9,9-bis(3-tert-butyl-4-hydroxyphenyl)fluorene

• 分子结构分类: 有机化合物 - 苯类化合物 - 芴
• 英文名称: 9,9-bis(3-tert-butyl-4-hydroxyphenyl)fluorene
• 英文别名: 9,9-bis(4-hydroxy-3-tert-butylphenyl)fluorene；2-Tert-butyl-4-[9-(3-tert-butyl-4-hydroxyphenyl)fluoren-9-yl]phenol
• 化学式: C₃₃H₃₄O₂
• 分子量: 462.632
• InChiKey: BHEUHZKBYVNFKH-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  9.3
• 重原子数：
  35
• 可旋转键数：
  4
• 环数：
  5.0
• sp3杂化的碳原子比例：
  0.27
• 拓扑面积：
  40.5
• 氢给体数：
  2
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  9,9-bis(3-tert-butyl-4-hydroxyphenyl)fluorene 、 对硝基氯苯 在 potassium carbonate 作用下， 以 N,N-二甲基甲酰胺 、 甲苯 为溶剂， 反应 7.0h， 以82%的产率得到9,9-bis[3-tert-butyl-4-(4-nitrophenoxy)phenyl]fluorene
  参考文献：
  名称：

  一种含双叔丁基结构的芳香二胺单体及其制 备方法与应用

  摘要：

  本发明提供了一种含双叔丁基结构芳香二胺单体，其制备方法为：首先由双酚化合物9,9‑双(3‑叔丁基‑4‑羟基苯基)芴与对氯硝基苯在碱性条件下反应，得到二硝基化合物9,9‑双[3‑叔丁基‑4‑(4‑硝基苯氧基)苯基]芴；然后将二硝基化合物在有机溶剂中进行催化还原，得到芳香二胺单体9,9‑双[3‑叔丁基‑4‑(4‑胺基苯氧基)苯基]芴。该含双叔丁基结构芳香二胺单体可应用于可溶性聚醚酰亚胺的制备，所制聚醚酰亚胺具有良好的成膜性、高的热性能和优良的气体分离性能。

  公开号：

  CN104356011B

文献信息

• Optically active compound and photosensitive resin composition
  申请人：——

  公开号：US20030211421A1

  公开（公告）日：2003-11-13

  A photoactive compound is used in combination with a photosensitizer, represented by the following formula (1): A −[( J ) m −( X-Pro )] n (1) wherein A represents a hydrophobic unit comprising at least one kind of hydrophobic groups selected from a hydrocarbon group and a heterocyclic group, J represents a connecting group, X-Pro represents a hydrophilic group protected by a protective group Pro which is removable by light exposure, m represents 0 or 1, and n represents an integer of not less than 1. The protective group Pro may be removable by light exposure in association with the photosensitizer (especially, a photo acid generator), or may be a hydrophobic protective group. The hydrophilic group may be a hydroxyl group or a carboxyl group. The photoactive compound has high sensitivity to a light source of short wavelength beams, for resist application, therefore, the photoactive compound is advantageously used for forming a pattern with high resolution.

  一种光活性化合物与光敏剂结合使用，由以下公式（1）表示： A −[( J ) m −( X-Pro )] n (1) 其中，A代表至少包括一种从烃基和杂环基中选择的疏水基的疏水单元，J代表连接基团，X-Pro代表由光照可去除的保护基团Pro保护的亲水基团，m代表0或1，n代表不少于1的整数。 保护基团Pro可以与光敏剂（特别是光酸发生剂）一起通过光照可去除，也可以是疏水保护基团。亲水基团可以是羟基或羧基。光活性化合物对短波长光源具有很高的敏感性，用于光刻应用，因此，该光活性化合物有利于形成具有高分辨率的图案。
• (METH)ACRYLIC RESIN COMPOSITION, FILM, POLARIZING PLATE PROTECTIVE FILM, POLARIZING PLATE, AND LIQUID CRYSTAL DISPLAY DEVICE
  申请人：FUJIFILM Corporation

  公开号：US20160376463A1

  公开（公告）日：2016-12-29

  There is provided a (meth)acrylic resin composition, containing a (meth)acrylic resin; a compound denoted by General Formula (1) described below; and a specific compound: wherein R 1 to R 8 each independently represent a hydrogen atom, a halogen atom, a hydroxyl group, or a hydrocarbon group having 1 to 6 carbon atoms, R 11 and R 12 each independently represent a hydrogen atom, a halogen atom, or a hydrocarbon group having 1 to 12 carbon atoms, m and n each independently represent an integer of 0 to 4, in a case where m and n represent an integer of greater than or equal to 2, a plurality of R 11 's and R 12 's may be identical to each other or different from each other, at least two R 11 's, at least two R 12 's, or R 11 and R 12 may form a ring by being linked to each other.

