乙氧基-乙基-苯氧基-膦 | 100134-00-7

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 中文名称: 乙氧基-乙基-苯氧基-膦
• 英文名称: ethoxy-ethyl-phenoxy-phosphine
• 英文别名: Aethoxy-aethyl-phenoxy-phosphin；Ethoxy-ethyl-phenoxyphosphane
• CAS: 100134-00-7
• 化学式: C₁₀H₁₅O₂P
• 分子量: 198.202
• InChiKey: IUDHDWAHHDHSCA-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  2.6
• 重原子数：
  13
• 可旋转键数：
  5
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.4
• 拓扑面积：
  18.5
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为产物：
  描述：

  P-乙基-亚膦酸二乙酯 、 苯酚 在 sodium 作用下， 生成 乙氧基-乙基-苯氧基-膦
  参考文献：
  名称：

  Organic Phosphorus Compounds. IV.¹ A Study of the Transesterification of Dialkyl Alkylphosphonites

  摘要：

  DOI：

  10.1021/ja01555a012

文献信息

• [EN] PROCESS FOR PREPARATION OF ARYL PHOSPHOROUS COMPOUNDS<br/>[FR] PROCÉDÉ DE PRÉPARATION DE COMPOSÉS ARYL PHOSPHORÉS
  申请人：COUNCIL SCIENT IND RES

  公开号：WO2014024212A1

  公开（公告）日：2014-02-13

  The present invention relates to cost effective, transition-metal-free one pot process for the preparation of aryl phosphorous compounds of formula (I). Particularly, the present invention provides a process for C-P bond formation. In particular, the invention relates to mild fluoride induced generation of aryne species in situ which allows P-C bond formation to obtain aryl phosphorous compounds of formula (I) under mild condition.

  本发明涉及一种成本效益高、无过渡金属的一锅法制备芳基磷化合物（I）的过程。特别地，本发明提供了一种C-P键形成的过程。具体来说，该发明涉及在温和条件下通过氟化物诱导生成芳基炔烃中间体，从而实现P-C键形成，获得芳基磷化合物（I）。
• PROCESS FOR PREPARATION OF ARYL PHOSPHOROUS COMPOUNDS
  申请人：Council of Scientific & Industrial Research

  公开号：US20150210725A1

  公开（公告）日：2015-07-30

  The present invention relates to cost effective, transition-metal-free one pot process for the preparation of aryl phosphorous compounds of formula (I). Particularly, the present invention provides a process for C—P bond formation. In particular, the invention relates to mild fluoride induced generation of aryne species in situ which allows P—C bond formation to obtain aryl phosphorous compounds of formula (I) under mild condition.

  本发明涉及一种经济有效、无过渡金属的一锅法制备式芳基磷化合物的方法（I）。特别地，本发明提供了一种C-P键形成的方法。具体地，该发明涉及温和氟化物诱导下原位生成芳基亚烯物种，从而允许P-C键形成，以在温和条件下获得式（I）的芳基磷化合物。
• Phosphorus compounds that delay the metathesis polymerization of cycloolefins
  申请人：HERCULES INCORPORATED

  公开号：EP0376198A2

  公开（公告）日：1990-07-04

  Disclosed is a process for delaying the metathesis polymerization of strained ring non-conjugated, cycloolefins in which the cycloolefin, a metathesis polymerization catalyst, an activator selected from the group consisting of alkylaluminum, alkylzinc and alkyltin compounds, and a reaction rate moderator are charged into a mold, the reaction rate moderator being a phosphorus-containing compound that includes various aryl phosphates, aliphatic phosphates, aliphatic phosphites, aryl phosphites, aryl phosphines and alkyl phosphines.

  本发明公开了一种用于延迟应变环非共轭环烯烃的偏聚聚合反应的工艺，在该工艺中，环烯烃、偏聚聚合催化剂、从烷基铝、烷基锌和烷基锡化合物组成的组中选出的活化剂以及反应速率调节剂被注入模具中，反应速率调节剂是一种含磷化合物，包括各种芳基膦酸盐、脂肪族膦酸盐、脂肪族亚磷酸盐、芳基亚磷酸盐、芳基膦和烷基膦。
• RESIN COMPOSITION
  申请人：Teijin Chemicals, Ltd.

  公开号：EP1038920A1

  公开（公告）日：2000-09-27

  A resin composition comprising 100 parts by weight of a resin component selected from (a) an aromatic polycarbonate resin (A-1 component) obtained by melt polymerization and, when measured for fluorescent spectrum at an exciting wavelength of 320 nm, having a relative fluorescence intensity of 4x10-3 or less at 465 nm relative to a standard substance, (b) a resin mixture of said A-1 component and a styrene-based resin (A-2 component), and (c) a resin mixture of said A-1 component and an aromatic polyester resin (A-3 component), and 5 to 200 parts by weight of a reinforcing filler. This resin composition gives a molded article superior in wet heat fatigue and various physical properties.

  (b) 上述 A-1 组分和苯乙烯基树脂（A-2 组分）的树脂混合物，以及 (c) 上述 A-1 组分和芳香族聚酯树脂（A-3 组分）的树脂混合物。这种树脂组合物可使模塑制品具有更佳的湿热疲劳性能和各种物理性能。
• PHOSPHINIC ACID AMIDES AS MATRIX METALLOPROTEASE INHIBITORS
  申请人：THE PROCTER & GAMBLE COMPANY

  公开号：EP0925303B1

  公开（公告）日：2002-10-23