乙基-二甲基-十八烷基溴化铵 | 111-98-8

• 分子结构分类: 有机化合物 - 有机氮化合物
• 中文名称: 乙基-二甲基-十八烷基溴化铵
• 中文别名: 十八烷基二甲基乙基溴化铵
• 英文名称: octadecyl-dimethyl-ethyl-ammonium bromide
• 英文别名: octadecanyldimethylethylammonium bromide；stearyl-dimethylethyl-ammonium bromide；stearylethyldimethylammonium bromide；N-Ethyl-N,N-dimethyl stearyl ammonium bromide；ethyl-dimethyl-octadecylazanium;bromide
• CAS: 111-98-8
• 化学式: Br*C₂₂H₄₈N
• 分子量: 406.534
• InChiKey: WSPPHMXAIHWZAH-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  4.35
• 重原子数：
  24
• 可旋转键数：
  18
• 环数：
  0.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  1

安全信息

• 海关编码：
  2923900090

反应信息

• 作为产物：
  描述：

  溴乙烷 、 十六烷基二甲基叔胺 、 十八烷基二甲基叔胺 、 N,N-dimethyl-(12S,13R)-epoxy-cis-9-octadecenyl amine 、 Z-N,N-二甲基-9-十八烯胺 以 乙醇 为溶剂， 反应 28.0h， 生成 N-乙基-N,N-二甲基-9-十八碳烯-1-铵溴化物 、 乙基-二甲基-十八烷基溴化铵 、 N,N,N-ethyl-dimethyl-(12S,13R)-epoxy-cis-9-octadecenyl ammonium bromide 、 十六烷基二甲基乙基溴化铵
  参考文献：
  名称：

  Vernonia油：转换为包括N，N-二甲基-（12S，13R）-环氧-顺式-9-十八碳烯基胺的叔胺混合物

  摘要：

  Galnensis的Vernonia galamensis是在热带非洲发现的一种潜在的新型工业油料作物。它是从植物的种子中提取的天然环氧化油，称为氧化藜芦油（VO）的来源。在这项研究中，VO用作合成胺混合物的原料，主要产物胺为N，N-二甲基-（12 S，13 R）-环氧-顺式-9-十八碳烯基胺。通过使用甲醇钠的碱催化甲醇分解法将VO酯交换，生成VO甲酯（VOME）。在回流条件下，以二甲胺为试剂和溶剂对VOME进行氨解，得到叔酰胺，其中N，N-二甲基（12 S，13 R）-环氧-顺式-9-十八碳烯酰胺为主要产物。然后在回流条件下用氢化锂铝在乙醚中对该混合物进行金属氢化物还原，以获得所需的胺混合物，包括N，N-二甲基-（12 S，13 R）-环氧-顺式-9-十八碳烯基胺。电子冲击质谱法用于表征胺的混合物。此外，质子NMR，13 C NMR和FTIR用于表征N，N-二甲基-（12 S，13 R）

  DOI：

  10.1007/s11746-011-1808-x

文献信息

• Thickened aqueous cleaning compositions
  申请人：Akzo Nobel N.V.

  公开号：EP0265979A2

  公开（公告）日：1988-05-04

  The invention relates to an aqueous composition incorporating quaternary ammonium salt or amine oxide surfactant and cumene sulphonate, xylene sul­phonate, toluene sulphonate or mixtures thereof and displaying pronounced shear thinning behaviour, i.e., exhibiting high viscosities at low rates of shear and intended to be applied to non-horizontal structural surfaces. These compositions comprise: a. from 0.1% to 10% by weight of a surfactant selected from the group con­sisting of quaternary ammonium compounds and tertiary amine oxides, b. from 0.01% to 3% by weight of an organic anionic sulphonate selected from the group consisting of cumene sulphonate, xylene sulphonate, and toluene sulphonate, in their acid or salt form, and mixtures thereof, and c. water, wherein optionally one or more cleaning, deesinfecting and/or odourizing agents may be dissolved or dispersed. Acid-containing compositions are preferred and more particularly those con­taining 1-10% by weight of citric acid or hydrochloric acid. The invention also relates to thickening compositions, containing above-­mentioned nitrogen containing surfactant and the sulphonate and to processes of cleaning non-horizontal surfaces.

  本发明涉及一种水性组合物，其中含有季铵盐或氧化胺表面活性剂和积烯磺酸盐、二甲苯磺酸盐、甲苯磺酸盐或其混合物，并具有明显的剪切稀化特性，即在低剪切速率下表现出高粘度，可用于非水平结构表面。 这些组合物包括 a. 0.1%至 10%（按重量计）的表面活性剂，选自季铵化合物和氧化叔胺组、 b. 0.01%至 3%（按重量计）的有机阴离子磺酸盐，选自由其酸或盐形式的积 苯磺酸盐、二甲苯磺酸盐和甲苯磺酸盐及其混合物组成的组，以及 c. 水，其中可选择性地溶解或分散一种或多种清洁剂、除菌剂和/或除臭剂。 含酸的组合物是首选，尤其是含有 1-10%（重量）柠檬酸或盐酸的组合物。本发明还涉及含有上述含氮表面活性剂和磺酸盐的增稠组合物，以及清洁非水平表面的工艺。
• Linear viscoelastic aqueous liquid automatic dishwasher detergent composition
  申请人：Colgate-Palmolive Company

  公开号：EP0517312A1

  公开（公告）日：1992-12-09

  Automatic dishwasher detergent composition is formulated as a linear viscoelastic, pseudoplastic, gel-like aqueous product of exceptionally good physical stability, low bottle residue, low cup leakage, and improved cleaning performance, Linear viscoelasticity and pseudoplastic behavior is attributed by incorporation of cross-linked high molecular weight polyacrylic acid type thickener. Potassium to sodium weight ratios of at least 1/1 minimize amount of undissolved solid particles to further contribute to stability and pourability. Control of incorporated air bubbles functions to provide the product with a bulk density of 1.26 to 1.40 g/cc which roughly corresponds to the density of the liquid phase. Stearic acid or other fatty acid or salt further improve physical stability.

