1-(6-chloro-pyridin-3-yl)-2-(nitromethylene)imidazolidine

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 吡啶及其衍生物
• 英文名称: 1-(6-chloro-pyridin-3-yl)-2-(nitromethylene)imidazolidine
• 英文别名: 2-nitromethylene-1-(6-chloro-pyridin-3-yl)-imidazolidine；1-(6-chloro-3-pyridyl)-2-(nitromethylene)imidazolidine；2-nitromethylene-1-(6-chloro-3-pyridyl)imidazolidine；2-chloro-5-[(2E)-2-(nitromethylidene)imidazolidin-1-yl]pyridine
• 化学式: C₉H₉ClN₄O₂
• 分子量: 240.649
• InChiKey: BONVNNBQRUDIOQ-RMKNXTFCSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  1.9
• 重原子数：
  16
• 可旋转键数：
  1
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.22
• 拓扑面积：
  74
• 氢给体数：
  1
• 氢受体数：
  5

反应信息

• 作为反应物：
  描述：

  1-(6-chloro-pyridin-3-yl)-2-(nitromethylene)imidazolidine 、 3-氯苯硫酚 在 聚合甲醛 作用下， 以 甲醇 、 氯仿 、 2-nitromethylene-1-(6-chloro-3-pyridyl) imidazolidine 为溶剂， 以68%的产率得到1-(6-chloro-pyridin-3-yl)-2-(1-nitro-2-(3-chloro-phenylthio)ethylidene)imidazolidine
  参考文献：
  名称：

  Nitromethylene compounds and their use as pesticides

  摘要：

  本文介绍了一般式为的亚硝基甲烯化合物，其中n为1或2; R¹为可选择性取代的3-吡啶基团；每个R²独立地选择自烷基、卤代烷基或氢原子；m为0、1或2；R³为可选择性取代的芳基、烷基、烯基或烷基羰基团。同时还介绍了它们的制备过程以及作为杀虫剂的用途。

  公开号：

  EP0605059A1
• 作为产物：
  描述：

  N-(6-chloro-pyridin-3-yl)-1,2-diaminoethane 、 1,1-双(甲硫基)-2-亚硝基乙烯 以 甲醇 、 乙醇 、 二氯甲烷 为溶剂， 以25%的产率得到1-(6-chloro-pyridin-3-yl)-2-(nitromethylene)imidazolidine
  参考文献：
  名称：

  N-pyridyl nitromethylene heterocyclic compounds and their use as

  摘要：

  本发明提供了一般式为##STR1##的亚硝基甲烯化合物，其中n为2、3或4，R.sup.1为可选取代的3-吡啶基团，每个R.sup.2独立地选自烷基团、卤代烷基团或氢原子，R.sup.3为氢原子或烷基羰基团，它们的制备过程以及它们作为农药，特别是杀虫剂的用途。

  公开号：

  US05039686A1

文献信息

• COATED PESTICIDAL MATRICES, A PROCESS FOR THEIR PREPARATION AND COMPOSITIONS CONTAINING THEM
  申请人：——

  公开号：US20030194419A1

  公开（公告）日：2003-10-16

  The present invention provides improved coated pesticidal matrices and a process for their preparation. The present invention also provides a wettable powder pesticidal composition containing the improved coated pesticidal matrices.

  本发明提供了改进的涂层杀虫剂基质及其制备方法。本发明还提供了一种含有改进的涂层杀虫剂基质的可湿性粉剂杀虫剂组合物。
• Nitromethylene compounds, their preparation and their use as pesticides
  申请人：SHELL INTERNATIONALE RESEARCH MAATSCHAPPIJ B.V.

  公开号：EP0369526A2

  公开（公告）日：1990-05-23

  The invention provides nitromethylene compounds of general formula wherein n is 2, 3 or 4, R¹ is an optionally substituted 3-pyridyl group, each R² is independently selected from an alkyl group, a haloalkyl group or a hydrogen atom, and R³ is a hydrogen atom or an alkylcarbonyl group, processes for their preparation, and their use as pesticides, particularly insecticides.

  本发明提供通式如下的硝基亚甲基化合物 其中 n 是 2、3 或 4，R¹ 是任选取代的 3-吡啶基，每个 R² 独立地选自烷基、卤代烷基或氢原子，R³ 是氢原子或烷基羰基，其制备方法及其作为杀虫剂，特别是杀虫剂的用途。
• Coated pesticidal matrices, a process for their preparation and compositions containing them
  申请人：American Cyanamid Company

  公开号：EP0890308A1

  公开（公告）日：1999-01-13

  The present invention provides improved coated pesticidal matrices and a process for their preparation. The present invention also provides a wettable powder pesticidal composition containing the improved coated pesticidal matrices.

  本发明提供了改进的包衣杀虫基质及其制备工艺。本发明还提供了一种含有改良包衣农药基质的可湿性粉剂农药组合物。
• Combination of Active Substances with Insecticidal Properties
  申请人：Funke Christian

  公开号：US20070232598A1

  公开（公告）日：2007-10-04

  The invention relates to novel insecticidal active compound combinations comprising, firstly, compounds which act as insecticides on nicotinergic acetylcholine receptors as agonists and antagonists, and at least one active compound from the group of the anthranilamides, which combinations are suitable for protecting plants against attack by pests.
• Insecticidal compositions
  申请人：Erdelen Christoph

  公开号：US20070275971A1

  公开（公告）日：2007-11-29

  The present invention relates to insecticidal mixtures of chloronicotinyl insecticides of the formula (I) in which R 1 represents C 1 -C 5 -alkyl, R 2 represents hydrogen or C 1 -C 5 -alkyl or R 1 and R 2 together represent —CH 2 —CH 2 —; —CH 2 —CH 2 —CH 2 — or X represents an NH group, NCH 3 group or represents sulphur, Y represents nitrogen or a CH group and Z represents cyano or nitro, with one or more of the synergists mentioned in the description.