  提供了一种（甲基）丙烯酸树脂组合物，包含以下化合物：(甲基)丙烯酸树脂；符合下式（1）的化合物；以及一种特定的化合物： 其中，R1至R8各自独立地表示氢原子、卤素原子、羟基或具有1到6个碳原子的碳氢基团，R11和R12各自独立地表示氢原子、卤素原子或具有1到12个碳原子的碳氢基团，m和n各自独立地表示0到4的整数，在m和n表示大于或等于2的整数的情况下，多个R11和R12可以相同或不同，至少两个R11、至少两个R12或R11和R12可以通过彼此连接形成环。
• OPTICAL FILM
  申请人：Motoyoshi Tetsuya

  公开号：US20110288261A1

  公开（公告）日：2011-11-24

  The object of this invention is to provide an optical film formed of a copolycarbonate having a desired chromatic dispersion and low photoelasticity and having excellent melt processability. The optical film comprises a copolycarbonate composed of 25 to 90 mol % of unit (A) of the following formula, wherein each of R 1 and R 2 is independently a hydrogen atom, a hydrocarbon group having 1 to 10 carbon atoms or a halogen atom, each of R 3 and R 4 is independently a hydrocarbon group having 1 to 10 carbon atoms, each of m and n is independently an integer of 0 to 4, and each of p and q is independently an integer of 0 or more, and 10 to 75 mol % of unit (B) of the following formula, wherein R a is a monocyclic or polycyclic alicyclic hydrocarbon group having 4 to 20 carbon atoms, the alicyclic hydrocarbon group may contain a hetero atom or may have a bridge structure, and q is 0 or 1, the optical film satisfying the following expression (1), R (450)< R (550)< R (650)  (1) wherein R(450), R(550) and R(650) are in-plane retardation values of the film at wavelengths of 450 nm, 550 nm and 650 nm.

  本发明的目的是提供一种光学薄膜，其由具有所需色散和低光弹性以及优异的熔融加工性的共聚碳酸酯形成。该光学薄膜包括由以下式中25至90摩尔％的(A)单元组成的共聚碳酸酯，其中R1和R2各自独立地为氢原子，具有1至10个碳原子的烃基或卤素原子，R3和R4各自独立地为具有1至10个碳原子的烃基，m和n各自独立地为0至4的整数，p和q各自独立地为0或更多的整数，并且由以下式中10至75摩尔％的(B)单元组成，其中Ra是具有4至20个碳原子的单环或多环脂环烃基，脂环烃基可以含有杂原子或具有桥式结构，q为0或1，该光学薄膜满足以下式(1)，R(450)
• OPTICALLY ACTIVE COMPOUND AND PHOTOSENSITIVE RESIN COMPOSITION
  申请人：Kansai Research Institute, Inc.

  公开号：EP1375463A1

  公开（公告）日：2004-01-02

  A photoactive compound is used in combination with a photosensitizer, represented by the following formula (1):         A-[(J)m-(X-Pro)]n     (1)    wherein A represents a hydrophobic unit comprising at least one kind of hydrophobic groups selected from a hydrocarbon group and a heterocyclic group, J represents a connecting group, X-Pro represents a hydrophilic group protected by a protective group Pro which is removable by light exposure, m represents 0 or 1, and n represents an integer of not less than 1. The protective group Pro may be removable by light exposure in association with the photosensitizer (especially, a photo acid generator), or may be a hydrophobic protective group. The hydrophilic group may be a hydroxyl group or a carboxyl group. The photoactive compound has high sensitivity to a light source of short wavelength beams, for resist application, therefore, the photoactive compound is advantageously used for forming a pattern with high resolution.

  光活性化合物与光敏剂结合使用，光敏剂由下式（1）表示： A-[(J)m-(X-Pro)]n (1) 其中 A 代表疏水单元，包括至少一种选自烃基和杂环基的疏水基团；J 代表连接基团；X-Pro 代表亲水基团，该亲水基团受保护基团 Pro 的保护，该保护基团可通过光照去除；m 代表 0 或 1；n 代表不小于 1 的整数。 保护基 Pro 可以通过与光敏剂（特别是光酸发生器）一起进行光照射而去除，也可以是疏水保护基。亲水基团可以是羟基或羧基。光活性化合物对短波长光束的光源具有很高的灵敏度，因此在抗蚀剂应用中，光活性化合物可用于形成具有高分辨率的图案。
• AROMATIC COMPOUND HAVING FLUORENE SKELETON AND POLYARYLENE HAVING SULFONIC ACID GROUP
  申请人：JSR Corporation

  公开号：EP2011812A1

  公开（公告）日：2009-01-07

  Sulfonated polyarylenes have excellent processability and methanol resistance. The polyarylene includes a structural unit (S) represented by Formula (2-2) below and a structural unit (T) represented by Formula (2-3) below, the structural unit (S) accounting for a proportion "s" of 95 to 50 mol%, the structural unit (T) accounting for a proportion "t" of 5 to 50 mol% ("s"+ "t" = 100 mol%) : wherein each A independently represents a divalent linking group represented by -CO- or -SO2-; and R1 to R4 each independently represent a hydrogen atom, a fluorine atom, an alkyl group or an aryl group.

  磺化聚芳基烯具有优异的加工性和耐甲醇性。 聚芳基烯包括下式（2-2）表示的结构单元（S）和下式（2-3）表示的结构单元（T），结构单元（S）所占比例 "s "为 95 至 50 摩尔%，结构单元（T）所占比例 "t "为 5 至 50 摩尔%（"s "+"t"=100 摩尔%）： 其中，每个 A 独立地代表由 -CO- 或 -SO2- 表示的二价连接基团；R1 至 R4 各自独立地代表氢原子、氟原子、烷基或芳基。