3,5-di-tert-butylphenyl methanesulfonate

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: 3,5-di-tert-butylphenyl methanesulfonate
• 英文别名: 3,5-Di-tert-butylphenyl methanesulfonate；(3,5-ditert-butylphenyl) methanesulfonate
• 化学式: C₁₅H₂₄O₃S
• 分子量: 284.42
• InChiKey: OBVUPOOOBPENIV-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  4.8
• 重原子数：
  19
• 可旋转键数：
  4
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.6
• 拓扑面积：
  51.8
• 氢给体数：
  0
• 氢受体数：
  3

反应信息

• 作为反应物：
  描述：

  3,5-di-tert-butylphenyl methanesulfonate 、 氰化锌 在 三苯基膦树脂 palladium diacetate 作用下， 以 四氢呋喃 为溶剂， 反应 2.0h， 以93%的产率得到3,5-bis(t-butyl)benzonitrile
  参考文献：
  名称：

  Application of Polymer‐Supported Triphenylphosphine and Microwave Irradiation to the Palladium‐Catalyzed Cyanation of Aryl Triflates

  摘要：

  DOI：

  10.1080/00397910601039044
• 作为产物：
  描述：

  3,5-二叔丁基苯酚 、 甲基磺酰氯 在 三乙胺 作用下， 以 甲苯 为溶剂， 反应 3.17h， 以98%的产率得到3,5-di-tert-butylphenyl methanesulfonate
  参考文献：
  名称：

  EP2133327

  摘要：

  公开号：

文献信息

• METHOD FOR PRODUCING AROMATIC COMPOUND
  申请人：Abe Koji

  公开号：US20110230694A1

  公开（公告）日：2011-09-22

  The present invention is a method for producing an aromatic compound by substituting the sulfonic acid group in a sulfonic acid aromatic-ester with a hydrogen atom in the presence of a platinum group metal catalyst, wherein an alkali metal carboxylate and/or an ammonium formate are made to coexist in the system. According to the present invention, an aromatic compound where the sulfonic acid group in a sulfonic acid aromatic-ester is substituted with a hydrogen atom, can be produced efficiently with good operability without using metal magnesium.

  本发明是一种通过在存在铂族金属催化剂的情况下，用氢原子替代磺酸芳香酯中的磺酸基团来生产芳香化合物的方法，其中在系统中使碱金属羧酸盐和/或铵甲酸盐共存。根据本发明，在不使用金属镁的情况下，可以高效地生产磺酸芳香酯中的磺酸基团被氢原子替代的芳香化合物，并具有良好的操作性。
• tert-BUTYLPHENYL SULFONATE COMPOUND, NONAQUEOUS ELECTROLYTE SOLUTION FOR LITHIUM SECONDARY BATTERY USING THE SAME, AND LITHIUM SECONDARY BATTERY USING THE SAME
  申请人：Abe Koji

  公开号：US20100055576A1

  公开（公告）日：2010-03-04

  The disclosed subject matter relate to a di-tert-butylphenyl alkylsulfonate compound, tert-butylphenyl alkylsulfonate compound, di-tert-butylphenyl arylsulfonate compound or tert-butylphenyl arylsulfonate compound useful as an intermediate raw material of a pharmaceutical, agricultural chemical, electronic material or polymer material and the like, or as a battery material, and also provides a nonaqueous electrolytic solution for a lithium secondary battery having superior cycle performance and other battery properties through the use thereof, and a lithium secondary battery. The disclosed embodiments further relate to a nonaqueous electrolytic solution for use as in a lithium secondary battery containing, in a nonaqueous electrolytic solution in which an electrolyte salt is dissolved in a nonaqueous solvent, 0.01 to 10% by weight of a di-tert-butylphenyl alkylsulfonate compound, tert-butylphenyl alkylsulfonate compound, di-tert-butylphenyl arylsulfonate compound or tert-butylphenyl arylsulfonate compound, and to a lithium secondary battery and a compound.

  所披露的主题涉及一种二叔丁基苯基烷基磺酸酯化合物、叔丁基苯基烷基磺酸酯化合物、二叔丁基苯基芳基磺酸酯化合物或叔丁基苯基芳基磺酸酯化合物，作为制药、农业化学品、电子材料或聚合物材料等的中间原料，或作为电池材料，并且提供了一种非水电解质溶液，通过使用它具有卓越的循环性能和其他电池性能的锂二次电池，以及一种锂二次电池。所披露的实施例还涉及一种用作锂二次电池中的非水电解质溶液，其中电解质盐溶解在非水溶剂中，0.01至10重量％的二叔丁基苯基烷基磺酸酯化合物、叔丁基苯基烷基磺酸酯化合物、二叔丁基苯基芳基磺酸酯化合物或叔丁基苯基芳基磺酸酯化合物，并且涉及一种锂二次电池和一种化合物。
• TERT-BUTYLPHENYL SULFONATE COMPOUND, NONAQUEOUS ELECTROLYTE SOLUTION FOR LITHIUM SECONDARY BATTERY USING THE SAME, AND LITHIUM SECONDARY BATTERY USING THE SAME
  申请人：UBE INDUSTRIES, LTD.

