Nine new compounds containing PS ligands of the types [P(OtBu)S3]2-, [ArP(StBu)S2]- and [ArP(OtBu)S2]- are reported (Ar = 4-anisyl). It is demonstrated that the topology of alkali metal ion and ligand composition influence the structure of supramolecular arrangements.
报道了九种新的化合物,它们包含类型为[P(OtBu)S3] 2-,[ArP(StBu)S2]-和[ArP(OtBu)S2]-的PS
配体(Ar = 4-茴香基)。结果表明,碱
金属离子的拓扑结构和
配体组成会影响超分子排列的结构。