  自动洗碗机洗涤剂组合物被配制成线性粘弹性、假塑性、凝胶状的水性产品，具有极佳的物理稳定性、低瓶内残留物、低杯漏和更高的清洁性能，其线性粘弹性和假塑性是通过加入交联高分子量聚丙烯酸类增稠剂实现的。钾与钠的重量比至少为 1/1，最大限度地减少了未溶解固体颗粒的数量，从而进一步提高了稳定性和浇注性。控制气泡的加入可使产品的体积密度达到 1.26 至 1.40 g/cc，这与液相的密度基本一致。硬脂酸或其他脂肪酸或盐可进一步提高物理稳定性。
• ACIDIC HARD SURFACE CLEANING AND DISINFECTING COMPOSITIONS WHICH INCLUDE SILICONE QUARTERNARY AMMONIUM SALTS
  申请人：——

  公开号：US20020002125A1

  公开（公告）日：2002-01-03

  Acidic, hard surface cleaning and disinfecting compositions include a film-forming, organosilicone quaternary ammonium compound providing a protective layer for water and stain repellency

  酸性硬表面清洁和消毒组合物包括一种成膜有机硅季铵盐化合物，可提供防水防污保护层
• Thickened hard surface cleaner
  申请人：Ecolab Inc.

  公开号：US20020082178A1

  公开（公告）日：2002-06-27

  A low viscosity aqueous cleaning composition provides increasing viscosity upon dilution which provides a high viscosity diluted cleaning composition having solvents compatible with the rod micelle thickener and the cleaning system that clings for an extended period of time in a thickened form containing cleaning system ingredients that can penetrate and remove hard baked-on soils on vertical surfaces in cleaning units. The composition contains active cleaning ingredients (acid, alkaline and enzyme) that, in combination with thickening systems, provide the useful properties. The thickened materials can be applied on cold or hot surfaces and can successfully penetrate, soften and remove baked-on food soil on a variety of surfaces including oven walls, doors and grills, baking dishes, utensils, etc. The material is applied in the form of a thick diluted liquid spray or hot foam directly to the hardened soil, is permitted to penetrate the soil, resulting softened soils are then easily removed by hot or cold water rinse or by mechanical action such as scrubbing, scraping or wiping.

  低粘度的水性清洁组合物在稀释后粘度会增加，从而提供高粘度的稀释清洁组合物，该组合物的溶剂与棒状胶束增稠剂和清洁系统相容，可长时间以增稠的形式附着，其中含有的清洁系统成分可渗透并清除清洁装置中垂直表面上坚硬的烘烤污垢。该组合物含有活性清洁成分（酸、碱和酶），与增稠系统结合可提供有用的特性。增稠材料可用于冷或热的表面，并能成功渗透、软化和清除各种表面上的烘烤食物污垢，包括烤箱壁、门和烤架、烤盘、器皿等。这种材料以浓稠稀释液喷雾或热泡沫的形式直接喷洒在坚硬的污垢上，使其渗透到污垢中，然后用热水或冷水冲洗，或用擦洗、刮擦或抹布等机械方法轻松去除软化的污垢。
• Antimicrobially-treated fabrics
  申请人：Kimberly-Clark Worldwide, Inc.

  公开号：US20030127207A1

  公开（公告）日：2003-07-10

  A method for forming an antimicrobially-treated fabric is provided. The method includes forming a solution from a liquid and an antimicrobial agent, such as 3-(trimethoxysilyl)propyloctadecyldimethyl ammonium chloride. In one embodiment, a cellulosic fibrous material is combined with the solution while in the pulper to form a liquid suspension such that the antimicrobial agent becomes substantive to the cellulosic fibrous material. A web is formed from the antimicrobially-treated cellulosic fibrous material such that substantially all of the cellulosic fibrous material present within the web is derived from the antimicrobially-treated cellulosic fibrous material. In one embodiment, the web of antimicrobially-treated fibrous material is also hydraulically entangled with a nonwoven substrate. In some embodiments, when dried, the antimicrobial agent forms a covalent bond with the cellulosic fibrous material.

  提供了一种形成抗菌处理织物的方法。该方法包括用液体和抗菌剂（如 3-(三甲氧基硅基)丙基十八烷基二甲基氯化铵）形成溶液。在一个实施方案中，纤维素纤维材料在碎浆机中与溶液结合，形成液体悬浮液，使抗菌剂与纤维素纤维材料紧密结合。用抗菌处理过的纤维素纤维材料形成纤维网，使纤维网中的纤维素纤维材料基本上全部来自抗菌处理过的纤维素纤维材料。在一个实施方案中，抗菌处理纤维材料网还与无纺基材水力缠结。在某些实施方案中，抗菌剂在干燥后会与纤维素纤维材料形成共价键。