG SDI CO., LTD.

  公开号：US20150280136A1

  公开（公告）日：2015-10-01

  An organic optoelectronic device and a display device including the same are disclosed, and the organic optoelectronic device includes an anode, a cathode and at least one organic layer interposed between the anode and the cathode, wherein the organic thin layer includes an emission layer, a hole transport layer, a hole injection layer, an electron transport layer, an electron injection layer, or a combination thereof, the organic thin layer includes an emission layer and a plurality of a hole transport layers, the hole transport layer contacting the emission layer of the plurality of hole transport layer includes a compound represented by a combination of Chemical Formula 1, Chemical Formula 2 or 3, and Chemical Formula 4, and one of the hole transport layers not contacting the emission layer includes a compound represented by Chemical Formula B-1.
• US9553270B2
  申请人：——

  公开号：US9553270B2

  公开（公告）日：2017-01-24