5-Chloramino-N-chloropentanimine

• 分子结构分类: 有机化合物 - 有机氮化合物
• 英文名称: 5-Chloramino-N-chloropentanimine
• 英文别名: N-chloro-5-chloroiminopentan-1-amine
• 化学式: C₅H₁₀Cl₂N₂
• 分子量: 169.054
• InChiKey: BMYQMSXZTURGKP-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  1.5
• 重原子数：
  9
• 可旋转键数：
  5
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.8
• 拓扑面积：
  24.4
• 氢给体数：
  1
• 氢受体数：
  2

反应信息

• 作为产物：
  描述：

  L-赖氨酸盐酸盐 在 氯 作用下， 以 水 为溶剂， 反应 0.5h， 生成 5-Dichloraminopentanal 、 5-Chloramino-N-chloropentanimine 、 5-Dichloramino-N-chloropentanimine 、 N,N'-Dichlorolysine
  参考文献：
  名称：

  Chloramines V:  Products and Implications of the Chlorination of Lysine in Municipal Wastewaters

  摘要：

  The chlorination reactions of lysine (Lys) in water and wastewater were studied. 5-Chloraminopentanal (VIII) and 5-dichloraminopentanal (IX) are the main products at Cl-2/Lys molar ratios of I and 2 after 30-min contact time. Formation of N,N-dichlorolysine (V) was suggested but not confirmed. 5-Dichloramino-N-chloropentanimine (XII) and 5-dichloraminopentanenitrile (XV) are the main producs at Cl-2/Lys molar ratios of 4 and 5. At a Cl-2/Lys molar ratio of 3, a compound believed to be 5-chloramino-N-chloropentanimine (XI) was observed, but its yield was small. Half-lives of lysine chlorination products in model solutions were found to be as follows: 0.8 (V), 1.5 (XI), 23 (XII), >45 (VIII and IX), and 210 h (XV). The concentrations of lysine and its chlorination products after 30-min contact time were determined in a primary municipal wastewater. All have the potential to interfere with the proper measurement of disinfection levels in chlorinated wastewaters.

  DOI：

  10.1021/es960534t