3,3-bis[2-(p-pyrrolidinophenyl)-2-(p-methoxyphenyl)ethenyl]-4,5,6,7-tetrachlorophthalide

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: 3,3-bis[2-(p-pyrrolidinophenyl)-2-(p-methoxyphenyl)ethenyl]-4,5,6,7-tetrachlorophthalide
• 英文别名: 4,5,6,7-tetrachloro-3,3-bis[(Z)-2-(4-methoxyphenyl)-2-(4-pyrrolidin-1-ylphenyl)ethenyl]-2-benzofuran-1-one
• 化学式: C₄₆H₄₀Cl₄N₂O₄
• 分子量: 826.647
• InChiKey: ZZDIQZGOGADMNT-KJLMGFARSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  13.3
• 重原子数：
  56
• 可旋转键数：
  10
• 环数：
  8.0
• sp3杂化的碳原子比例：
  0.24
• 拓扑面积：
  51.2
• 氢给体数：
  0
• 氢受体数：
  6

反应信息

• 作为产物：
  描述：

  1-(4-methoxyphenyl)-1-(4-pyrrolidinophenyl)ethylene 、 四氯苯二甲酸酐 、 邻二氯苯 在 sodium hydroxide 、 乙酸酐 作用下， 以 水 、 甲苯 为溶剂， 生成 3,3-bis[2-(p-pyrrolidinophenyl)-2-(p-methoxyphenyl)ethenyl]-4,5,6,7-tetrachlorophthalide
  参考文献：
  名称：

  Divinyl compounds and chromogenic recording-material prepared by using

  摘要：

  本文揭示了一种新颖的二乙烯化合物，其化学式表示为(I)：##STR1##以及利用这些二乙烯化合物制备的记录材料。这种二乙烯化合物本身几乎无色，在大气中极其稳定，并通过显影剂迅速变为深灰色。由这种二乙烯化合物产生的彩色图像在耐光性和耐湿性方面表现出色，并且可通过光学文字阅读设备或条形码阅读设备读取开发的文字。

  公开号：

  US04808567A1

文献信息

• A phtalide compound and a near infrared absorber and a recording material each comprising the same compound
  申请人：YAMAMOTO CHEMICALS, INC.

  公开号：EP0664292A1

  公开（公告）日：1995-07-26

  A phthalide compound of general formula (I) and a near infrared absorber and a recording material each utilizing the phthalide compound are disclosed. wherein ring A represents a substituent group of the following formula    where R₁ represents hydrogen, alkyl, alkoxy or halogen; n represents an integer of 1-3; ring B represents a defined aromatic ring; R₂ represents alkyl or aryl; R₃ represents alkyl; R₄ and R₅ independently represent alkyl or unsubstituted or substituted phenyl; R₆ represents hydrogen, alkyl or alkoxy. The near infrared absorber and the recorded image on the recording material absorb strongly the near infrared region with no appreciable absorption in the visible region of the spectrum. The near infrared absorber is colorless or pale in color and yet highly capable of absorbing near infrared radiation. The recorded image on the recording material can hardly be read with the eye but can be read with the OCR. Moreover, the effect on the developed shade of any concomitant color former in a recording material is minimal.

  本发明公开了通式（I）的邻苯二甲酸盐化合物以及利用该邻苯二甲酸盐化合物的近红外吸收剂和记录材料。 其中环 A 代表下式的取代基团 其中 R₁ 代表氢、烷基、烷氧基或卤素；n 代表 1-3 的整数；环 B 代表确定的芳环；R₂ 代表烷基或芳基；R₃ 代表烷基；R₄ 和 R₅ 独立地代表烷基或未取代或取代的苯基；R₆ 代表氢、烷基或烷氧基。 近红外吸收体和记录材料上记录的图像对近红外区域有强烈的吸收，而对光谱的可见光区域没有明显的吸收。近红外吸收体是无色或浅色的，但吸收近红外辐射的能力很强。记录材料上记录的图像几乎无法用肉眼读取，但可以用 OCR 读取。此外，记录材料中的任何伴色前者对显影色调的影响微乎其微。
• LITHOGRAPHY ORIGINAL PLATE, PLATEMAKING METHOD FOR LITHOGRAPHY PLATE, ORGANIC POLYMER PARTICLES, AND PHOTOSENSITIVE RESIN COMPOSITION
  申请人：FUJIFILM Corporation

  公开号：EP3640039A1

  公开（公告）日：2020-04-22

  Provided are a lithographic printing plate precursor having an image-recording layer on a hydrophilic support, in which the image-recording layer includes an organic polymer particle, and the organic polymer particle is a reaction product obtained by at least reacting an aromatic polyvalent isocyanate compound having a structure represented by Formula PO and water, a method for making a lithographic printing plate having excellent printing resistance in the case of using an ultraviolet-curable ink in printing, a new organic polymer particle, and a resin composition including the organic polymer particle.