  公开号：US20140011097A1

  公开（公告）日：2014-01-09

  The disclosed subject matter relate to a di-tert-butylphenyl alkylsulfonate compound, tertbutylphenyl alkylsulfonate compound, di-tert-butylphenyl arylsulfonate compound or tertbutylphenyl arylsulfonate compound useful as an intermediate raw material of a pharmaceutical, agricultural chemical, electronic material or polymer material and the like, or as a battery material, and also provides a nonaqueous electrolytic solution for a lithium secondary battery having superior cycle performance and other battery properties through the use thereof, and a lithium secondary battery. The disclosed embodiments further relate to a nonaqueous electrolytic solution for use as in a lithium secondary battery containing, in a nonaqueous electrolytic solution in which an electrolyte salt is dissolved in a nonaqueous solvent, 0.01 to 10% by weight of a di-tert-butylphenyl alkylsulfonate compound, tert-butylphenyl alkylsulfonate compound, ditert-butylphenyl arylsulfonate compound or tert-butylphenyl arylsulfonate compound, and to a lithium secondary battery and a compound.

  公开的主题涉及一种二叔丁基苯基烷基磺酸酯化合物，叔丁基苯基烷基磺酸酯化合物，二叔丁基苯基芳基磺酸酯化合物或叔丁基苯基芳基磺酸酯化合物，可用作制药、农业化学品、电子材料或聚合物材料等的中间原料，或作为电池材料，并且通过使用它们提供了一种具有优异循环性能和其他电池性能的锂二次电池的非水电解质溶液，以及锂二次电池。所公开的实施例还涉及用作锂二次电池中的非水电解质溶液的一种非水电解质溶液，其中在非水溶剂中溶解电解质盐，含有0.01至10重量％的二叔丁基苯基烷基磺酸酯化合物，叔丁基苯基烷基磺酸酯化合物，二叔丁基苯基芳基磺酸酯化合物或叔丁基苯基芳基磺酸酯化合物，以及锂二次电池和化合物。
• Tert-butylphenyl sulfonate compound, nonaqueous electrolyte solution for lithium secondary battery using the same, and lithium secondary battery using the same
  申请人：Abe Koji

  公开号：US08546599B2

  公开（公告）日：2013-10-01

  The disclosed subject matter relate to a di-tert-butylphenyl alkylsulfonate compound, tert-butylphenyl alkylsulfonate compound, di-tert-butylphenyl arylsulfonate compound or tert-butylphenyl arylsulfonate compound useful as an intermediate raw material of a pharmaceutical, agricultural chemical, electronic material or polymer material and the like, or as a battery material, and also provides a nonaqueous electrolytic solution for a lithium secondary battery having superior cycle performance and other battery properties through the use thereof, and a lithium secondary battery. The disclosed embodiments further relate to a nonaqueous electrolytic solution for use as in a lithium secondary battery containing, in a nonaqueous electrolytic solution in which an electrolyte salt is dissolved in a nonaqueous solvent, 0.01 to 10% by weight of a di-tert-butylphenyl alkylsulfonate compound, tert-butylphenyl alkylsulfonate compound, di-tert-butylphenyl arylsulfonate compound or tert-butylphenyl arylsulfonate compound, and to a lithium secondary battery and a compound.

  公开的主题涉及一种二叔丁基苯基烷基磺酸酯化合物、叔丁基苯基烷基磺酸酯化合物、二叔丁基苯基芳基磺酸酯化合物或叔丁基苯基芳基磺酸酯化合物，可用作制药、农药、电子材料或聚合物材料等中间原料，或用作电池材料，并且通过使用它们提供了一种具有优异循环性能和其他电池性能的锂二次电池的非水电解质溶液，以及一种锂二次电池。公开实施例进一步涉及一种非水电解质溶液，用于锂二次电池中，其中在非水电解质溶液中溶解了电解质盐的非水溶剂中含有0.01至10重量％的二叔丁基苯基烷基磺酸酯化合物、叔丁基苯基烷基磺酸酯化合物、二叔丁基苯基芳基磺酸酯化合物或叔丁基苯基芳基磺酸酯化合物，以及一种锂二次电池和化合物。
• US8283508B2
  申请人：——

  公开号：US8283508B2

  公开（公告）日：2012-10-09