Molecular and Electronic-Structure Basis of the Ambipolar Behavior of Naphthalimide-Terthiophene Derivatives: Implementation in Organic Field-Effect Transistors
作者:Rocío Ponce Ortiz、Helena Herrera、María J. Mancheño、Carlos Seoane、José L. Segura、Paula Mayorga Burrezo、Juan Casado、J. Teodomiro López Navarrete、Antonio Facchetti、Tobin J. Marks
DOI:10.1002/chem.201301489
日期:2013.9.9
A new family of naphthalimide‐fused thienopyrazine derivatives for ambipolar charge transport in organic field‐effect transistors is presented. Their electronic and molecular structures were elucidated through optical and vibrational spectroscopy aided by DFT calculations. The results indicate that these compounds have completely planar molecular skeletons which promote good film crystallinity and