1,3-dihydroxy-5-vinyloxybenzene

• 分子结构分类: 有机化合物 - 苯类化合物 - 酚类
• 英文名称: 1,3-dihydroxy-5-vinyloxybenzene
• 英文别名: 5-ethenoxybenzene-1,3-diol
• 化学式: C₈H₈O₃
• 分子量: 152.15
• InChiKey: PCPXULICWBYAAW-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  1.7
• 重原子数：
  11
• 可旋转键数：
  2
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  49.7
• 氢给体数：
  2
• 氢受体数：
  3

反应信息

• 作为反应物：
  描述：

  、 disodium;carbonate 、 间苯三酚 、 乙酸乙烯酯 、 1,3-dihydroxy-5-vinyloxybenzene 、 1-hydroxy-3,5-bis(vinyloxy)benzene 在 氩 作用下， 以 甲苯 为溶剂， 反应 6.0h， 以1,3,5-tris(vinyloxy)benzene were formed的产率得到1,3,5-tris(ethenyloxy)benzene
  参考文献：
  名称：

  Aromatic vinyl ether compounds

  摘要：

  公式（1）或公式（2）所代表的芳香基乙醚化合物，其中每个R和R'是氢原子或由公式（3）表示的基团，其余变量如规范中所定义，前提是公式（1）中至少有一个pR和公式（2）中至少有一个uR是公式（3）基团。这些芳香基乙醚化合物可用作阳离子聚合的固化剂。

  公开号：

  US20040181098A1
• 作为产物：
  描述：

  乙酸乙烯酯 、 间苯三酚 在 bis(1,5-cyclooctadiene)diiridium(I) dichloride sodium carbonate 作用下， 以 甲苯 为溶剂， 反应 6.0h， 以5%的产率得到1,3-dihydroxy-5-vinyloxybenzene
  参考文献：
  名称：

  Aromatic vinyl ether compounds

  摘要：

  公开号：

  EP1413568B1

文献信息

• AROMATIC VINYL ETHER COMPOUNDS
  申请人：IWAHAMA Takahiro

  公开号：US20090088592A1

  公开（公告）日：2009-04-02

  Aromatic vinyl ether compounds represented by Formula (1) or by Formula (2) wherein each R and R′ is a hydrogen atom or a group represented by Formula (3) and wherein the remaining variables are as defined in the specification, provided that at least one pR in Formula (1) and at least one uR in Formula (2) is a Formula (3) group. These aromatic vinyl ether compounds are useful as, e.g., curing agents for cationic polymerization.

  化合物的芳香基乙醚可以由公式（1）或公式（2）表示，其中每个R和R′是氢原子或由公式（3）表示的基团，其余变量如规范中定义的那样，前提是公式（1）中至少有一个pR和公式（2）中至少有一个uR是公式（3）基团。这些芳香基乙醚化合物可用作阳离子聚合的固化剂。
• Composition and method for preparing linear copolymers of polar and non-polar olefins absent free radical addition polymer
  申请人：Rohm and Haas Company

  公开号：EP1964862A1

  公开（公告）日：2008-09-03

  A polynnerizable composition including a late transition metal complex, a non-polar olefin, a polar olefin, and a free radical scavenger, wherein the polymerizable composition is capable of forming a linear poly[(non-polar olefin)-(polar olefin)] substantially free of free radical addition polymer, is disclosed. A method of copolymerizing a non-polar olefin with a polar olefin, catalyzed by a late transition metal complex in the presence of a free radical scavenger, to produce a linear poly[(non-polar olefin)-(polar olefin)] substantially free of free radical addition polymer is also disclosed.

  本发明公开了一种可聚合组合物，该组合物包括晚过渡金属络合物、非极性烯烃、极性烯烃和自由基清除剂，其中该可聚合组合物能够形成基本上不含自由基加成聚合物的线性聚[（非极性烯烃）-（极性烯烃）]。本发明还公开了一种在游离基清除剂存在下，通过后期过渡金属配合物催化，使非极性烯烃与极性烯烃共聚，从而生成基本上不含游离基加成聚合物的线性聚[（非极性烯烃）-（极性烯烃）]的方法。
• A porous linear polymer composition
  申请人：Rohm and Haas Company

  公开号：EP1964859A1

  公开（公告）日：2008-09-03

  A porous polymer composition including plural linear mixed polarity polymer particles, wherein the particles include a linear poly[(non-polar olefin)-(polar olefin)] and at least one pore, is disclosed, as are those particles further including a catalytic component. A method of forming the plural linear mixed polarity polymer particles is also disclosed. A method of using plural linear mixed polarity polymer particles which include a catalytic component to catalyze polymerization is further disclosed. A porous polymer composition including plural linear non-polar polymer particles and a catalytic component is further disclosed, along with a method of making those linear non-polar polymer particles including the catalytic component and a method of using them to catalyze polymerization.

  本发明公开了一种多孔聚合物组合物，包括多个线性混合极性聚合物颗粒，其中颗粒包括线性聚[（非极性烯烃）-（极性烯烃）]和至少一个孔，这些颗粒还包括催化成分。还公开了一种形成复数线性混合极性聚合物颗粒的方法。还公开了一种使用包含催化成分的复数线性混合极性聚合物颗粒催化聚合的方法。进一步公开了一种包括复数线性非极性聚合物颗粒和催化组分的多孔聚合物组合物，以及制造这些包括催化组分的线性非极性聚合物颗粒的方法和使用它们催化聚合的方法。
• Composition and method for preparing linear copolymers of polar and non-polar olefins free of free radical initiated polymer
  申请人：Rohm and Haas Company

  公开号：EP1964862B1

  公开（公告）日：2010-12-22
• Porous linear polymer composition
  申请人：Acholla Francis V.

  公开号：US20080207789A1

  公开（公告）日：2008-08-28

  A porous polymer composition including plural linear mixed polarity polymer particles, wherein the particles include a linear poly[(non-polar olefin)-(polar olefin)] and at least one pore, is disclosed, as are those particles further including a catalytic component. A method of forming the plural linear mixed polarity polymer particles is also disclosed. A method of using plural linear mixed polarity polymer particles which include a catalytic component to catalyze polymerization is further disclosed. A porous polymer composition including plural linear non-polar polymer particles and a catalytic component is further disclosed, along with a method of making those linear non-polar polymer particles including the catalytic component and a method of using them to catalyze polymerization.