(4-pyridylthio)acetic acid

• 分子结构分类: 有机化合物 - 有机硫化合物 - 硫醚类
• 英文名称: (4-pyridylthio)acetic acid
• 英文别名: Pyridin-4-ylsulfanylformic acid；pyridin-4-ylsulfanylformic acid
• 化学式: C₆H₅NO₂S
• 分子量: 155.177
• InChiKey: UANCAPWAKICZEY-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  1.2
• 重原子数：
  10
• 可旋转键数：
  2
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  75.5
• 氢给体数：
  1
• 氢受体数：
  4

反应信息

• 作为反应物：
  描述：

  硫氰酸铵 、 (4-pyridylthio)acetic acid 、 copper diacetate 在 NaOH 作用下， 以 水 为溶剂， 以35%的产率得到Cu3 bis(4-pyridylthiolate)(CN)
  参考文献：
  名称：

  A Twelve-Connected Cu₆S₄ Cluster-Based Coordination Polymer

  摘要：

  Hydrothermal reaction of Cu(MeCO2)2, (4-pyridylthio)acetic acid, and NH4SCN resulted in a metal-organic framework [Cu3(4-pyridinethiolate)2(CN)] which has twelve-connected face-centered cubic topology with Cu6S4 clusters as nodes.

  DOI：

  10.1021/ja050284t

文献信息

• FUNCTIONALIZED POLYMERS AND METHODS FOR THEIR MANUFACTURE
  申请人：Luo Steven

  公开号：US20110077325A1

  公开（公告）日：2011-03-31

  A method for preparing a functionalized polymer, the method comprising the steps of (i) polymerizing monomer with a coordination catalyst to form a reactive polymer; and (ii) reacting the reactive polymer with a carboxylic or thiocarboxylic ester containing a silylated amino group.

  一种制备功能化聚合物的方法，包括以下步骤：(i)使用配位催化剂聚合单体，形成反应性聚合物；(ii)将反应性聚合物与含有硅烷基氨基的羧酸酯或硫代羧酸酯反应。
• Polymers Functionalized With A Carboxylic Or Thiocarboxylic Ester Containing A Silylated Amino Group
  申请人：Luo Steven

  公开号：US20140018500A1

  公开（公告）日：2014-01-16

  A method for preparing a functionalized polymer, the method comprising the steps of: (i) polymerizing monomer with an anionic initiator to form a reactive polymer; and (ii) reacting the reactive polymer with a carboxylic or thiocarboxylic ester containing a silylated amino group, where the silylated amino group is directly attached to a moiety selected from the group consisting of acyclic moieties, heterocyclic moieties, and nonaromatic cyclic moieties.

  一种制备功能化聚合物的方法，该方法包括以下步骤：（i）使用阴离子引发剂聚合单体，形成反应性聚合物；（ii）将反应性聚合物与含有硅烷化氨基的羧酸酯或硫代羧酸酯反应，其中硅烷化氨基直接连接到选自无环基团、杂环基团和非芳香环基团的基团之一。
• POLYMERS FUNCTIONALIZED WITH A CARBOXYLIC OR THIOCARBOXYLIC ESTER CONTAINING A SILYLATED AMINO GROUP
  申请人：Bridgestone Corporation

  公开号：EP2699606A2

  公开（公告）日：2014-02-26
• US8895670B2
  申请人：——

  公开号：US8895670B2

  公开（公告）日：2014-11-25
• [EN] FUNCTIONALIZED POLYMERS AND METHODS FOR THEIR MANUFACTURE<br/>[FR] POLYMÈRES FONCTIONNALISÉS ET LEURS PROCÉDÉS DE FABRICATION
  申请人：BRIDGESTONE CORP

  公开号：WO2011041534A1

  公开（公告）日：2011-04-07

  A method for preparing a functionalized polymer, the method comprising the steps of (i) polymerizing monomer with a coordination catalyst to form a reactive polymer; and (ii) reacting the reactive polymer with a carboxylic or thiocarboxylic ester containing a silylated amino group.