2-(benzo[b]thiophen-2-yl)propanal

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 苯并噻吩类
• 英文名称: 2-(benzo[b]thiophen-2-yl)propanal
• 英文别名: 2-(1-Benzothiophen-2-yl)propanal；2-(1-benzothiophen-2-yl)propanal
• 化学式: C₁₁H₁₀OS
• 分子量: 190.266
• InChiKey: BKIKMMIIVWMUIQ-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  2.9
• 重原子数：
  13
• 可旋转键数：
  2
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.18
• 拓扑面积：
  45.3
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为产物：
  描述：

  2-(benzo[b]thiophen-2-yl)-2-methyloxirane 在 zinc(II) chloride 作用下， 以 甲苯 为溶剂， 以97 %的产率得到2-(benzo[b]thiophen-2-yl)propanal
  参考文献：
  名称：

  NOVEL RUTHENIUM COMPLEXES, METHOD OF THEIR SYNTHESIS, INTERMEDIATE COMPOUNDS USED IN THIS METHOD, METHOD OF THEIR SYNTHESIS AND USE OF NOVEL RUTHENIUM COMPLEXES IN OLEFIN METATHESIS REACTIONS

  摘要：

  The object of the invention is a novel ruthenium complex of the general formula Ru-1, in which all the variable substituents have the meanings defined in the description. Also an object of the invention is a method for obtaining the ruthenium complex, a ligand precursor intermediate compound used in the preparation of the ruthenium complex CAAC-1 and the use of this ruthenium complex as a (pre)catalyst in olefin metathesis reactions.

  公开号：

  WO2024052871A1

文献信息

• The Use of Formaldehyde in the Rhodium-Catalyzed Linear-Selective Hydroformylation of Vinylheteroarenes
  作者：Tsumoru Morimoto、Jian Pan、Hideyuki Kobayashi、Hiroki Tanimoto、Kiyomi Kakiuchi

  DOI：10.3987/com-19-14064

  日期：——
• NOVEL RUTHENIUM COMPLEXES, METHOD OF THEIR SYNTHESIS, INTERMEDIATE COMPOUNDS USED IN THIS METHOD, METHOD OF THEIR SYNTHESIS AND USE OF NOVEL RUTHENIUM COMPLEXES IN OLEFIN METATHESIS REACTIONS
  申请人：[en]UNIWERSYTET WARSZAWSKI

  公开号：WO2024052871A1

  公开（公告）日：2024-03-14

  The object of the invention is a novel ruthenium complex of the general formula Ru-1, in which all the variable substituents have the meanings defined in the description. Also an object of the invention is a method for obtaining the ruthenium complex, a ligand precursor intermediate compound used in the preparation of the ruthenium complex CAAC-1 and the use of this ruthenium complex as a (pre)catalyst in olefin metathesis reactions.