  本发明提供了一种在亲水性支持物上具有图像记录层的平版印刷板前体，其中图像记录层包括有机聚合物颗粒，而有机聚合物颗粒是至少将具有式 PO 所表示的结构的芳香族多价异氰酸酯化合物与水反应而得到的反应产物；一种在印刷中使用紫外线固化油墨的情况下具有优异耐印刷性的平版印刷板的制造方法；一种新的有机聚合物颗粒；以及一种包括有机聚合物颗粒的树脂组合物。
• THERMOSENSITIVE RECORDING MATERIAL AND LAMINATE
  申请人：Mitsubishi Chemical Corporation

  公开号：EP3666541A1

  公开（公告）日：2020-06-17

  An object is to provide a thermosensitive recording material and a laminate which are excellent in color development sensitivity and favorable in storage characteristics such as heat resistance, plasticizer resistance, moisture resistance, oil resistance, and grease resistance. A thermosensitive recording material in which a thermosensitive recording layer is provided on a support, wherein the thermosensitive recording layer contains a specific diphenylsulfone compound and an analog compound thereof at a specific ratio. A laminate in which a thermosensitive recording layer is provided on a support, wherein the thermosensitive recording layer contains a specific diphenylsulfone compound and an analog compound thereof at a specific ratio.

  目的是提供一种热敏记录材料和层压板，它们具有优异的显色灵敏度和良好的储存特性，如耐热性、耐增塑剂性、耐潮湿性、耐油性和耐油脂性。一种热敏记录材料，其热敏记录层设置在支持物上，其中热敏记录层按特定比例含有特定的二苯砜化合物及其类似化合物。一种层压材料，其热敏记录层设置在支架上，其中热敏记录层按特定比例含有特定的二苯砜化合物及其类似化合物。
• PLANOGRAPHIC PRINTING ORIGINAL PLATE, METHOD FOR PRODUCING PLANOGRAPHIC PRINTING PLATE, PLANOGRAPHIC PRINTING METHOD AND CURABLE COMPOSITION
  申请人：FUJIFILM Corporation

  公开号：EP3845394A1

  公开（公告）日：2021-07-07

  Provided are a planographic printing plate precursor including a support, and an image recording layer in this order, in which the image recording layer contains polymer particles containing an addition polymerization type resin, and the addition polymerization type resin contains a polymerizable group and a hydrophilic structure; a method of producing a planographic printing plate using the planographic printing plate precursor; a planographic printing method using the planographic printing plate precursor; and a curable composition containing the polymer particles.

  本发明提供了一种平版印刷板前体，依次包括支撑体和图像记录层，其中图像记录层含有含有加成聚合型树脂的聚合物颗粒，加成聚合型树脂含有可聚合基团和亲水结构；一种使用该平版印刷板前体生产平版印刷板的方法；一种使用该平版印刷板前体的平版印刷方法；以及一种含有该聚合物颗粒的固化组合物。
• LITHOGRAPHIC PRINTING PLATE PRECURSOR, METHOD FOR MANUFACTURING LITHOGRAPHIC PRINTING PLATE, AND LITHOGRAPHIC PRINTING METHOD
  申请人：FUJIFILM Corporation

  公开号：EP3900942A1

  公开（公告）日：2021-10-27

  Provided are a planographic printing plate precursor including a support and an image recording layer on the support, in which the image recording layer contains an organic particle containing a resin that has a constitutional unit A having a cation moiety and a constitutional unit B having an anion moiety; and a method of preparing a planographic printing plate using the planographic printing plate precursor.

  本发明提供了一种平版印刷板前体，包括支撑物和支撑物上的图像记录层，其中图像记录层包含一种有机颗粒，该有机颗粒含有一种树脂，该树脂具有具有阳离子分子的构型单元 A 和具有阴离子分子的构型单元 B；以及一种使用该平版印刷板前体制备平版印刷板的方法。