α-naphthyl perfluoroheptanoyl ketone

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: α-naphthyl perfluoroheptanoyl ketone
• 英文别名: 2,2,3,3,4,4,5,5,6,6,7,7,8,8,8-Pentadecafluoro-1-naphthalen-1-yloctan-1-one；2,2,3,3,4,4,5,5,6,6,7,7,8,8,8-pentadecafluoro-1-naphthalen-1-yloctan-1-one
• 化学式: C₁₈H₇F₁₅O
• 分子量: 524.229
• InChiKey: NMWRBPVVIHRNKT-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  8
• 重原子数：
  34
• 可旋转键数：
  7
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.39
• 拓扑面积：
  17.1
• 氢给体数：
  0
• 氢受体数：
  16

反应信息

• 作为产物：
  描述：

  萘 、 全氟辛酰氯 在 三氯化铝 作用下， 以 二氯甲烷 为溶剂， 反应 2.0h， 生成 α-naphthyl perfluoroheptanoyl ketone
  参考文献：
  名称：

  Simultaneous, Segregated Storage of Two Agents in a Multicompartment Micelle

  摘要：

  The simultaneous, segregated storage of two different chromophores in a multicompartment micelle, which is formed from self-assembly of (polyethylethylene)(polyethylene oxide)(polyperfluoropropylene oxide) mikto-arm star terpolymers in water, was investigated by spectrophotometry. The multicompartment micelles, with segregated micellar cores composed of fluorocarbon and hydrocarbon compartments, can simultaneously absorb two chemically different molecules. These two molecules were confined into their preferred compartments with high selectivity.

  DOI：

  10.1021/ja056841t

文献信息

• Simultaneous, Segregated Storage of Two Agents in a Multicompartment Micelle
  作者：Timothy P. Lodge、April Rasdal、Zhibo Li、Marc A. Hillmyer

  DOI：10.1021/ja056841t

  日期：2005.12.1

  The simultaneous, segregated storage of two different chromophores in a multicompartment micelle, which is formed from self-assembly of (polyethylethylene)(polyethylene oxide)(polyperfluoropropylene oxide) mikto-arm star terpolymers in water, was investigated by spectrophotometry. The multicompartment micelles, with segregated micellar cores composed of fluorocarbon and hydrocarbon compartments, can simultaneously absorb two chemically different molecules. These two molecules were confined into their preferred compartments with high selectivity.